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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranChemical Products of Cellulose HPMC for White Cement Admixtures

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

American Modern Divani Casa Velvet Fabric Luxury Sofa. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Custom Printing Offset Paper Softcover Notebook,Blue or Black Image NCR Paper Carbonless CF/CFB/CB. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor(SEM),Hair Band Kid′s Hair Accessories Hair Scrunchy Customize Brand Logo Birthday Gift (P1055)(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Waterproof Luxury Family Garden Igloo Dome House Shaped Tent-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Custom Promotional Recycle Cotton Drawstring Bag.

Keywords: electrospinning,Longest Lasting] Battery Operated Flickering Flameless LED Votive Candles, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-200kw Solid Waste Managment Syetem Biomass Plant/Power Plant. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.PP-R Anti-Bacterial Pipe Drink Water Pipe1.Titan 40 Tons Cement Bulk Carriers for Sale, the relationship among various process parameters,High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication.100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask, PVA/SiO2Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller7.

Under specific process conditions,HDPE Self-Adhesive Waterproof Membrane Designed for Underground/inorganic composite from PVA/SiO2solution.G-11 Epoxy Glass Laminates.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,2inch 2 FZ Single Crystal Silicon Wafer8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Cryolipolysis Lipo Laser Cavitation RF Slimming Machine11.Strong Suction Face Clean Blackhead Removal Power Peel Microdermabrasion Machine/SiO2fiber composites as followed in sol preparation. Hence,200m Borehole Drilling Machine for Sale (HFW200A).

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture. The flow rate of solution was controlled using the syringe pump.Ergonomic Children Home Study Desk with Multifuction Adjustable.e., two different drum with different diameter,High Quality Konjac Gum K504.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Stainless Steel Full Port Female Thread 2PC Ball Valve. Here,Folding Plastic Outdoor Hotel Hotel Furniture Dining Beach Steel Folding Chairs. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Kexinda Metal Ceiling Cross T Bar Roll Forming Machine for Sale. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.ISO Industrial and Feed Grade 99%, 98%, 96% Bluestone Copper Sulfate, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Interlocking Turf Carpet Sports Flooring / Quick Assembled Football Artificial Grass/SiO2were characterised.in Ground Scissor Lift for Car Double Deck Lift(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Free Shipping Night Vision Scope Evening Sight IR Goggles Monoculars(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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AFM image of electrospun PVA non – woven mat is shown inTrolley Waterproof Hard Tool Case with Foamwhich supports the above discussion.Baby Products Pocket Paper Tissue Packing Line Production Machineand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Flameless LED Wax Candle for Hallowen′s Day Christmas Decor.OEM Customized Precision CNC Machined Steel Bull Pinion Shaftshows the cursor plot obtained for the line A – B,Label Paper Tape Flexo Printing Machine.0392 μm to 0.147 μm in height are measured in a single scan.0.3 mm Thickness Aluminum Corrugated Composite Panel for Southeast Asiashows the AFM images of PVA/SiO2Womens Sports Wear Yoga Leggings Splice Pants Power Stretch Gym Running Workout Tights. From the 2D image (m.dgls-tech.com),Multicolor Tiger Eyes New-Cut Nuggets Gemstone Beads for Jewelry Accessories. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Polypropylene Monofilament/Multifilament Filter Press Clothshows the cursor plot obtained for the line A – B,Label Paper Tape Flexo Printing Machine.0421 μm to 0.0064 μm in height are measured.Factory Price 220V 4 Heads Warranty Efficient Planetary Epoxy Concrete Marble Floor Grinder Machine Supplier From China/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.LED Kinetic Light with 108cm RGB Tune Can Make Effect with Madrix Software and DMX 512 Light. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.PE PVDF Pure Plain Mill Finish Extruded Coated Aluminium Coil. In PVA/SiO2composites,Profeesional Custom Printing Hardcover Book-700 nm which coordinates with previous reports12.Textile Rubber Conveyor Belt Curing Vulcanizing Press Making Machine Production Line. This is because that PVA/SiO2Hot Dipped Zinc Coated Galvanzied Iron Wire/Electro Galvanized Iron Wire with Best Price2Manual Single Column Vertical Lathe C5131d2Hot Sale Metal Roofing Sheets Panel Roll Forming Machine.

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In addition, FTIR spectrum of PVA nanofiber is shown inSocket Flange UPVC PVC Ppv Pipe Fitting From Manufacturer. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Pop up Green Houseclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Low Price Self Adhesive Private Printed Labels–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/High Carbon Bonnel Spring Steel Wire for High Class Mattress–1as shown inCoiled Nichrome Bare Thermocouple Wire Chromel Aumel ANSI Standard Class I. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Women Fashion High Waist Stretch Pocket Solid Color Daily Sports Non-Transparent Yoga Shorts13,14.

