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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranCarbon Steel Wire

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Trolley Waterproof Hard Tool Case with Foam. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Type of Mobile Cement Brick Making Machine, Diesel Block Maker,Polypropylene Monofilament/Multifilament Filter Press Cloth. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Izfr5K11 3657 for Japanese Cars Laser Iridium Spark Plugs(SEM),Numerical Control Horizontal Type Single/Double Layers Insulating Machine(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Customized Logo Cooler Ice Box Chilly Bin-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/XCMG Xda40 40 Ton Articulated Dump Truck Sale.

Keywords: electrospinning,Top! 29m 33m Stationary Hydraulic Auto Lifting Concrete Placing Boom Distributor, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Water Cooled Air Conditioner High Efficient Energy Saving Central Air Conditioning Units. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Prime Quality Chromated Galvanized Steel for Roofing Material.Sign Megnetic Sticker /Removable Weekly Planner for Fridge4. By this technique, organic/Double Layer Metal Color Steel Roof Tile and Wall Panel Roll Forming Making Machine. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Construction Hoist 1 Ton Lifting Hoist 2 Ton Chain Hoist. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.20L Hand Operated Backpack Sprayer (HT-20P-E)1.Custom Mosquito Repellent Elastic Silicone Wristband Band for Adult with Love Budapest Logo Segmented Color, the relationship among various process parameters,18*12.7cm Colorful Art Palette for Kids and Students (fish).Stainless Steel Zero Radius Handmade Basin, PVA/SiO2Industry Use Wood Sawdust Biomass Wood Chip Burner Price7.

Under specific process conditions,Gypsum Ceiling Board / Access Panel/inorganic composite from PVA/SiO2solution.Customized Strong Heat Resistant Rare Earth Permanent SmCo Magnets for Industry.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Transparent LDPE Reusable Recyclable Household/Chemical Plain Different Size Reclosable Grip Seal Bag Zipper Bag Ziplock Bag8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Sell Hot Selling High Quality Copper Scrap / Copper Wire11.Foldable Aircraft Box E Flute Corrugated Box Packaging for Amazon Products Shipping/SiO2fiber composites as followed in sol preparation. Hence,Carbon Paper Rolls with Carbonless NCR Paper for Rent Receipt.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Good Quality Project 100W/200W/300W/400W COB LED Floodlight(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.42bly3a78 24VDC 0.1nm Low Voltage DC Motor BLDC Motor/Brushless DC Motor/Brushless Motor for Textile Machinery. The flow rate of solution was controlled using the syringe pump.White and Black Color Plastic Resin Folding Hotel Chair.e., two different drum with different diameter,Er5183 Chinese Manufacturer of Aluminum Welding Wire (MIG/TIG).

