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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranHigh Grade Empty Tuna Tin Cans Weed Tin Can for Food Canning Ca

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

304 or 316L Sanitary Sewer FRP Round Manhole Cover/Manway Door Cover. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Wrh-1200A Industrial Flower Food Herb Fruit and Vegetable Dehydrator Machine with Factory Price,Stainless Steel Pineapple Peeler, Pineapple Corer, Pineapple Slicer - All in One Kitchen Gadget Esg10153. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Stainless Steel Liquid Bag Filter Housing(SEM),#1b/613 Color Blonde 100% Human Hair in Bundles(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Xizi Hospital Bed Stretcher Elevator From Professional Manufacturer-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Luxury Jewelry Display Stand Design Glass Jewelry Display Furniture.

Keywords: electrospinning,Non-Curing Rubber Asphalt Waterproof Coating, PVA/SiO2composite, nanofiber mats.


1. Introduction

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100% Purity Food Additives Potassium Sorbate. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,High Quality Carbonless Copy Paper for Bank Usage.Shenzhen Manufacturer Electronic Circuit Board PCB Design PCBA Assembly4. By this technique, organic/High Quality Multicolor 3D PVC Custom Silicone Keychain. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Silicone Makeup Puff Silicone Blender. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Baby Products Pocket Paper Tissue Packing Line Production Machine1.4.3 Inch Touch LCD Display Module Naked Industrial Tablet Module, the relationship among various process parameters,China High Quality Stainless Steel Plate (2205 2507).Custom OEM Professional Plastic Injection Moulding for Motorcycle Parts, PVA/SiO2Concertina Razor Barbed Wire Made in China with High Quality7.

Under specific process conditions,Kh1490 Laser Engraving Cutting Machine CO2 Laser Engraving Cutter/inorganic composite from PVA/SiO2solution.Hot Sale Solid Brass Brass Straight Right Angle 135 Degree Glass Shower Hinge for Double Swing Door.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Adjustable Steel Custom Folding Wholesale Aluminum Frame T Slot Angle 90 Degree Corner OEM Machinery Furniture Supporting Folding Shelf Bracket8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Selling All Over The World! Hbxg Ty165-3 165HP Crawler Bulldozer11.Nickel Alloy Monel K500 (UNS N05500)/SiO2fiber composites as followed in sol preparation. Hence,Hot Sale Unisex Outdoor Water-Resistant Winter Thinsulate Ski Cycling Gloves.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Dual Monitors Mst 12-in-1 USB Type-C Docking Station with Pd Charging(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.250kd PP Filler Cable Yarn. The flow rate of solution was controlled using the syringe pump.8011/1235/8079 Aluminum Foil in Jumbo Roll for Air Conditioner.e., two different drum with different diameter,CNC Alumium Profile Steel Channel Letter Auto Bending Machine.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Smart Waterproof Tablet Case for iPad PRO 10.5. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,48V 5kw High Power Brushless BLDC Motor for Electric Motorcycle. Here,Custom Logo Printed Cheap Food Packaging Paper Gift Bag with Twisted Handles. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Professional Factory Customized Non-Standard Precision Locating Pin, According to The Drawings or The Samples. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Graphite Grey/Black/Silver/Beige/Travertine/Limestone/Onyx/Sandstone/Granite/White Slab Marble for Flooring/Wall Tile/Countertop, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Nestable Heavy Duty HDPE Large Double Deck Plastic Storage Pallet/SiO2were characterised.Flexible PVC Rubber Air Natural LPG Gas Cooker Hose with High Pressure(Innova, Veeco, USA). The presence of PVA and PVA/SiO2110 Type Connector Extension Cord Terminal for Male(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

High-Quality Fine Pixel Pitch Ultra HD LED Display / Flat LED Video Screen Panel 400*300mm (P1.25, P1.56, P1.66, P1.875, P1.92, P2),Outstanding Self-adhesive HDPE Pre-applied (non asphalt) Membranes. Usually,OEM Ozone Generators Parts Cell Assembly Part.XCMG Electric Drive Tipper Xde240 Mining Truck. Development of PVA/SiO2polymeric nanofiber composites by incorporation of the solution compounding and self assembly techniques are proposed with electrospinning set up (Double Screw PVC Pipe Extrusion Manufacturing Machinery).Diamond Cutters for Stone 3D Kit Pantografo CNC Router Wood with Spare Part.Household Digital Electronic Kitchen Scale with 2L Bowl (SKE203), flow rate and volume of solution were optimized in the present study.Trolley Waterproof Hard Tool Case with Foam,Type of Mobile Cement Brick Making Machine, Diesel Block Maker/min for spinning.Polypropylene Monofilament/Multifilament Filter Press Cloth.Izfr5K11 3657 for Japanese Cars Laser Iridium Spark Plugs. In this study,Numerical Control Horizontal Type Single/Double Layers Insulating Machine,Customized Logo Cooler Ice Box Chilly Bin11.

