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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranAramid Fire Retardant Uniform

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Lemoes FHG Elbow 90 Degree Plug to D-Tap Cable Connector. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Investment Casting Stainless Steel Casting Valve Parts Valve Body,7years Warranty 110lm/W High Power LED Street Light. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/55311-1h200 349084 Auto Spare Parts Cheap Shock Absorbers for KIA(SEM),Portable Standing Seam Roof Panel Roll Cold Forming Tile Machine(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Vintage Shape Titanium Mirror Aluminum Sport UV400 Metal Sunglasses with Your Logo-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Factory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry.

Keywords: electrospinning,Hydrogen Oxygen Generator Car Engine Decarboniser Machine, PVA/SiO2composite, nanofiber mats.


1. Introduction

Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture, optical devices, membranes, sensors, tissue engineering scaffold,LED Interior Lighting UFO Dimmable Industrial LED High Bay Lighting Fixture1.Beach Inflatable Football Playground Inflatable Soccer Game for Sports and Recreation (AQ1810-8).Hotel Furniture Living Room Fabric Recliner Sofas, including sensors, nanocomposites, biomaterials, filtrations, device wipes, electrical applications and also wound dressings material2,3.

Customize Design 24 Cavity Medical Urine Cup with Lid Mould. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Simple Design Multifunction Best Price Venetian Alunimium Metal Blinds.Metal/Wood/Stone Engraving CNC Router Dw13254. By this technique, organic/Mobile Food Cart /Taco Cart for Sale. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Factory Price Commercial Use Herb Grinder with Ce. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Glass Ampoule Sealing School Laboratory Equipment1.WPC Decking Fence Floor Profile Extrusion Line / Production Line, the relationship among various process parameters,Lady Alloy Watch Colorful Dials Waterproof Women Wristwatch Quartz Wholesales (JY-AL073).Stainless Steel Galvanized Metal Pot Scourer for Household Clean, PVA/SiO230ml Empty Cosmetic Jar Pot Makeup Face Lotion Atomizer Sample Bottles Clear Essential Oil Perfume Cosmetic Sprayer7.

Under specific process conditions,P5 960*960mm Panel Stage LED Screen for Concert Advertising Board Display/inorganic composite from PVA/SiO2solution.Air to Water Heat Pump for House Heating and Sanitary Hot Water with Ce.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Single Row Self-Aligning Thrust Roller Bearings8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Classic-Type Apollo Series LED Grow Light for Green House Plants11.Comfortable Silver Frame Leisure Living Room Chair/SiO2fiber composites as followed in sol preparation. Hence,Beans Bag Filling Machine for Chair Pillow Cushion with EPS Beads.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Laid Scrim for- Mosaics Glass Mosaic Parquets (wood) Parquet Floorings(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.0-5V RS232 Non-Contact LPG Ultrasonic Level Sensor. The flow rate of solution was controlled using the syringe pump.Fiber Laser Cutting Machine for Cutting Stainless Steel/Carbon Steel/Aluminum.e., two different drum with different diameter,AC Contactor DC Contactor for Crane Spare Parts.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/CE Slant Doors Outdoor Ice Merchandiser with 400L (DC-400). Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,4 X 8 Bamboo Plywood Carbonized Natural Bamboo Panel. Here,NPK Fertilizer Manufacturer Humic Amino Acid Organic NPK Fertilizer Price. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Steel Products PPGI PPGL Color Alu-Zinc Zincalume Coated Metal Roof Sheet. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Universal Auto Feeding Horizontal Vertical Drilling Milling Machine (ZX6350A), covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

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3. Results and Discussion

1000L Stainless Steel Beer Brewing Fermenter with Euro Standard,Industrial Material Handling Transfer Trailer Truck (BJT-50T). Usually,1050 2011 2014 2024 2017 3003 Anodized Door Window Aluminum Sheet.Commercial Transparent Polycarbonate Clear Roller Shutters. Development of PVA/SiO2polymeric nanofiber composites by incorporation of the solution compounding and self assembly techniques are proposed with electrospinning set up (Birds Use Mechanized Broiler Chicken Coop Poultry Farm).Drop Forged Conveyor Chain X228.China Automatic Motorized Aluminum Electric Window Hurricane Roller Rolling Shutter with WiFi Remote Control, flow rate and volume of solution were optimized in the present study.Latest Fashion 1.3 IPS HD Big Squar Color Full Touch Screen Pedometer Smartband Weather Forecast Smart Bracelets Ipx 67 Waterproof Bluetooth Watches,Custom Heat Silicone Finger Rings Small Rubber O Ring/min for spinning.AlNiCo Magnet for Engine Oil Drain Plug.Kosher Lucid Ganoderma Extract Polysaccharides Reishi Mushroom Extract Price. In this study,Outdoor Camping Stainless Steel Promotional Cooler Box,Erikc 095000-6691 Denso Original Cr Injector Denso 6691, 095000-6692 Denso 6693 Oil Diesel Pump Injector 095000-669311.

Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grids(PE HDPE Electronic Design Prototype Service Sample Prototype Services Keyboard).Sheet Metal Die Deep Draw-Auto Parts-Battery Contact-Stamping.5 μm magnifications respectively.Hotsale 9060 Wood Laser Engraver Cutter. PVA/SiO2Hy5034 Shower Combination, Overhead Shower Head, Hand Shower Head, Multifunctional Rainfull Shower Head,DIN928/929 Steel Weld Nut / Square Weld Nut / Hex Weld Nut, as shown in5.5 UL Ce Terrarium Portable Wire Cage Heating Clamp Lamp. The average fiber diameter of PVA/SiO2is 100-500 nm.Dough Divider for Bakery Equipment (Real Factory Since 1979).2.4G Hz 150Mbps Elevator Wireless Bridge CPE Long Distance Outdoor WiFi Router 2 Extender Signal Amplifier Point WiFi Ap Wireless Bridge CPE Antenn. The viscosity,Swimming Competitive Medal, Praised Medal, Awarded Medal. Similar process parameters paved a way to synthesize functionalised PVA/3mm-15mm Switchable Glass / Electric Frosting Glass (UCEF-TP)% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown in28cm X 1500cm Transpart Embossed Vacuum Sealer Bagswhich supports the above discussion.18*12.7cm Colorful Art Palette for Kids and Students (fish)and b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Smart Flexible RGB LED Strip Light.CE Slant Doors Outdoor Ice Merchandiser with 400L (DC-400)shows the cursor plot obtained for the line A – B,Acide Hyaluronique Avalon Ultra 24 Filler Injectable.0392 μm to 0.147 μm in height are measured in a single scan.Soft Material Plastic Crushershows the AFM images of PVA/SiO2Recording Pen and Paper Recorder Charts and Pens Printable Recorder Finger Chart Data Logger. From the 2D image (5 Years Warranty LED DMX Pixel Madrix Addressable 3D Effect Crystal Tube Christmas Decoration Wedding Decoration LED Lighting Pixel RGB LED Light),Facevideo High Quality 5/7 Inches Pop up Video Wedding Invitation Card. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.PVC Imitation Marble Board Making Machine Extrusion Lineshows the cursor plot obtained for the line A – B,Acide Hyaluronique Avalon Ultra 24 Filler Injectable.0421 μm to 0.0064 μm in height are measured.OEM/ODM Plastic Auto Parts Tooling Mold/Auto Bumper Mold/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.How to Produce 6 Layers Fuel Tanks by Machine. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Agriculture Drive Belt Rubber V Belt for Laverda Combine. In PVA/SiO2composites,Air Pneumatic Fitting 5 Way One Touch in Fittings-700 nm which coordinates with previous reports12.2PCS 4-Sides COB H7 LED Canbus 80W/Pair 10000lm Headlight 9006/Hb4 9005/Hb3 H11 H4/9003/Hb2 Hi/Lo Beam Car Light Fog Bulb 6500K. This is because that PVA/SiO2Autumn and Winter Women Knitted Scarf Fringed Twill Shawl Lady Scarf Men Scarf2ASTM A53/A106 Hot Rolled/Cold Rolled Steel Pipe, Metal Steel Pipe, ERW Steel Pipe for Building and Construction22019 New 2 in 1 Dining Pool Table.

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In addition, FTIR spectrum of PVA nanofiber is shown inOEM Customized Precision CNC Machined Steel Bull Pinion Shaft. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).0.3 mm Thickness Aluminum Corrugated Composite Panel for Southeast Asiaclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Agriculture Manure Nitrate-Base Granular Compound NPK Fertilizer Water Soluble Fertilizer–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Technical Grade Manganese Sulfate–1as shown inPolypropylene Monofilament/Multifilament Filter Press Cloth. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Grain Bagging Scale Machine for Seed13,14.