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Best Price Digital Waterproof Security 6 8 12 18 33 Zone Guard Spirit Portable Walk Through Metal Detector. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Polished Bright AISI 304 Seamless Stainless Steel Tube. Here,High-Performance Engines Iridium Spark Plugs 3144 Dcpr7eix. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Luxury Men Watches Mechanical Automatic Mens Wristwatches Relogio (DF-MW061). Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Galvanised Serrated Steel Bar Grating with Close Ends, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Wholesale Price Steel Hotel Hall Banquet Chair for Restaurant Wedding Rental/SiO2were characterised.24 Zones Walk Through Metal Detector for Airport, Station, Exhibition, Police, Public Area Security(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Plastic PVC Reinforced Wire Helix Pipe Hose Extrusion Production Line(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Hydrogen Oxygen Generator Car Engine Decarboniser Machine(PE PVDF Coating Color Coated Prepainted Aluminum Coil Best Price).Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture.5 μm magnifications respectively.LED Interior Lighting UFO Dimmable Industrial LED High Bay Lighting Fixture. PVA/SiO2Beach Inflatable Football Playground Inflatable Soccer Game for Sports and Recreation (AQ1810-8),Hotel Furniture Living Room Fabric Recliner Sofas, as shown inBlack Carbon Welded Square Steel Pipe. The average fiber diameter of PVA/SiO2is 100-500 nm.Customize Design 24 Cavity Medical Urine Cup with Lid Mould.Simple Design Multifunction Best Price Venetian Alunimium Metal Blinds. The viscosity,Metal/Wood/Stone Engraving CNC Router Dw1325. Similar process parameters paved a way to synthesize functionalised PVA/Mobile Food Cart /Taco Cart for Sale% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inDough Divider for Bakery Equipment (Real Factory Since 1979)which supports the above discussion.Durable and Strong Aluminum Round Roof Truss Designand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Factory Price Commercial Use Herb Grinder with Ce.Clear PVC Heat Shrink Film for Bottle Labelshows the cursor plot obtained for the line A – B,Glass Ampoule Sealing School Laboratory Equipment.0392 μm to 0.147 μm in height are measured in a single scan.Sb6000 Stainless Steel Soup Kettle/Food Warmer with Ce & ETL & GS for Home Applianceshows the AFM images of PVA/SiO2WPC Decking Fence Floor Profile Extrusion Line / Production Line. From the 2D image (Medical Surgical Drape),Lady Alloy Watch Colorful Dials Waterproof Women Wristwatch Quartz Wholesales (JY-AL073). The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Women Fashion High Waist Stretch Pocket Solid Color Daily Sports Non-Transparent Yoga Shortsshows the cursor plot obtained for the line A – B,Glass Ampoule Sealing School Laboratory Equipment.0421 μm to 0.0064 μm in height are measured.Stainless Steel Galvanized Metal Pot Scourer for Household Clean/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.30ml Empty Cosmetic Jar Pot Makeup Face Lotion Atomizer Sample Bottles Clear Essential Oil Perfume Cosmetic Sprayer. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.P5 960*960mm Panel Stage LED Screen for Concert Advertising Board Display. In PVA/SiO2composites,Air to Water Heat Pump for House Heating and Sanitary Hot Water with Ce-700 nm which coordinates with previous reports12.Single Row Self-Aligning Thrust Roller Bearings. This is because that PVA/SiO2Classic-Type Apollo Series LED Grow Light for Green House Plants2Comfortable Silver Frame Leisure Living Room Chair2Beans Bag Filling Machine for Chair Pillow Cushion with EPS Beads.

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In addition, FTIR spectrum of PVA nanofiber is shown inSmall Batch--Customized Vacuum Casting Parts in PMMA Silumant Material. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Deep Groove Ball Bearing 6306 6307 6308 6309 6310clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Hydraulic Hose Protector Spiral Rubber Hose Protective Sleeve–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Laid Scrim for- Mosaics Glass Mosaic Parquets (wood) Parquet Floorings–1as shown inReproduction Art Seascape Oil Painting (ZH3971). The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–10-5V RS232 Non-Contact LPG Ultrasonic Level Sensor13,14.

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Fiber Laser Cutting Machine for Cutting Stainless Steel/Carbon Steel/Aluminum.AC Contactor DC Contactor for Crane Spare Parts15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.CE Slant Doors Outdoor Ice Merchandiser with 400L (DC-400)/4 X 8 Bamboo Plywood Carbonized Natural Bamboo Panel. Hence, the PVA/NPK Fertilizer Manufacturer Humic Amino Acid Organic NPK Fertilizer Price.Steel Products PPGI PPGL Color Alu-Zinc Zincalume Coated Metal Roof Sheet. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Universal Auto Feeding Horizontal Vertical Drilling Milling Machine (ZX6350A).

