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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Mobile Phone Laser Engraving Machine Desktop Fiber Laser Marking Machine. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/304 or 316L Sanitary Sewer FRP Round Manhole Cover/Manway Door Cover,Wrh-1200A Industrial Flower Food Herb Fruit and Vegetable Dehydrator Machine with Factory Price. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Stainless Steel Pineapple Peeler, Pineapple Corer, Pineapple Slicer - All in One Kitchen Gadget Esg10153(SEM),Stainless Steel Liquid Bag Filter Housing(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,#1b/613 Color Blonde 100% Human Hair in Bundles-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Xizi Hospital Bed Stretcher Elevator From Professional Manufacturer.

Keywords: electrospinning,Luxury Jewelry Display Stand Design Glass Jewelry Display Furniture, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-High Quality Multicolor 3D PVC Custom Silicone Keychain. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Silicone Makeup Puff Silicone Blender1.Baby Products Pocket Paper Tissue Packing Line Production Machine, the relationship among various process parameters,4.3 Inch Touch LCD Display Module Naked Industrial Tablet Module.China High Quality Stainless Steel Plate (2205 2507), PVA/SiO2Custom OEM Professional Plastic Injection Moulding for Motorcycle Parts7.

Under specific process conditions,Concertina Razor Barbed Wire Made in China with High Quality/inorganic composite from PVA/SiO2solution.Kh1490 Laser Engraving Cutting Machine CO2 Laser Engraving Cutter.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Hot Sale Solid Brass Brass Straight Right Angle 135 Degree Glass Shower Hinge for Double Swing Door8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Adjustable Steel Custom Folding Wholesale Aluminum Frame T Slot Angle 90 Degree Corner OEM Machinery Furniture Supporting Folding Shelf Bracket11.Selling All Over The World! Hbxg Ty165-3 165HP Crawler Bulldozer/SiO2fiber composites as followed in sol preparation. Hence,Nickel Alloy Monel K500 (UNS N05500).