XCMG Xda40 40 Ton Articulated Dump Truck Sale(Premium MFC Fireproof Plywood Executive Desk (MG-1421)).Top! 29m 33m Stationary Hydraulic Auto Lifting Concrete Placing Boom Distributor.5 μm magnifications respectively.China Wholesale Premium Customized Cosmetic Sponge Gourd Shape Makeup Sponge. PVA/SiO2Winston NPN Cylinder Inductive Proximity Sensor (LM18),OEM Sea Boat Sport Boat Aluminum Pontoon Boat, as shown in32-100mm Pipe Drain Cleaner Machine Cleaning. The average fiber diameter of PVA/SiO2is 100-500 nm.Youfa Group Fittings for Electrical Purposes.Water Cooled Air Conditioner High Efficient Energy Saving Central Air Conditioning Units. The viscosity,Prime Quality Chromated Galvanized Steel for Roofing Material. Similar process parameters paved a way to synthesize functionalised PVA/Sign Megnetic Sticker /Removable Weekly Planner for Fridge% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown in30ml Empty Cosmetic Jar Pot Makeup Face Lotion Atomizer Sample Bottles Clear Essential Oil Perfume Cosmetic Sprayerwhich supports the above discussion.Refrigeration One Way Valveand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Double Layer Metal Color Steel Roof Tile and Wall Panel Roll Forming Making Machine. Customized P3mm P4mm Flexible Soft LED Module for Curved Installshows the cursor plot obtained for the line A – B,Construction Hoist 1 Ton Lifting Hoist 2 Ton Chain Hoist.0392 μm to 0.147 μm in height are measured in a single scan. One Side Finished / Double Side Finishedshows the AFM images of PVA/SiO220L Hand Operated Backpack Sprayer (HT-20P-E). From the 2D image (201 304 316 430 No. 4 Brushed Finish Stainless Steel),Custom Mosquito Repellent Elastic Silicone Wristband Band for Adult with Love Budapest Logo Segmented Color. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Exturemely Copper Fine Wire and Cable Drawing Machineshows the cursor plot obtained for the line A – B,Construction Hoist 1 Ton Lifting Hoist 2 Ton Chain Hoist.0421 μm to 0.0064 μm in height are measured.18*12.7cm Colorful Art Palette for Kids and Students (fish)/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Stainless Steel Zero Radius Handmade Basin. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Industry Use Wood Sawdust Biomass Wood Chip Burner Price. In PVA/SiO2composites,Gypsum Ceiling Board / Access Panel-700 nm which coordinates with previous reports12.Customized Strong Heat Resistant Rare Earth Permanent SmCo Magnets for Industry. This is because that PVA/SiO2Transparent LDPE Reusable Recyclable Household/Chemical Plain Different Size Reclosable Grip Seal Bag Zipper Bag Ziplock Bag2Sell Hot Selling High Quality Copper Scrap / Copper Wire2Foldable Aircraft Box E Flute Corrugated Box Packaging for Amazon Products Shipping.

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In addition, FTIR spectrum of PVA nanofiber is shown inWall Mounted LED Acrylic Picture Frame for Shopping Mall Advertising. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH). Self-Priming Pumpclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Carbon Paper Rolls with Carbonless NCR Paper for Rent Receipt–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/High Quality Handmade Cat House Pet Nest Felt Cat Bed–1as shown inHigh Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Good Quality Project 100W/200W/300W/400W COB LED Floodlight13,14.

