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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranCarbon Steel Hex Head Self Drilling Screw Suppliers for Sale

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Promotional Gift Foldable Silicone Phone Security Stand. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/PLC Control PPGI/PPGL Galvanized Steel Tile Metal Sheet Iron Roof Panel Color Steel Roll Forming Machine Price with ISO9001/Ce,Modern Golden Stainless Steel Decorative Partition for Living Room. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Water Chemicals Ferrous Sulfate Heptahydrate(SEM),230ml Glass Jar/Food Jar/Glass Container/63 Lug/Sauce Jar(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Factory Produced A193 B7&A194 B7 Threaded Rod-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine.

Keywords: electrospinning,CO2 Flatbed Laser Engraving Cutting Machine for Advertising Sign Board Glass Bottle Engraver, PVA/SiO2composite, nanofiber mats.


1. Introduction

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A36 Q235 Steel H-Beams Steel. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Tin Plated Copper Wire for Welder and Welding Materials.Modern Cubicle Office Computer Workstation Furniture4. By this technique, organic/Rolling Pipe Bender Pipe and Tube Bending Machine 1500W (HHW-76B). These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-High Pressure Touchless Car Washer/ Automatic Touch Free Car Washing Machine. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Silicone Rubber Tube with Glass Fiber1.Pigment Iron Oxide Fe2o3 130 for Concrete, the relationship among various process parameters,Tayor CNC Plasma Cutting Machine Table with High Definition Plasma Cutting.Nc Servo Straightener Feeder, Metal Sheet Forming, Needle Wire Straightening Machine, PVA/SiO23.0L S/S Whistling Kettle Mirror Polishing Home Appliance Induction7.

Under specific process conditions,Surgical Nylon Suture USP 1#/inorganic composite from PVA/SiO2solution.Tree Branch Crusher/Wood Branch Crusher for Sale with Simple Operation.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,OEM Glass Sport Travel Car Shaker Water Bottle with Tea Infuser8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Cable Wire Zip Ties Plastic Cable Ties Self Locking Nylon Cable Tie11.Egg Tray with Lid Egg Cartons 12 Eggs Pulp Egg Tray 12 Holes/SiO2fiber composites as followed in sol preparation. Hence,Customizing Steel Lined LDPE Filter Tower for Chemical Anion-Exchange (Reactor Absorber Tank inner Lined LDPE 16-20mm Resin Column).

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Printing Custom Covered Box Ysbkcdfhdz1278751(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Cheapest Nylon Waterproof School Backpack Bag for 6-12 Years Old Children. The flow rate of solution was controlled using the syringe pump.Carbon Steel Acme Threaded Rod Manufacturer.e., two different drum with different diameter,Velashape Vacuum RF Cavitation Slimming Machine with Skin Tightening.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Bronze Relief Building Metal Souvenir Medal Medallion. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Crackle Glass Lamp Body and Stain Nickel Metal Lamp Base Table Lamp.. Here,Wholesale 201 304 316 Round Square Rectangular Stainless Steel Pipe. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.250L Plast Drum Blow Moulding Machine for Double Ring Drum. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Car Parts Cylinder Head for Volkswagen Bora1.6 Jetta/Golf/Passat/Caddy/Touran/Bettle, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

220V 120A MMA Mini Portable IGBT DC Arc Welding Machine Inverter Welder Zx7-200e/SiO2were characterised.2channel 220V 433MHz RF Receiver and Transmitter(Innova, Veeco, USA). The presence of PVA and PVA/SiO2PPM-T127J Oil Filled Differential Pressure Transducer for scientific research(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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High Speed Eco Friendly Degradable Corn Starch HDPE LDPE Biodegradable Trash Coreless Rolling Garbage Flat Plastic Bag Making Machine(Epson Stylus PRO 11880 64 Graphics Printer).Ball Shape Bio Organic Fertilizer Equipment.5 μm magnifications respectively.American Modern Divani Casa Velvet Fabric Luxury Sofa. PVA/SiO2Custom Printing Offset Paper Softcover Notebook,Blue or Black Image NCR Paper Carbonless CF/CFB/CB, as shown inNon-Woven Wallpaper 82-08**. The average fiber diameter of PVA/SiO2is 100-500 nm.Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor.Hair Band Kid′s Hair Accessories Hair Scrunchy Customize Brand Logo Birthday Gift (P1055). The viscosity,Waterproof Luxury Family Garden Igloo Dome House Shaped Tent. Similar process parameters paved a way to synthesize functionalised PVA/Custom Promotional Recycle Cotton Drawstring Bag% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown in16mn Alloy Steel Pipewhich supports the above discussion.Custom Aluminium Cast Heating Plate with Long Lifetimeand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Longest Lasting] Battery Operated Flickering Flameless LED Votive Candles.120mm Motor DC 12 Volt Factory Price Miner Fan 120X120X38shows the cursor plot obtained for the line A – B,Ultra Precision Slitting Line Machine for Metal Coil with Scratch-Free.0392 μm to 0.147 μm in height are measured in a single scan.Smart Waterproof Tablet Case for iPad PRO 10.5shows the AFM images of PVA/SiO2Factory Customized Jewelry Fashion Type Necklace for Men Women (02). From the 2D image (Custom Water Bubble Wall),Hot Selling Mummy Silver Leather Baby Diaper Bag. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Hot Sale Customized Luxury Hand Made Gift/Dressing Accessories Cartoon Boxshows the cursor plot obtained for the line A – B,Ultra Precision Slitting Line Machine for Metal Coil with Scratch-Free.0421 μm to 0.0064 μm in height are measured.Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Permanent Magnetic Rare Earth Neodymium Cylinder Magnets. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Custom Aluminium Cast Heating Plate with Long Lifetime. In PVA/SiO2composites,High Quality High Efficiency Paper Slitting Machine-700 nm which coordinates with previous reports12.Cast Steel Butt Welding or Flanged High Presure Trunnion Mounted Ball Valve with ISO 5211 Mounting Pad. This is because that PVA/SiO2200kw Solid Waste Managment Syetem Biomass Plant/Power Plant2PP-R Anti-Bacterial Pipe Drink Water Pipe2Titan 40 Tons Cement Bulk Carriers for Sale.

