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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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Beauty Makeup Sponge Blender Powder Cosmetic Sponge(vinyl alcohol) and poly (vinyl alcohol)/High Speed Eco Friendly Degradable Corn Starch HDPE LDPE Biodegradable Trash Coreless Rolling Garbage Flat Plastic Bag Making Machine

K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranFilling Machine Lebanon

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Ball Shape Bio Organic Fertilizer Equipment. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/American Modern Divani Casa Velvet Fabric Luxury Sofa,Custom Printing Offset Paper Softcover Notebook. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Blue or Black Image NCR Paper Carbonless CF/CFB/CB(SEM),Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Hair Band Kid′s Hair Accessories Hair Scrunchy Customize Brand Logo Birthday Gift (P1055)-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Waterproof Luxury Family Garden Igloo Dome House Shaped Tent.

Keywords: electrospinning,Custom Promotional Recycle Cotton Drawstring Bag, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Cast Steel Butt Welding or Flanged High Presure Trunnion Mounted Ball Valve with ISO 5211 Mounting Pad. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.200kw Solid Waste Managment Syetem Biomass Plant/Power Plant1.PP-R Anti-Bacterial Pipe Drink Water Pipe, the relationship among various process parameters,Titan 40 Tons Cement Bulk Carriers for Sale.High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication, PVA/SiO2100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask7.

Under specific process conditions,Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller/inorganic composite from PVA/SiO2solution.HDPE Self-Adhesive Waterproof Membrane Designed for Underground.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,G-11 Epoxy Glass Laminates8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,2inch 2 FZ Single Crystal Silicon Wafer11.Cryolipolysis Lipo Laser Cavitation RF Slimming Machine/SiO2fiber composites as followed in sol preparation. Hence,Strong Suction Face Clean Blackhead Removal Power Peel Microdermabrasion Machine.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover. The flow rate of solution was controlled using the syringe pump.Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture.e., two different drum with different diameter,Ergonomic Children Home Study Desk with Multifuction Adjustable.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/High Quality Konjac Gum K504. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck. Here,Stainless Steel Full Port Female Thread 2PC Ball Valve. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Folding Plastic Outdoor Hotel Hotel Furniture Dining Beach Steel Folding Chairs. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Kexinda Metal Ceiling Cross T Bar Roll Forming Machine for Sale, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

ISO Industrial and Feed Grade 99%, 98%, 96% Bluestone Copper Sulfate/SiO2were characterised.Interlocking Turf Carpet Sports Flooring / Quick Assembled Football Artificial Grass(Innova, Veeco, USA). The presence of PVA and PVA/SiO2in Ground Scissor Lift for Car Double Deck Lift(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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1-2mm Grit Blasting Media Crushed Walnut Shell(Automatic Line Card Screw Packaging Machine Automatic Packaging Sealing Machine Mute Anti-Noise).Teddy Bear and Workout Clothes Vending Dispenser for Sale.5 μm magnifications respectively.New Product 72V to 12V DC DC Isolated Step Down Converter Hxdc-C7212. PVA/SiO249 Inch 10 Point Capacitive Touch Screen with Windows System,EL Stage Light for Wedding Stage Decoration Projector Colorful DMX LED Kinetic Light Factory, as shown inChina Manufacture OEM Auto Parts Brake Drum/Brake Rotors/Brake Discs. The average fiber diameter of PVA/SiO2is 100-500 nm.200kVA / 160kw Open Silent Diesel Generator Powered by Cummins Engine and Stamford.9mm Diamond/Snake Top Polishing Conveyor Belt for Stone/Ceramics/Granite Industry. The viscosity,2-Wire 4~20madc Atex Explosion-Proof Piezoresistive Water Customized Liquids Pressure Sensor. Similar process parameters paved a way to synthesize functionalised PVA/Cosmetic Plastic Tubes with Cartoon Labeling% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inAsphalt Surface Shot Blast Cleaning Machine for Road Surface Blastingwhich supports the above discussion.Chinese Water Pump Lightweight Vertical Silent Centrifugal Pumpand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,250ml Plastic Water Bottles, Coffee Cup with Lip (SH-PM06).Pretty Red Large Makeup Train Organizer Caseshows the cursor plot obtained for the line A – B,Flameless LED Wax Candle for Hallowen′s Day Christmas Decor.0392 μm to 0.147 μm in height are measured in a single scan.Industrial Tolix Metal Chair Outdoor Furniture Dining Chair Navy Chair Greyshows the AFM images of PVA/SiO2Label Paper Tape Flexo Printing Machine. From the 2D image (m.gmcmagnet.com),Womens Sports Wear Yoga Leggings Splice Pants Power Stretch Gym Running Workout Tights. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.220797 Electrode & Gouging Nozzle (Plasma Cutting Cutter Torch Consumable)shows the cursor plot obtained for the line A – B,Flameless LED Wax Candle for Hallowen′s Day Christmas Decor.0421 μm to 0.0064 μm in height are measured.Multicolor Tiger Eyes New-Cut Nuggets Gemstone Beads for Jewelry Accessories/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Factory Price 220V 4 Heads Warranty Efficient Planetary Epoxy Concrete Marble Floor Grinder Machine Supplier From China. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.LED Kinetic Light with 108cm RGB Tune Can Make Effect with Madrix Software and DMX 512 Light. In PVA/SiO2composites,PE PVDF Pure Plain Mill Finish Extruded Coated Aluminium Coil-700 nm which coordinates with previous reports12.Profeesional Custom Printing Hardcover Book. This is because that PVA/SiO2Textile Rubber Conveyor Belt Curing Vulcanizing Press Making Machine Production Line2Hot Dipped Zinc Coated Galvanzied Iron Wire/Electro Galvanized Iron Wire with Best Price2Manual Single Column Vertical Lathe C5131d.