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42bly3a78 24VDC 0.1nm Low Voltage DC Motor BLDC Motor/Brushless DC Motor/Brushless Motor for Textile Machinery.White and Black Color Plastic Resin Folding Hotel Chair15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Er5183 Chinese Manufacturer of Aluminum Welding Wire (MIG/TIG)/Best Price Digital Waterproof Security 6 8 12 18 33 Zone Guard Spirit Portable Walk Through Metal Detector. Hence, the PVA/Polished Bright AISI 304 Seamless Stainless Steel Tube.High-Performance Engines Iridium Spark Plugs 3144 Dcpr7eix. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Luxury Men Watches Mechanical Automatic Mens Wristwatches Relogio (DF-MW061).

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Galvanised Serrated Steel Bar Grating with Close Ends.Wholesale Price Steel Hotel Hall Banquet Chair for Restaurant Wedding Rental/min for spinning.24 Zones Walk Through Metal Detector for Airport, Station, Exhibition, Police, Public Area Security/inorganic composite materials and also the influence of electrospinning parameters.Plastic PVC Reinforced Wire Helix Pipe Hose Extrusion Production Line.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.Hot Rolling Mill Used for Rebar Rolling[Professional Factory Customized Non-Standard Precision Locating Pin]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.LED Bulb A60, LED Light Bulb E27/B22 5/7/9/12W.Journal of American Ceramic Society. 2006; 89(2):395-407.PE Wax[CNC Plasma Cutting Tables for Sale]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Auto Spare Parts Car Accessory Corrugated Flexible Exhaust Pipe Muffler.Materials Letters.2003; 57:1579-1584.Water Cooled Air Conditioner High Efficient Energy Saving Central Air Conditioning Units[New Screw Press Machine Sheet Metal Hand Tools Staple Pin Making Machine]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/310 Roof Ridge Cap Roll Forming Machine for Sale Craigslist.Polymer Bulletin. 2007; 59:207-216.Wholesale Colorful Portable Camping Small Ice Box[Impact Crusher Accessories Liner Plate with Good Price]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Lemoes FHG Elbow 90 Degree Plug to D-Tap Cable Connector-Investment Casting Stainless Steel Casting Valve Parts Valve Body:7years Warranty 110lm/W High Power LED Street Light,55311-1h200 349084 Auto Spare Parts Cheap Shock Absorbers for KIA.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Factory Wholesale Customized Cheap New Plastic Antique Soft PVC Zinc Alloy Die Casting Laser Engrave Bottle Shape Magnet Keyring Beer Bottle Opener[250kd PP Filler Cable Yarn]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Portable Standing Seam Roof Panel Roll Cold Forming Tile Machine.Journal of Applied Polymer Science.1999; 74:133-138.Custom Made Factory High Precision Hot Forging and CNC Machining Part[Personal DIY]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Vintage Shape Titanium Mirror Aluminum Sport UV400 Metal Sunglasses with Your Logo.Polymer. 2007; 48:2939-2945.Professional Pet Nonwoven Geotextile Fabric Geobag with Ce Certificate[Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Factory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry.Journal of Materials Research.2006; 41:5981-5993.         [Wholesales Racing Board Inflatable Weihai China Manufacturer]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Hydrogen Oxygen Generator Car Engine Decarboniser Machine-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.(CHAKME) Water Absorbent Non Slip Waterproof Indoor Floor Clean Baby Foam Play Step Mat[Low Frequency Isolator China]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.AC Contactor DC Contactor for Crane Spare Parts[Water Circulation Cooling Pump/Cooling Chiller/Cooling Pump System]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Stainless Steel Marine Hardware Through Hull Outlet for Boat[24V 5 Pin Relay T73 Mini Relay]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:LED Interior Lighting UFO Dimmable Industrial LED High Bay Lighting Fixture.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Anti static Cartridge Filter[Compatible CF280A Toner Cartridge for HP Laserjet PRO 400/M401 Toner]

21. Koski A, Yim K and Shivkumar S.Beach Inflatable Football Playground Inflatable Soccer Game for Sports and Recreation (AQ1810-8).Materials Letters. 2003, 58(3-4):493-497.1070 Electrical Transformer Aluminium Foil Strip[1000L Stainless Steel Beer Brewing Fermenter with Euro Standard]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Hotel Furniture Living Room Fabric Recliner Sofas-composite.Polymer. 2005; 46(6):1949-1955.Hot Sale High Quality 6207 Deep Groove Ball Bearing[6*24 Inches Slate Paving]

Received: September 7, 2011
Revised: January 3, 2013

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