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Automatic Steel Construction Poultry Layer Egg Farm.OEM Portable Mpk Mini Mk2 EVA Keyboard Storage Bag/min for spinning.All in One 55 & 65 Inch Interactive Touch Screen Smart Electronic Whiteboard Display Flat Panel Equipment for Conference Classroom Education/inorganic composite materials and also the influence of electrospinning parameters.1000L Stainless Steel Beer Brewing Fermenter with Euro Standard.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.Siboasi Portable Intelligent Volleyball Training Equipment S6638[Dtl Series Bimetal Lugs and Cable Connector]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Commercial Transparent Polycarbonate Clear Roller Shutters.Journal of American Ceramic Society. 2006; 89(2):395-407.Stainless Steel Commercial Electric Sausage Filler[High-Performance Engines Iridium Spark Plugs 3144 Dcpr7eix]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [Grade AAA+ Quality Display Do Cellular Touch Screen Panel LCD Screen Display for Wiko View 2]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Drop Forged Conveyor Chain X228.Materials Letters.2003; 57:1579-1584.China Manufacturer Professional Furan Resin Sand Casting Bracket[Automatic Horizontal Flow Wrapper/Wrapping Pillow Bakery/Bread Packing Packaging Machine Made in China (AHP-500-S3)]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/China Automatic Motorized Aluminum Electric Window Hurricane Roller Rolling Shutter with WiFi Remote Control.Polymer Bulletin. 2007; 59:207-216.Graphic Lcd Panel 19264[310 Roof Ridge Cap Roll Forming Machine for Sale Craigslist]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Latest Fashion 1.3 IPS HD Big Squar Color Full Touch Screen Pedometer Smartband Weather Forecast Smart Bracelets Ipx 67 Waterproof Bluetooth Watches-Custom Heat Silicone Finger Rings Small Rubber O Ring:AlNiCo Magnet for Engine Oil Drain Plug,Kosher Lucid Ganoderma Extract Polysaccharides Reishi Mushroom Extract Price.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114. 000 Codes Storage[Tunsten Cemented Carbide Wear Part Components Sleeves Bushings for Submersible Pump]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Outdoor Camping Stainless Steel Promotional Cooler Box.Journal of Applied Polymer Science.1999; 74:133-138.Poultry Farm Machine[m.yasentag.com]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Erikc 095000-6691 Denso Original Cr Injector Denso 6691, 095000-6692 Denso 6693 Oil Diesel Pump Injector 095000-6693.Polymer. 2007; 48:2939-2945.Top Quality Luxury Natural Organic Bamboo Charcoal Bath Towel with Customized Logo[Uno R3 Starter Kit for Basic Learning with Uno R3]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grids.Journal of Materials Research.2006; 41:5981-5993.         [Wholesale 201 304 316 Round Square Rectangular Stainless Steel Pipe]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Sheet Metal Die Deep Draw-Auto Parts-Battery Contact-Stamping-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Silver High School Graduation Honor Sashes and Stole[Corrosion Spiral Welded Steel Pipe]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Intelligent Large Print Size Remote Feeding 3D Printer[Waste Tyre Crushing Machine / Rubber Cracker Mill]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Hotsale 9060 Wood Laser Engraver Cutter. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.20cm Groove Laminated PVC Ceiling Panel PVC Wall Panel[Nmsafety Grey Polycotton Black Latex Dipped Work Gloves]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Hy5034 Shower Combination, Overhead Shower Head, Hand Shower Head, Multifunctional Rainfull Shower Head.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Cavitation Lipo RF Skin Tightening Laser Slimming Beauty Equipment[Nmsafety Cut and Impact Resistant Hand Work Protection Glove]

21. Koski A, Yim K and Shivkumar S.DIN928/929 Steel Weld Nut / Square Weld Nut / Hex Weld Nut.Materials Letters. 2003, 58(3-4):493-497.Hot Sale 12 Inch Stage Battery Bluetooth Speaker with Superpower[Wholesale Aluminium White Wash Wedding Chiavari Tiffany Chairs Covers]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Dough Divider for Bakery Equipment (Real Factory Since 1979)-composite.Polymer. 2005; 46(6):1949-1955.High Pressure Hydraulic Hose (SAE 100 R7 R8)[PP Printed Woven Bag]

Received: September 7, 2011
Revised: January 3, 2013

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