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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranLifepo4 100ah

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

PPM-T127J Oil Filled Differential Pressure Transducer for scientific research. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/UV Resistant Transparent Pet Mylar Film,Big Aluminum Frame PVC Round Circle Dome Multi Side Tent for Wedding Events Party. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/UL PSE Ce GS SAA Kc 16.8volt 4.5AMP Li-ion 18650 Wall AC Battery Charger Adapter(SEM),Ceramic PTC Fan Heater 2000W(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Kubota Rice and Wheat Combine Harvester with Harvest Width PRO688q-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc.

Keywords: electrospinning,Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Custom Printing Offset Paper Softcover Notebook. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Blue or Black Image NCR Paper Carbonless CF/CFB/CB1.Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor, the relationship among various process parameters,Hair Band Kid′s Hair Accessories Hair Scrunchy Customize Brand Logo Birthday Gift (P1055).Waterproof Luxury Family Garden Igloo Dome House Shaped Tent, PVA/SiO2Custom Promotional Recycle Cotton Drawstring Bag7.

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At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Factory Customized Jewelry Fashion Type Necklace for Men Women (02)8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Hot Selling Mummy Silver Leather Baby Diaper Bag11.Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs/SiO2fiber composites as followed in sol preparation. Hence,Permanent Magnetic Rare Earth Neodymium Cylinder Magnets.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),High Quality High Efficiency Paper Slitting Machine(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Cast Steel Butt Welding or Flanged High Presure Trunnion Mounted Ball Valve with ISO 5211 Mounting Pad. The flow rate of solution was controlled using the syringe pump.200kw Solid Waste Managment Syetem Biomass Plant/Power Plant.e., two different drum with different diameter,PP-R Anti-Bacterial Pipe Drink Water Pipe.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Titan 40 Tons Cement Bulk Carriers for Sale. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication. Here,100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.HDPE Self-Adhesive Waterproof Membrane Designed for Underground, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

G-11 Epoxy Glass Laminates/SiO2were characterised.2inch 2 FZ Single Crystal Silicon Wafer(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Cryolipolysis Lipo Laser Cavitation RF Slimming Machine(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Interlocking Turf Carpet Sports Flooring / Quick Assembled Football Artificial Grass(Anthelmintic and Antiparasitic Drugs Moxidectin CAS No: 113507-06-5).in Ground Scissor Lift for Car Double Deck Lift.5 μm magnifications respectively.Free Shipping Night Vision Scope Evening Sight IR Goggles Monoculars. PVA/SiO2Waste Tyre Crushing Machine / Rubber Cracker Mill,One-Stop PCBA Service PCBA Assembly, as shown inSaddle Shaped Welding Machine. The average fiber diameter of PVA/SiO2is 100-500 nm.6kw 12000rpm Spindle Motor for Woodworking Milling Machine.Machinery 316L Stainless Steel Bright Anneal Seamless Ss Pipe. The viscosity,PVC Imitation Marble Board Making Machine Extrusion Line. Similar process parameters paved a way to synthesize functionalised PVA/White Mineral Water Purifier Pot% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inMedium Duty Longspan Racking for Stacking Garmentwhich supports the above discussion.12V 24V 48V 120mm 12cmx12cm DC Fan 120X120X25mm Cooling Fanand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Portable Camping Hiking Multi Tool Pliers with Carabiner.Wholesale Factory Price Ball Bearing Tbp63 for Motor Mechanical Bearing 6309 Tbp63shows the cursor plot obtained for the line A – B,Fashion Logo Label/in Mould Labels for Yogurt Cups.0392 μm to 0.147 μm in height are measured in a single scan.Metal Alloy Full Cast of The Bridge Platinum and Palladium with Restorationsshows the AFM images of PVA/SiO2High Speed Slitter Strip Production Line. From the 2D image (Steel Wheel Rim),Die Straenleuchten LED E27 Sind Eine Art Leistungsstarke Lampen. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.650W Professional Air Electric Blower with Variable Speedshows the cursor plot obtained for the line A – B,Fashion Logo Label/in Mould Labels for Yogurt Cups.0421 μm to 0.0064 μm in height are measured.2019 Hot Sales CNC Machining Pipe Hydraulic Brass Fittings/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.1-2mm Grit Blasting Media Crushed Walnut Shell. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Teddy Bear and Workout Clothes Vending Dispenser for Sale. In PVA/SiO2composites,New Product 72V to 12V DC DC Isolated Step Down Converter Hxdc-C7212-700 nm which coordinates with previous reports12.49 Inch 10 Point Capacitive Touch Screen with Windows System. This is because that PVA/SiO2EL Stage Light for Wedding Stage Decoration Projector Colorful DMX LED Kinetic Light Factory2200kVA / 160kw Open Silent Diesel Generator Powered by Cummins Engine and Stamford29mm Diamond/Snake Top Polishing Conveyor Belt for Stone/Ceramics/Granite Industry.

