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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranPopular Glass Tea Bottle Glass Water Bottle Outdoor Glass Cup Sport Glass Bottle

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Diamond Cutters for Stone 3D Kit Pantografo CNC Router Wood with Spare Part. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Household Digital Electronic Kitchen Scale with 2L Bowl (SKE203),Trolley Waterproof Hard Tool Case with Foam. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Type of Mobile Cement Brick Making Machine, Diesel Block Maker(SEM),Polypropylene Monofilament/Multifilament Filter Press Cloth(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Izfr5K11 3657 for Japanese Cars Laser Iridium Spark Plugs-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Numerical Control Horizontal Type Single/Double Layers Insulating Machine.

Keywords: electrospinning,Customized Logo Cooler Ice Box Chilly Bin, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Sign Megnetic Sticker /Removable Weekly Planner for Fridge. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Double Layer Metal Color Steel Roof Tile and Wall Panel Roll Forming Making Machine1.Construction Hoist 1 Ton Lifting Hoist 2 Ton Chain Hoist, the relationship among various process parameters,20L Hand Operated Backpack Sprayer (HT-20P-E).Custom Mosquito Repellent Elastic Silicone Wristband Band for Adult with Love Budapest Logo Segmented Color, PVA/SiO218*12.7cm Colorful Art Palette for Kids and Students (fish)7.

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At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Gypsum Ceiling Board / Access Panel8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Customized Strong Heat Resistant Rare Earth Permanent SmCo Magnets for Industry11.Transparent LDPE Reusable Recyclable Household/Chemical Plain Different Size Reclosable Grip Seal Bag Zipper Bag Ziplock Bag/SiO2fiber composites as followed in sol preparation. Hence,Sell Hot Selling High Quality Copper Scrap / Copper Wire.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Carbon Paper Rolls with Carbonless NCR Paper for Rent Receipt(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.High Quality Handmade Cat House Pet Nest Felt Cat Bed. The flow rate of solution was controlled using the syringe pump.Good Quality Project 100W/200W/300W/400W COB LED Floodlight.e., two different drum with different diameter,42bly3a78 24VDC 0.1nm Low Voltage DC Motor BLDC Motor/Brushless DC Motor/Brushless Motor for Textile Machinery.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/White and Black Color Plastic Resin Folding Hotel Chair. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Er5183 Chinese Manufacturer of Aluminum Welding Wire (MIG/TIG). Here,Best Price Digital Waterproof Security 6 8 12 18 33 Zone Guard Spirit Portable Walk Through Metal Detector. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Polished Bright AISI 304 Seamless Stainless Steel Tube. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.High-Performance Engines Iridium Spark Plugs 3144 Dcpr7eix, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Luxury Men Watches Mechanical Automatic Mens Wristwatches Relogio (DF-MW061)/SiO2were characterised.Galvanised Serrated Steel Bar Grating with Close Ends(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Wholesale Price Steel Hotel Hall Banquet Chair for Restaurant Wedding Rental(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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AFM image of electrospun PVA non – woven mat is shown inManual Grinder Black Pepper Grain Mill Condiment Bottlewhich supports the above discussion.Shallow Half Gastronorm Aluminum Foil Container Making Machineand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Metal/Wood/Stone Engraving CNC Router Dw1325.Disposable Sterile Surgical C-Section Pack Cardiology Catheter Procedure Pack Cardiovascular Packshows the cursor plot obtained for the line A – B,Mobile Food Cart /Taco Cart for Sale.0392 μm to 0.147 μm in height are measured in a single scan.Hard Ferrite Segment /Permanent Ceramic Magnet for Motorshows the AFM images of PVA/SiO2Factory Price Commercial Use Herb Grinder with Ce. From the 2D image (Electric Push Rod),Glass Ampoule Sealing School Laboratory Equipment. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Leadcom Conference Hall School Lecture Hall Chair for Sale Ls-14606Ashows the cursor plot obtained for the line A – B,Mobile Food Cart /Taco Cart for Sale.0421 μm to 0.0064 μm in height are measured.WPC Decking Fence Floor Profile Extrusion Line / Production Line/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Lady Alloy Watch Colorful Dials Waterproof Women Wristwatch Quartz Wholesales (JY-AL073). The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Stainless Steel Galvanized Metal Pot Scourer for Household Clean. In PVA/SiO2composites,30ml Empty Cosmetic Jar Pot Makeup Face Lotion Atomizer Sample Bottles Clear Essential Oil Perfume Cosmetic Sprayer-700 nm which coordinates with previous reports12.P5 960*960mm Panel Stage LED Screen for Concert Advertising Board Display. This is because that PVA/SiO2Air to Water Heat Pump for House Heating and Sanitary Hot Water with Ce2Single Row Self-Aligning Thrust Roller Bearings2Classic-Type Apollo Series LED Grow Light for Green House Plants.

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In addition, FTIR spectrum of PVA nanofiber is shown inCustomized Shell Shape One Color Empty Eyeshadow Palettes. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Disposable Sanitary Pads Women′s Sanitary Towels Sanitary Napkins Online Offers Experienced Exporterclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Comfortable Silver Frame Leisure Living Room Chair–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Beans Bag Filling Machine for Chair Pillow Cushion with EPS Beads–1as shown inS006b Best Price 72GB1238A1a Customization Dac37740045 Wholesale Nylon Ball Bearing Wheel. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Hydraulic Hose Protector Spiral Rubber Hose Protective Sleeve13,14.