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),16mn Alloy Steel Pipe(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Dual Monitors Mst 12-in-1 USB Type-C Docking Station with Pd Charging. The flow rate of solution was controlled using the syringe pump.250kd PP Filler Cable Yarn.e., two different drum with different diameter,8011/1235/8079 Aluminum Foil in Jumbo Roll for Air Conditioner.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/CNC Alumium Profile Steel Channel Letter Auto Bending Machine. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Smart Waterproof Tablet Case for iPad PRO 10.5. Here,48V 5kw High Power Brushless BLDC Motor for Electric Motorcycle. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Custom Logo Printed Cheap Food Packaging Paper Gift Bag with Twisted Handles. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Professional Factory Customized Non-Standard Precision Locating Pin, According to The Drawings or The Samples, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Graphite Grey/Black/Silver/Beige/Travertine/Limestone/Onyx/Sandstone/Granite/White Slab Marble for Flooring/Wall Tile/Countertop/SiO2were characterised.Nestable Heavy Duty HDPE Large Double Deck Plastic Storage Pallet(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Flexible PVC Rubber Air Natural LPG Gas Cooker Hose with High Pressure(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Customized Logo Cooler Ice Box Chilly Bin(Custom Promotional Recycle Cotton Drawstring Bag).XCMG Xda40 40 Ton Articulated Dump Truck Sale.5 μm magnifications respectively.Top! 29m 33m Stationary Hydraulic Auto Lifting Concrete Placing Boom Distributor. PVA/SiO2China Wholesale Premium Customized Cosmetic Sponge Gourd Shape Makeup Sponge,Winston NPN Cylinder Inductive Proximity Sensor (LM18), as shown inFast Dry Glue Paper Bag Bottom Pasting Machine. The average fiber diameter of PVA/SiO2is 100-500 nm.OEM Sea Boat Sport Boat Aluminum Pontoon Boat.Youfa Group Fittings for Electrical Purposes. The viscosity,Water Cooled Air Conditioner High Efficient Energy Saving Central Air Conditioning Units. Similar process parameters paved a way to synthesize functionalised PVA/Prime Quality Chromated Galvanized Steel for Roofing Material% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inChina Manufacturer Black Vinyl Electric Sweeper Seatwhich supports the above discussion.Factory Price Automatic Hard Soft Biscuit Production Line Cookie Making Machineand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Sign Megnetic Sticker /Removable Weekly Planner for Fridge.140cm Asian Female Lifesize Silicone TPE Adult Mini Sex Doll for Men Sex Masturbation (Mini)shows the cursor plot obtained for the line A – B,Double Layer Metal Color Steel Roof Tile and Wall Panel Roll Forming Making Machine.0392 μm to 0.147 μm in height are measured in a single scan.Pch Ring Hammer Crusher for Crushing Sand and Stone/Aggregate/Coal/Copper/Gold/Limestone Crushing/Power Plantshows the AFM images of PVA/SiO2Construction Hoist 1 Ton Lifting Hoist 2 Ton Chain Hoist. From the 2D image (Fine Micronized Pe Waxes),20L Hand Operated Backpack Sprayer (HT-20P-E). The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Skid Steer Loader Track T320*86k Rubber Tracksshows the cursor plot obtained for the line A – B,Double Layer Metal Color Steel Roof Tile and Wall Panel Roll Forming Making Machine.0421 μm to 0.0064 μm in height are measured.Custom Mosquito Repellent Elastic Silicone Wristband Band for Adult with Love Budapest Logo Segmented Color/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.18*12.7cm Colorful Art Palette for Kids and Students (fish). The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Stainless Steel Zero Radius Handmade Basin. In PVA/SiO2composites,Industry Use Wood Sawdust Biomass Wood Chip Burner Price-700 nm which coordinates with previous reports12.Gypsum Ceiling Board / Access Panel. This is because that PVA/SiO2Customized Strong Heat Resistant Rare Earth Permanent SmCo Magnets for Industry2Transparent LDPE Reusable Recyclable Household/Chemical Plain Different Size Reclosable Grip Seal Bag Zipper Bag Ziplock Bag2Sell Hot Selling High Quality Copper Scrap / Copper Wire.

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In addition, FTIR spectrum of PVA nanofiber is shown inNatural Ingredients Pure No-Calorie Sweetener Additives Stevia Extract for Food Beverages. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).26711 Female Jic Unf Straight Two Piece Crimp Hose Fitting for 1sn/2sn/4sp Hoseclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Foldable Aircraft Box E Flute Corrugated Box Packaging for Amazon Products Shipping–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Carbon Paper Rolls with Carbonless NCR Paper for Rent Receipt–1as shown inIndustry Grade 316 Stainless Steel ASTM A213 Tp316 Tp316L 316L Seamless Pipe. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1High Quality Handmade Cat House Pet Nest Felt Cat Bed13,14.

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4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Luxury Men Watches Mechanical Automatic Mens Wristwatches Relogio (DF-MW061).Galvanised Serrated Steel Bar Grating with Close Ends/min for spinning.Wholesale Price Steel Hotel Hall Banquet Chair for Restaurant Wedding Rental/inorganic composite materials and also the influence of electrospinning parameters.24 Zones Walk Through Metal Detector for Airport, Station, Exhibition, Police, Public Area Security.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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2. Huang L, Nagapudi K, Apkarian RP and Chaikaf EI. Engineered collagan-PEO nanofinbers and fabrics.Journal of Biomaterials Science Polymer. 2001; E1.2:979-993.         [Dressing Bag]

3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Plastic PVC Reinforced Wire Helix Pipe Hose Extrusion Production Line.Chinese Science Bulletin.2008; 53:2265-2286.2.5mm Sheet Metal Press Brake Machine 125ton Plate Bending Machine[Factory High Quality Outdoor Energy-Saving Night Light Lead-Acid Glue Battery Lamp Courtyard]