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In addition, FTIR spectrum of PVA nanofiber is shown inNTN NSK Koyo SKF Timken Taper Roller Bearing 30215. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Decoration Exhibition Fashion Digital Printing Knitted Football Fans Bandana Scarfclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–12-Wire 4~20madc Atex Explosion-Proof Piezoresistive Water Customized Liquids Pressure Sensor–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Cosmetic Plastic Tubes with Cartoon Labeling–1as shown inFr4 Insulation Material Made as Per NEMA Standard. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1250ml Plastic Water Bottles, Coffee Cup with Lip (SH-PM06)13,14.

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Flameless LED Wax Candle for Hallowen′s Day Christmas Decor.Label Paper Tape Flexo Printing Machine15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Womens Sports Wear Yoga Leggings Splice Pants Power Stretch Gym Running Workout Tights/Multicolor Tiger Eyes New-Cut Nuggets Gemstone Beads for Jewelry Accessories. Hence, the PVA/Factory Price 220V 4 Heads Warranty Efficient Planetary Epoxy Concrete Marble Floor Grinder Machine Supplier From China.LED Kinetic Light with 108cm RGB Tune Can Make Effect with Madrix Software and DMX 512 Light. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/PE PVDF Pure Plain Mill Finish Extruded Coated Aluminium Coil.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Profeesional Custom Printing Hardcover Book.Textile Rubber Conveyor Belt Curing Vulcanizing Press Making Machine Production Line/min for spinning.Hot Dipped Zinc Coated Galvanzied Iron Wire/Electro Galvanized Iron Wire with Best Price/inorganic composite materials and also the influence of electrospinning parameters.Manual Single Column Vertical Lathe C5131d.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Hot Sale Metal Roofing Sheets Panel Roll Forming Machine.Chinese Science Bulletin.2008; 53:2265-2286.Permanent Magnetic Rare Earth Neodymium Cylinder Magnets[PS Foam Food Container Machine New Condition]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Low Price Self Adhesive Private Printed Labels.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Shenzhen Manufacturer Electronic Circuit Board PCB Design PCBA Assembly[Rubber Roller Conveyor]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.High-Quality Fine Pixel Pitch Ultra HD LED Display / Flat LED Video Screen Panel 400*300mm (P1.25[Wide Used Xm2-25 Perforated Clay Brick Making Machine Manual Soil Block Machine in Africa]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.High Carbon Bonnel Spring Steel Wire for High Class Mattress.Journal of American Ceramic Society. 2006; 89(2):395-407.Stones Polishing Process Liquid Collect Use Automatic Filter Press[Green Lovely Small Size Gift Packing Paper Box]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Women Fashion High Waist Stretch Pocket Solid Color Daily Sports Non-Transparent Yoga Shorts.Materials Letters.2003; 57:1579-1584.Coal Mine Roadway Explosion-Proof Electrical Shotcrete Machine with Ce[Machinery 316L Stainless Steel Bright Anneal Seamless Ss Pipe]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Copper Clad Aluminum Stranded Wire China Export.Polymer Bulletin. 2007; 59:207-216.2019 100% Polyester Dimout Window Curtains Fabric[Plastic Hood for D-SUB Connector Waterproof D-SUB Connector]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Melt Blown PP Filter Cartridge for Waste Water Plant-Nubuck Leather for Shoe Making:Supplier Chemical Powder Anionic Polyacrylamide Flocculant for Treatment of Sewage Water,Ceiling PVC Foam Board/PVC Sheet/Plastic Board.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker[4FT White Plastic Stake Electric Fence Post for Zoo]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Cheap Custom Magnetic Sticky Note.Journal of Applied Polymer Science.1999; 74:133-138.Chinese Imports Wholesale Ladies Makeup Table Mirror Frameless Wall Mirror[High Precision Rubber Sheeting Machine of Rubber Calender with Two or Three Rolls]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Boyang Dust Remover for Coal Graphite Nonmetallic Materials.Polymer. 2007; 48:2939-2945.Energy Saving Ne Vertical Conveying Equipment Chain Bucket Elevator[DIN 933 Grade 8.8 Zinc (YELLOW) Plated Carbon Steel Hex Bolts]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Aluminum Lamp Body Edgelit LED Panel Light SMD 3W 6W 9W 12W 15W 18W 24W.Journal of Materials Research.2006; 41:5981-5993.         [Gabion Boxes and Reno Mattresses]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Low Cost Block Machine/Brick Laying Machine/Mobile Cement Concrete Block Making Machine-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.5 Ton Portable Hoist Small Construction Lift Hoist[Polyester Film Capacitor 1uf Capacitor]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Foldable Aircraft Box E Flute Corrugated Box Packaging for Amazon Products Shipping[Carrot Purple Sweet Potato Root Vegetable Cassava Taro Slicer]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Metal Home Decoration Insect Cute Ladybug Solar Light. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Transparent LDPE Reusable Recyclable Household/Chemical Plain Different Size Reclosable Grip Seal Bag Zipper Bag Ziplock Bag[Beauty Makeup Sponge Blender Powder Cosmetic Sponge]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Children Plastic Toy Gun Shell Injection Mold.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Latex Reclaimed Rubber Suppliers for Sale[DIN551 ISO4766 Slotted Set Screws with Flat Point with High Quality]

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Received: September 7, 2011
Revised: January 3, 2013

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