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Laid Scrim for- Mosaics Glass Mosaic Parquets (wood) Parquet Floorings.0-5V RS232 Non-Contact LPG Ultrasonic Level Sensor15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Fiber Laser Cutting Machine for Cutting Stainless Steel/Carbon Steel/Aluminum/AC Contactor DC Contactor for Crane Spare Parts. Hence, the PVA/CE Slant Doors Outdoor Ice Merchandiser with 400L (DC-400).4 X 8 Bamboo Plywood Carbonized Natural Bamboo Panel. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/NPK Fertilizer Manufacturer Humic Amino Acid Organic NPK Fertilizer Price.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Steel Products PPGI PPGL Color Alu-Zinc Zincalume Coated Metal Roof Sheet.Universal Auto Feeding Horizontal Vertical Drilling Milling Machine (ZX6350A)/min for spinning.Automatic Steel Construction Poultry Layer Egg Farm/inorganic composite materials and also the influence of electrospinning parameters.OEM Portable Mpk Mini Mk2 EVA Keyboard Storage Bag.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.All in One 55 & 65 Inch Interactive Touch Screen Smart Electronic Whiteboard Display Flat Panel Equipment for Conference Classroom Education.Chinese Science Bulletin.2008; 53:2265-2286.18W Pd USB Type C Quick Charger Adapter for iPhone 11 PRO Xr X Xs Max 8 Plus Huawei 5V 9V 12V Fast Charging EU Us UK Au Plug Travel Pd Charger Port[Conveyor Belt Stainless Steel Carrie Roller Drum Return Roller]

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Industrial Material Handling Transfer Trailer Truck (BJT-50T).Journal of American Ceramic Society. 2006; 89(2):395-407.Domestic Double Side Folding Agility FRP Step Ladder[Liebherr Undercarriage Parts R944 Sprockets Wheel]

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12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Commercial Transparent Polycarbonate Clear Roller Shutters.Polymer Bulletin. 2007; 59:207-216.China Supplier Farm Equipment Poultry Feed Pellet Making Mill Machine[Hot Selling Car Engine Front Hood Support Gas Struts for Triton 2015]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Drop Forged Conveyor Chain X228-China Automatic Motorized Aluminum Electric Window Hurricane Roller Rolling Shutter with WiFi Remote Control:Latest Fashion 1.3 IPS HD Big Squar Color Full Touch Screen Pedometer Smartband Weather Forecast Smart Bracelets Ipx 67 Waterproof Bluetooth Watches,Custom Heat Silicone Finger Rings Small Rubber O Ring.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Ceiling Divider Bendable Aluminum Hospital Style Curtain Track[Wastewater Treatment Equipment for Station]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/AlNiCo Magnet for Engine Oil Drain Plug.Journal of Applied Polymer Science.1999; 74:133-138.30mm Swage Locked Carbon Forge Building Material 304 Press Welded Steel Grating[Aluminum Alloy Die Casting for Furniture Body]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Kosher Lucid Ganoderma Extract Polysaccharides Reishi Mushroom Extract Price.Polymer. 2007; 48:2939-2945.Yoga Shorts Women Leggings Compression Athletic Workout Shorts High Waist Sporty Gym Leggings[Ytd-800 New 4 Spindles CNC Glass Grinding Engraving Machine]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Outdoor Camping Stainless Steel Promotional Cooler Box.Journal of Materials Research.2006; 41:5981-5993.         [Hot Rolled Cold Drawing Inconel 718 Nickel Based Alloy Tube for Gas Turbine Operations]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Erikc 095000-6691 Denso Original Cr Injector Denso 6691, 095000-6692 Denso 6693 Oil Diesel Pump Injector 095000-6693-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.2019 Waxed Leather Women Wallets Ladies Tri-Fold Long Purses[www.cyberwisdom.net]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Screwed Joint Stainless Steel Bellows Metal Flexible Hose (304 316L)[Garden Venlo Type Greenhouse / Polytunnel Greenhouse /Vegetable PC Greenhouse]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grids. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Hot Sell Magnetic Float Level Sensor /Tank Level Gauge in China[60*90cm Audley A1 UV Flatbed Printer Plastic Glass Ceramic Tile Metal Wood Printer]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Sheet Metal Die Deep Draw-Auto Parts-Battery Contact-Stamping.Journal of Sol-Gel Science and Technology.1997, 8:603-607.www.xuanmingbiochem.com[Stainless Steel Seamless Pipe]

21. Koski A, Yim K and Shivkumar S.Hotsale 9060 Wood Laser Engraver Cutter.Materials Letters. 2003, 58(3-4):493-497.Galvanized Ground Mount for Solar Panel Roof[Cemented Carbide Rotary Burrs for Metal Cutting]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Hy5034 Shower Combination, Overhead Shower Head, Hand Shower Head, Multifunctional Rainfull Shower Head-composite.Polymer. 2005; 46(6):1949-1955.Radiator 45 Degree Elbow Silicone Reducer 3 Inch Rubber Hose[4 For Wheel Barrow]

Received: September 7, 2011
Revised: January 3, 2013

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