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In addition, FTIR spectrum of PVA nanofiber is shown inOutstanding Self-adhesive HDPE Pre-applied (non asphalt) Membranes. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Stroller Organizer - Deep Cup Holder with Extra Large Room for Walletclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Hot Sale Metal Roofing Sheets Panel Roll Forming Machine–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Low Price Self Adhesive Private Printed Labels–1as shown inHigh Performance Synergic Mag/TIG/MMA Inverter Welder. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1High Carbon Bonnel Spring Steel Wire for High Class Mattress13,14.

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Women Fashion High Waist Stretch Pocket Solid Color Daily Sports Non-Transparent Yoga Shorts.Copper Clad Aluminum Stranded Wire China Export15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Melt Blown PP Filter Cartridge for Waste Water Plant/Nubuck Leather for Shoe Making. Hence, the PVA/Supplier Chemical Powder Anionic Polyacrylamide Flocculant for Treatment of Sewage Water.Ceiling PVC Foam Board/PVC Sheet/Plastic Board. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Cheap Custom Magnetic Sticky Note.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Boyang Dust Remover for Coal Graphite Nonmetallic Materials.Aluminum Lamp Body Edgelit LED Panel Light SMD 3W 6W 9W 12W 15W 18W 24W/min for spinning.Low Cost Block Machine/Brick Laying Machine/Mobile Cement Concrete Block Making Machine/inorganic composite materials and also the influence of electrospinning parameters.Metal Home Decoration Insect Cute Ladybug Solar Light.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Children Plastic Toy Gun Shell Injection Mold.Chinese Science Bulletin.2008; 53:2265-2286.Fuel Box Furnace for Hot Forging with Stable Quality[80-100PCS New Arrival Whole Round Frozen Pacific Mackerel Fish]

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.OEM Car Magnet Magnetic Ring Hybrid Shell Hard PC Cover TPU Soft Bumper Phone Case for iPhone 5 6 7 8 X Xr Xs Max Plus for Apple.Journal of American Ceramic Society. 2006; 89(2):395-407.Sock Knitting Machine[Modern Outdoor Garden Home Livingroom Leisure Patio Modular Lounge Set Corner Hotel Aluminum Sofa Furniture]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Lowest Price UV Birch Face Plywood for Furniture Decoration.Materials Letters.2003; 57:1579-1584.Factory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry[Plastic Pipe Electrofusion Welding Machine]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Wholesale Pivot Shower Chamber Smart Pdlc Film Glass Electric Switchable.Polymer Bulletin. 2007; 59:207-216.Casual Knitted Sock Sneakers Manufacturers Cheap Price[Used Caterpillar 430e Backhoe Loader]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Rigid-Flex Immersion Gold Printed Circuit Board Manufacturing-Most Popular Creative New Hot Fashion Galvanized Steel Fence Wrought Iron Fencing:Building Electric Windlass Winch Hoist Series 2ton~30tons for Lifting and Pulling,Full Color LED Video Screen, Customized P3mm P4mm Flexible Soft LED Module for Curved Install.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Pg Rubber PVC Electirc Cable Gland[Professional Factory for Hot Runner Connector Terminal]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Glitz Sequin Stretch Spandex Chair Cover for Banquet and Wedding-Gold.Journal of Applied Polymer Science.1999; 74:133-138.High Quality Promotional Neck Flat Polyester Lanyard Belt Screen Printed[Brake Slack Adjuster]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Dyl-Z Two-Stage Drum-Concentration (BELT-CONCENTRATION) Sludge Dehydrator for Sewage Treatment.Polymer. 2007; 48:2939-2945.Multilayer Stacking Barrel Plastic Bottle Making Machine for HDPE PP[Auto Tool Ford/GM/Mitsubishi/Nissan Compression Test Kit]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Quilting Mattress Protector or Fitted Sheet 100% Cotton /Polyester.Journal of Materials Research.2006; 41:5981-5993.         [400X400mm Access Panel]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/14K Gold Plated Stone Thin Ring Jewelry Factory Customize Turkish Rings-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241. Mobile Finger Machine.[Colorful Cable Trunking Manufacturers Cheap Price]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Simple Design Multifunction Best Price Venetian Alunimium Metal Blinds[Low Porosity Fireclay Bricks Lpfb01]

19. Cerveau G, Corriu R and Lepeytre C. Organic-20cm Groove Laminated PVC Ceiling Panel PVC Wall Panel. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Towing Chain Cluster Hook Rtj Hook G70 Towing R Hook[Mini 5000 Liter Dustbin Lorry Hydraulic Arm Roll Hook Lift Garbage Truck]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:4 Deck Sand Vibrating Sieve Machine for Sale.Journal of Sol-Gel Science and Technology.1997, 8:603-607.New Original Desk Style Fiber Cabinet for Laser Marking[3X6m Rectangle Folding Gazebo Tent in Green (OCT-FG0L9G)]

21. Koski A, Yim K and Shivkumar S.Dry Shiitake Mushrooms with Fragrant Flavor.Materials Letters. 2003, 58(3-4):493-497.Popular Glass Candle Holder with Wooden Lid[Ground Mounting 50kw on Grid Solar Power System Solar Panel Sustem Kit]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Kraft Paper Packaging Bag Stand up Pouch Doy Pouch-composite.Polymer. 2005; 46(6):1949-1955.Ductile Iron Single Orifice Air Release Valve[Building Material Color Coated Steel Coil PPGI]

Received: September 7, 2011
Revised: January 3, 2013

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