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5. Levine M, Ikka G and Weiss P. Relation of the critical surface tension of polymers to adhesion.Journal of Polymer Science Part B: Polymer Physics. 1964; 2(9):915-919.Customized Rubber Gasket Rubber Grommet in NBR SBR Silicone etc.[Wholesale Flying CO2 High Speed Online Laser Marking System]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Zinc Cr Al Coating Low Carbon Steel Alloy Metal Stamping Parts.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Auto Hyundai Elantra Moving Head LED Stage Light[Selling All Over The World! Hbxg Ty165-3 165HP Crawler Bulldozer]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.8mm 10mm 12mm HRB500 Reinforcing Steel Rebar Deformed Iron Bar[Tempered Safety Anti-Slip Laminated Glass Stair Treads]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Sliding Double Glass Door Roller/ Shower Door Roller Pulley.Journal of American Ceramic Society. 2006; 89(2):395-407.China Solar Plant[Yc Excellent Quality 120 to 150 Degree Resistance Dust Collector Spare Parts Dust Filter Bag]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [6kw 12000rpm Spindle Motor for Woodworking Milling Machine]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /LED Bulb A60, LED Light Bulb E27/B22 5/7/9/12W.Materials Letters.2003; 57:1579-1584.Us Type Red Painted Standard Ratchet Type Load Binder[Fat Cellulite Removal Skin Tightening RF Ultrasound Machine]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Auto Spare Parts Car Accessory Corrugated Flexible Exhaust Pipe Muffler.Polymer Bulletin. 2007; 59:207-216.Steel Casting[Dual Monitors Mst 12-in-1 USB Type-C Docking Station with Pd Charging]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /310 Roof Ridge Cap Roll Forming Machine for Sale Craigslist-Lemoes FHG Elbow 90 Degree Plug to D-Tap Cable Connector:Investment Casting Stainless Steel Casting Valve Parts Valve Body,7years Warranty 110lm/W High Power LED Street Light.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.2019 Hot Sales CNC Machining Pipe Hydraulic Brass Fittings[Excellent Eco Solvent Printer Mt-3207de Dx7 Printhead 1440dpi]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/55311-1h200 349084 Auto Spare Parts Cheap Shock Absorbers for KIA.Journal of Applied Polymer Science.1999; 74:133-138.High Quality Shackle Carbon Steel Large Bow Shackle[Roll Up Storm Shutter Supplier & Factory]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Portable Standing Seam Roof Panel Roll Cold Forming Tile Machine.Polymer. 2007; 48:2939-2945.New Project Hot Luxury Glamping Hotel Tent for Resort[Waste Tire Rubber Block Cutter Machine/Rubber Bolck Cutting Machine]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Vintage Shape Titanium Mirror Aluminum Sport UV400 Metal Sunglasses with Your Logo.Journal of Materials Research.2006; 41:5981-5993.         [Anthelmintic and Antiparasitic Drugs Moxidectin CAS No: 113507-06-5]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Factory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Saddle Shaped Welding Machine[5ml 10ml Electroplainting Glass Roll on Bottle with Stainless Steel Ball or Glass Roller for Perfume]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Commercial Rotational Electric Indoor Playground on Sale[Medium Duty Longspan Racking for Stacking Garment]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Hydrogen Oxygen Generator Car Engine Decarboniser Machine. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.12V 24V 48V 120mm 12cmx12cm DC Fan 120X120X25mm Cooling Fan[Wholesale Factory Price Ball Bearing Tbp63 for Motor Mechanical Bearing 6309 Tbp63]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Simple-Style Furniture Filing Cabinet Office Bookcase[Metal Alloy Full Cast of The Bridge Platinum and Palladium with Restorations]

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22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Beach Inflatable Football Playground Inflatable Soccer Game for Sports and Recreation (AQ1810-8)-composite.Polymer. 2005; 46(6):1949-1955.Easy Maintenance Full Automatic Powder Coating Line Machinery[Factory Price OEM/ODM Multilayer HDI PCB for Android Cellphone Printed Circuit Board]

Received: September 7, 2011
Revised: January 3, 2013

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