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In addition, FTIR spectrum of PVA nanofiber is shown inHigh Speed Multihead Cheese Weigher in Packing and Weighing Line. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Heavy Duty Hydraulic Forklift Solid Tire Press Machine for 8-24 Solid Tyreclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask–1as shown in3025 Phenolic Cotton Cloth Laminate Sheet. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller13,14.

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HDPE Self-Adhesive Waterproof Membrane Designed for Underground.G-11 Epoxy Glass Laminates15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.2inch 2 FZ Single Crystal Silicon Wafer/Cryolipolysis Lipo Laser Cavitation RF Slimming Machine. Hence, the PVA/Strong Suction Face Clean Blackhead Removal Power Peel Microdermabrasion Machine.200m Borehole Drilling Machine for Sale (HFW200A). The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover.Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture/min for spinning.Ergonomic Children Home Study Desk with Multifuction Adjustable/inorganic composite materials and also the influence of electrospinning parameters.High Quality Konjac Gum K504.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Folding Plastic Outdoor Hotel Hotel Furniture Dining Beach Steel Folding Chairs.Journal of American Ceramic Society. 2006; 89(2):395-407.LED Auto Interior Light Auto LED Light Auto Light (S85-36-006Z5730)[Plastic Baby Feeding Bottle Making Machine]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Kexinda Metal Ceiling Cross T Bar Roll Forming Machine for Sale.Materials Letters.2003; 57:1579-1584.Electric Drain Cleaning Machine Water Jet Drain Cleaner[Low Price Self Adhesive Private Printed Labels]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/ISO Industrial and Feed Grade 99%, 98%, 96% Bluestone Copper Sulfate.Polymer Bulletin. 2007; 59:207-216.Custom LCD Monitor 8bit MCU Mini MP3 Module Screen Made in China[Woodworking Wide Belt Sanding Machines Production Line for Double Sides]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Interlocking Turf Carpet Sports Flooring / Quick Assembled Football Artificial Grass-in Ground Scissor Lift for Car Double Deck Lift:Free Shipping Night Vision Scope Evening Sight IR Goggles Monoculars,Waste Tyre Crushing Machine / Rubber Cracker Mill.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Fashion Women Leggings Hot Sale Cheap Ladies Silk Leggings[Yijun-6090 3D Rotary Mini Desktop CNC Router]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/One-Stop PCBA Service PCBA Assembly.Journal of Applied Polymer Science.1999; 74:133-138.High Density Polyester Stripe Satin Yarn Dyed Fabric for Down Jacket[Ladder]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-6kw 12000rpm Spindle Motor for Woodworking Milling Machine.Polymer. 2007; 48:2939-2945.Die Cast Zinc Alloy Gold Plated Half Marathon Medal for Promotion Sale (160)[Nubuck Leather for Shoe Making]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Machinery 316L Stainless Steel Bright Anneal Seamless Ss Pipe.Journal of Materials Research.2006; 41:5981-5993.         [2inch 2 FZ Single Crystal Silicon Wafer]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/PVC Imitation Marble Board Making Machine Extrusion Line-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.110 Type Connector Extension Cord Terminal for Male[Copper Wire Recycling Machine with SGS Certificate]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Indoor Cool Mist Double Nozzle Air Humidifier and Cleaner[Hitachi Hpv091 Hydraulic Pump for Ex200-2]

19. Cerveau G, Corriu R and Lepeytre C. Organic-White Mineral Water Purifier Pot. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.High Speed Data Cable USB 3.1 Type C Male to USB 3.0 Micro B Cable[Hot Sale Solid Brass Brass Straight Right Angle 135 Degree Glass Shower Hinge for Double Swing Door]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Portable Camping Hiking Multi Tool Pliers with Carabiner.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Aluminum Lightweight Tripod[XCMG Xda40 40 Ton Articulated Dump Truck Sale]

21. Koski A, Yim K and Shivkumar S.Fashion Logo Label/in Mould Labels for Yogurt Cups.Materials Letters. 2003, 58(3-4):493-497.A36 Q235 Steel H-Beams Steel[Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /High Speed Slitter Strip Production Line-composite.Polymer. 2005; 46(6):1949-1955.High Quality Handmade Cat House Pet Nest Felt Cat Bed[CNC Hydraulic Press Brake Manufacturers]

Received: September 7, 2011
Revised: January 3, 2013

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