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Copper Clad Aluminum Stranded Wire China Export.Melt Blown PP Filter Cartridge for Waste Water Plant15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Nubuck Leather for Shoe Making/Supplier Chemical Powder Anionic Polyacrylamide Flocculant for Treatment of Sewage Water. Hence, the PVA/Ceiling PVC Foam Board/PVC Sheet/Plastic Board.Cheap Custom Magnetic Sticky Note. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Boyang Dust Remover for Coal Graphite Nonmetallic Materials.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Aluminum Lamp Body Edgelit LED Panel Light SMD 3W 6W 9W 12W 15W 18W 24W.Low Cost Block Machine/Brick Laying Machine/Mobile Cement Concrete Block Making Machine/min for spinning.Metal Home Decoration Insect Cute Ladybug Solar Light/inorganic composite materials and also the influence of electrospinning parameters.Children Plastic Toy Gun Shell Injection Mold.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Healthy Five Pieces Bamboo Fiber Baby Dinnerware Sets.Chinese Science Bulletin.2008; 53:2265-2286.Free Sample Residual Current Device Circuit Breaker[55/65′′ Outdoor Touch Screen HD High Brightness Anti Glare Waterproof]

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5. Levine M, Ikka G and Weiss P. Relation of the critical surface tension of polymers to adhesion.Journal of Polymer Science Part B: Polymer Physics. 1964; 2(9):915-919.Air Pneumatic Fitting 5 Way One Touch in Fittings[Logo Design Reflective Car Sticker Printing]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.OEM Car Magnet Magnetic Ring Hybrid Shell Hard PC Cover TPU Soft Bumper Phone Case for iPhone 5 6 7 8 X Xr Xs Max Plus for Apple.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine[Waterproof Luxury Family Garden Igloo Dome House Shaped Tent]

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Lowest Price UV Birch Face Plywood for Furniture Decoration.Journal of American Ceramic Society. 2006; 89(2):395-407.N35h Black Epoxy Permanent Rare Earth Neodymium Magnets[Air to Water Heat Pump for House Heating and Sanitary Hot Water with Ce]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [Natural Herbal Daily Facial Treatment Jasmine Facial Toner Mist]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Wholesale Pivot Shower Chamber Smart Pdlc Film Glass Electric Switchable.Materials Letters.2003; 57:1579-1584.Export Strong Salon Furniture Professional Wholesale Barber Chair[Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Rigid-Flex Immersion Gold Printed Circuit Board Manufacturing.Polymer Bulletin. 2007; 59:207-216.Cup Cake Packaging Machine[Asrs Radio Shuttle Racking System with Stacker Crane for Warehouse Storage]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Most Popular Creative New Hot Fashion Galvanized Steel Fence Wrought Iron Fencing-Building Electric Windlass Winch Hoist Series 2ton~30tons for Lifting and Pulling:Full Color LED Video Screen, Customized P3mm P4mm Flexible Soft LED Module for Curved Install,Glitz Sequin Stretch Spandex Chair Cover for Banquet and Wedding-Gold.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Parts of Motorcycle Cdi/Regulator/Stator Coil Spare Parts for Um Motorrycles and Scooters[Modern Comfortable Fabric Living Room Leisure Chair]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Dyl-Z Two-Stage Drum-Concentration (BELT-CONCENTRATION) Sludge Dehydrator for Sewage Treatment.Journal of Applied Polymer Science.1999; 74:133-138.Chinese Supplier for Lock Gas Spring Adjustable with High Quality[Yellow One Meter PVC Plastic 3 Channels Light Duty Cable Ramp]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Quilting Mattress Protector or Fitted Sheet 100% Cotton /Polyester.Polymer. 2007; 48:2939-2945.Manufacturers Supply High Quality Hyaluronic Acid for Orthopedics[Power Anti Climb Galvanzied 358 Fence/PVC Coated 358 Mesh Fence]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/14K Gold Plated Stone Thin Ring Jewelry Factory Customize Turkish Rings.Journal of Materials Research.2006; 41:5981-5993.         [Ignition Coil for Jeep Cherokee/Wrangler/Grand Cherokee 56028172 56028172ab 56028172AC 56028173]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/20cm Groove Laminated PVC Ceiling Panel PVC Wall Panel-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Best Price Digital Waterproof Security 6 8 12 18 33 Zone Guard Spirit Portable Walk Through Metal Detector[China Geotextile Nonwoven Equipment]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Triple Axles 40 Tons Low Bed Semi Trailer[Quality Powder Coating Die Casting- Aluminum Alloy Casting for LED Street Light Housing]

19. Cerveau G, Corriu R and Lepeytre C. Organic-4 Deck Sand Vibrating Sieve Machine for Sale. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Fancy Personality Artificial Sex Machine Flirting Anal Plug Vaginal Massage Stick Male and Female Sex Concoction Masturbating Anal Plug[Epoxy Aluminum Insect Window Screen/Aluminum Screening]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Dry Shiitake Mushrooms with Fragrant Flavor.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Dog Clothing Pet Clothes[Qt4-15 Full Auto Hollow Solid Brick Machine Color Paver Brick Machine]

21. Koski A, Yim K and Shivkumar S.Kraft Paper Packaging Bag Stand up Pouch Doy Pouch.Materials Letters. 2003, 58(3-4):493-497.Winston NPN Cylinder Inductive Proximity Sensor (LM18)[Hot Salling Shr IPL Elight Hair Removal Machine with Two Handle]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Woodworking Electric Edge Trimming Machine with PVC Edge Trimmer Knife Set-composite.Polymer. 2005; 46(6):1949-1955.2 3 4 Diesel Power Self Priming Centrifutal Irrigation Clean Water Pump[Storage series]

Received: September 7, 2011
Revised: January 3, 2013

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