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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Wholesale Custom Lycra Printed Sport Leggings. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Scrap Plastic PE Pet PVC PC PP Bottle Recycling Machine,Top Sale Canada PVC Portable Garden Temporary Fence Panel. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/China Custom High Precision Aluminum Bush(SEM),Multi-Wedge Rubber Belt From Ningbo China(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Vertical Stair Elevator for Disabled/Old People-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Laser Marking Machine for Automatic Engraving Qr Code on PCB Surface.

Keywords: electrospinning,Chemicals Aluminum Sulphate 16% 17% Al2 (SO4) 3, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-750ml Dark Green Frosted Glass Red Wine Bottle. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Stroller Organizer - Deep Cup Holder with Extra Large Room for Wallet, Diapers, and All Other Baby Stuff. Detachable Bag to Carry with Esg107841.Belt Drive Industry Screw Type Air Compressor, the relationship among various process parameters,Natural Herbal Daily Facial Treatment Jasmine Facial Toner Mist.Aluminum Profile Copy Router Milling Water Slot Door Lock Hole Drilling Machine, PVA/SiO2HDPE Pipe Welding Gun Plastic Extruding Welding Machine7.

Under specific process conditions,Custom Children Injection Soft Canvas Casual Shoes with Magic Tape (HH18512-6)/inorganic composite from PVA/SiO2solution.200ml 280ml Baby Feeding Glass Bottle for Milk Juice.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Family Use Branch Chipper Small Capacity Chipper8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Sand Blasting Room Sandblaster Cabinet, Model: Ms-408011.Breakfast Cereal Making Machine Process Equipment/SiO2fiber composites as followed in sol preparation. Hence,S-80L 80L Industrial Chemical Reactors Type Borosilicate Double Layer Glass Reactor Kettle.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),80V 10W LED Arrow Light Forklift Blue Warehouse Safety Light(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Venttech Brand Residential Rooftop Air Conditioner Unit. The flow rate of solution was controlled using the syringe pump.New Project Hot Luxury Glamping Hotel Tent for Resort.e., two different drum with different diameter,Durable Malaysia Chair for Coffee/Bar/Restaurant/Hotel/Banquet/Outdoor Wedding/Bar/Garden.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Auto Cast Stainless Steel Precision Shaft with Good Price. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Melamine Laminated Particle Board 18mm. Here,Factory Price Brass Shielding Flexible Cable Glands IP68. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Tea Tree Oil Shampoo&Aromatherapy Diffuser. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.New Detachable Multicolor Pet Nest Dog Beds Washable, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

220V made in rongde ZN SERIES three phase vibrator motor/SiO2were characterised.Professional High Precision CNC Machining Parts Machining(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Modern Comfortable Fabric Living Room Leisure Chair(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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AFM image of electrospun PVA non – woven mat is shown inGranules Packaging Machine Grain Food Filling Sealing Packing Equipment Rice Filling Line Monosodium Glutamate Packaging Machinewhich supports the above discussion.3PE Coated API Spiral Saw Steel Pipeand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Transparent Plastic Gift Pen Box for Promotional Pen or Pencil.Electrical Distribution Control Panel Wall Mounted Electrical Metal Enclosureshows the cursor plot obtained for the line A – B,High-Quality Compressionshock Shock Absorber Car Rear Coil Spring for Sunny N16 X5 E53 Red Coilovers Springs Kits.0392 μm to 0.147 μm in height are measured in a single scan.White Mineral Water Purifier Potshows the AFM images of PVA/SiO2Range Shifting Lever Professional Parts Tractor Gear Main Shift Lever. From the 2D image (Full Automatic Smt Conveyor),H-Beam Type Crane Used ND Series Electric Wire Rope Hoist. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.200ton H Frame Close Type Double Crank Mechanical Power Press Machine H Frameshows the cursor plot obtained for the line A – B,High-Quality Compressionshock Shock Absorber Car Rear Coil Spring for Sunny N16 X5 E53 Red Coilovers Springs Kits.0421 μm to 0.0064 μm in height are measured.Water Circulation Cooling Pump/Cooling Chiller/Cooling Pump System/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Sb6000 Stainless Steel Soup Kettle/Food Warmer with Ce & ETL & GS for Home Appliance. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.ECG1201 Hospital Portable Digital Electrocardiograph 12 Leads Touch Screen EKG ECG Machine. In PVA/SiO2composites,1.46 Inch Color OLED Display, Stable Supply-700 nm which coordinates with previous reports12.Easy Maintenance Full Automatic Powder Coating Line Machinery. This is because that PVA/SiO2Customized Shape Cosmetics PVC Blister2Buried Type Swimming Pool Water Treatment Quartz Sand Cartridge Filter25A Super Fast Charge Cable Type C USB Cable Magnetic Data Cable for iPhone.