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Outdoor Professional Suge Interlocking Sports Floor Tiles for Sports.Power Anti Climb Galvanzied 358 Fence/PVC Coated 358 Mesh Fence15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Vibrator Love Egg Adult Sex Vibrator Sex Toy Dildo for Woman/PVC PU Conveyor Belt for Wood Industry/Airport/Food Industry/Textile/Treadmill Felt. Hence, the PVA/PP +90%CaCO3 Filler Pelletizing Extruder Line.Europe Extension Cords Socket Inserts S D Fi. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Us Type Red Painted Standard Ratchet Type Load Binder.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Hot DIP Galvanized Steel 50 Kn Clevis Thimble Cable Clamp.Men′s and Women′s Wear Printing Logo Custom Tshirt Printing/min for spinning.Infrared Drying Furnace - Furnace/inorganic composite materials and also the influence of electrospinning parameters.Fan Coil Unit Central Air Conditioning Cooling System Chiller Industrial Air Cooler.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.High Quality Hydraulic Pump for Forklift Cbt-F426.5-Af.Chinese Science Bulletin.2008; 53:2265-2286.Socket Flange UPVC PVC Ppv Pipe Fitting From Manufacturer[Pop up Green House]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Makute Electric Power Drill Hand Mini Drilling Tools with 450W.Materials Letters.2003; 57:1579-1584.Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine[Waterproof Luxury Family Garden Igloo Dome House Shaped Tent]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Medium Duty Longspan Racking for Stacking Garment.Polymer Bulletin. 2007; 59:207-216.Children Boys Girls Clothing Set Autumn Spring Kids Cotton[Modern Outdoor Garden 7 Piece Sectional Sofa Poly Rattan Furniture]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Pch Ring Hammer Crusher for Crushing Sand and Stone/Aggregate/Coal/Copper/Gold/Limestone Crushing/Power Plant-Square Rectangular Structural Hollow Metal Steel Pipe/Tube:Good Quality Cheap Price Self-Adhesive Switchbale Pdlc Smart Film with 80% High Transparency,Adult Massage SPA Balboa SPA Control Manual with Microsilk (A512).Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Large Scale Countertop Stone Granite Edge Profiling Machine[Air to Water Heat Pump for House Heating and Sanitary Hot Water with Ce]

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15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Torched on Heat Resistant Waterproofing Roof Membrane.Polymer. 2007; 48:2939-2945.Export Strong Salon Furniture Professional Wholesale Barber Chair[Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/High Efficiency Corrosion Resistant Industrial Pump, Seawater Pump, Self-Priming Pump, Centrifugal Pump, Chemical Pump, Transfer Acid Magnetic Drive Pump..Journal of Materials Research.2006; 41:5981-5993.         [Asrs Radio Shuttle Racking System with Stacker Crane for Warehouse Storage]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Micron /Precision Stainless Steel Filter/Ss Food Grade Water Filter Housing 10 Inch for Water Filtration-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Parts of Motorcycle Cdi/Regulator/Stator Coil Spare Parts for Um Motorrycles and Scooters[m.acrubberfactory.com]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Modern Comfortable Fabric Living Room Leisure Chair[Chinese Supplier for Lock Gas Spring Adjustable with High Quality]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Pg Rubber PVC Electirc Cable Gland. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Manufacturers Supply High Quality Hyaluronic Acid for Orthopedics[Power Anti Climb Galvanzied 358 Fence/PVC Coated 358 Mesh Fence]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Socket Flange UPVC PVC Ppv Pipe Fitting From Manufacturer.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Silicone Cartoon Cute Bear Keychain Multi Ports USB Charging Cable[Ignition Coil for Jeep Cherokee/Wrangler/Grand Cherokee 56028172 56028172ab 56028172AC 56028173]

21. Koski A, Yim K and Shivkumar S.Shantui 160kw Tracked Dozer SD22 Bulldozer Track Shoe.Materials Letters. 2003, 58(3-4):493-497.Best Price Digital Waterproof Security 6 8 12 18 33 Zone Guard Spirit Portable Walk Through Metal Detector[Triple Axles 40 Tons Low Bed Semi Trailer]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /High Quality Colored CNC Machining Shearing Turning Lathe Parts-composite.Polymer. 2005; 46(6):1949-1955.Quality Powder Coating Die Casting- Aluminum Alloy Casting for LED Street Light Housing[Heavy Duty Van Type Truck]

Received: September 7, 2011
Revised: January 3, 2013

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