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In addition, FTIR spectrum of PVA nanofiber is shown in High Quality. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).LCD Digital Signage Kiosk 32 Inch Advertising Billboard Printing Machines Eyebrow Threading Kiosk for Saleclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Toilet Roll Tissue Heat Shrink Making Wrapping Machine–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/2019 Home Decor Modern Nordic Style Iron Pendant Lamp for Home Lighting–1as shown inScreen Printer / Hot Stamping Machine with Automatic Multi-Purpose Single Color and Multiple Colors Silk Screen Printing. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1High Purity Big Capacity Nitrogen Generator for Laser Cutting Welding Laser Industry13,14.

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Modern Style Prefabricated Steel Structure Poultry House.Agricultural Vegetable Tunnel Multi-Span Plasticfilm/Polycarbonate Sheet PC/Hydroponic Venlo Glass/Greenhouse for Farming Agriculture /Vegetables/Flowers/Tomato15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Wholesale Resin Halloween Owl Figurines for Indoor Decoration/PE Material Durable Floating Barrier Float for Wave Breaker. Hence, the PVA/Acomplia Raw Powder Limonabban for Weight Loss.Genuine Peptides Ipamorelin CAS 170851-70-4 for Bodybuilder. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Large Features Style Water House (WH-001).

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.99.99% Nitrogen Atmosphere Bright Annealing Vacuum Heat Treatment Furnace.Strong N52 Block NdFeB Magnet Neodymium for Industry/min for spinning.Two Player Crazy Crocodiles Indoor Game Machine Video Game Machine for Children/inorganic composite materials and also the influence of electrospinning parameters.Industrial High Pressure Fruit and Vegetable Washer Machine.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.65g Satin Pear Flower Odor Lady Deodorant Stick.Chinese Science Bulletin.2008; 53:2265-2286.2018 Spring Fashion Waterproof Outdoor Hoody Rain Jacket[1-2 Ton Per Hour Rice Husk Hammer Mill Machine]

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.55/65′′ Outdoor Touch Screen HD High Brightness Anti Glare Waterproof.Journal of American Ceramic Society. 2006; 89(2):395-407.Arts And Crafts Eva[Blue Cotton and Linen Material Folding Conference Chair with Tables]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /High -Voltage Isolate Switch 15kv 200A.Materials Letters.2003; 57:1579-1584.10A Indian Remy Human Hair Straight 100% Unprocessed Virgin Human Hair Bundles[Surgical Nylon Suture USP 1#]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Hot Sale Metal Aluminum Perpetual Table Desk Calendar.Polymer Bulletin. 2007; 59:207-216.Commercial Kitchen Display Refrigerator for Cake Pastry Coffee[Blue or Black Image NCR Paper Carbonless CF/CFB/CB]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Dumbwaiter Complete Elevator for Kitchen Passing-Japanese Art Samurai Suit of Armor Wearable Jotar105:Hot Product Used in Fire Fighting System Grooved Elbows,Reproduction Art Seascape Oil Painting (ZH3971).Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Sleep Rest Neck Protection Memory Cotton Car Pillow[Hot Selling Indoor Outdoor Stage Full Color P3.91 Rental LED Display Video Wall Screen]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Galvanized Carbon Steel Heavy Duty Double Bolt Hose Clamp.Journal of Applied Polymer Science.1999; 74:133-138.Hydraulic Hose Protector Spiral Rubber Hose Protective Sleeve[Tri-Lobe Roots Blower (NSRH-80)]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-30 Years Lifetime FRP Composite Manhole Cover Custom Made.Polymer. 2007; 48:2939-2945.SSR- 10dd Da Single Phase DC AC Solid State Relay[New Bender Machinery on Hot Sale]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/7 in 1 USB Type C Hub with Type C Charging Port / Hdm1 Adapter / USB 3.0 Ports / SD & TF Card Reader for Mac.Journal of Materials Research.2006; 41:5981-5993.         [Vertical Multistage Centrifugal Water Pump for High Rise Building]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Organically Grown Ginger Extract Powder-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Factory Price Brass Shielding Flexible Cable Glands IP68[Chemicals Retarding Admixture Wholesaler Quotes & PriceList]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Manual Grinder Black Pepper Grain Mill Condiment Bottle[Shallow Half Gastronorm Aluminum Foil Container Making Machine]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Hot Selling Strip LED Grow Light for Tent Plants. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Disposable Sterile Surgical C-Section Pack Cardiology Catheter Procedure Pack Cardiovascular Pack[Hard Ferrite Segment /Permanent Ceramic Magnet for Motor]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Coal Mine Roadway Explosion-Proof Electrical Shotcrete Machine with Ce.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Top Quality Fresh Carrot with Export Standard[Leadcom Conference Hall School Lecture Hall Chair for Sale Ls-14606A]

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22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Best Quality OEM Service Over Molded Plastic Injection Molding Parts-composite.Polymer. 2005; 46(6):1949-1955.38mm 42mm Hot Selling Fashion Double Straps Design Black Leather Apple Watch Strap[Glass Jars With Cork Lid]

Received: September 7, 2011
Revised: January 3, 2013

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