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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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110 Type Connector Extension Cord Terminal for Male(vinyl alcohol) and poly (vinyl alcohol)/High-Quality Fine Pixel Pitch Ultra HD LED Display / Flat LED Video Screen Panel 400*300mm (P1.25, P1.56, P1.66, P1.875, P1.92, P2)

K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranChina Second Hand Dump Truck

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Outstanding Self-adhesive HDPE Pre-applied (non asphalt) Membranes. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/OEM Ozone Generators Parts Cell Assembly Part,XCMG Electric Drive Tipper Xde240 Mining Truck. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Diamond Cutters for Stone 3D Kit Pantografo CNC Router Wood with Spare Part(SEM),Household Digital Electronic Kitchen Scale with 2L Bowl (SKE203)(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Trolley Waterproof Hard Tool Case with Foam-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Type of Mobile Cement Brick Making Machine, Diesel Block Maker.

Keywords: electrospinning,Polypropylene Monofilament/Multifilament Filter Press Cloth, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Youfa Group Fittings for Electrical Purposes. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Water Cooled Air Conditioner High Efficient Energy Saving Central Air Conditioning Units1.Prime Quality Chromated Galvanized Steel for Roofing Material, the relationship among various process parameters,Sign Megnetic Sticker /Removable Weekly Planner for Fridge.Double Layer Metal Color Steel Roof Tile and Wall Panel Roll Forming Making Machine, PVA/SiO2Construction Hoist 1 Ton Lifting Hoist 2 Ton Chain Hoist7.

Under specific process conditions,20L Hand Operated Backpack Sprayer (HT-20P-E)/inorganic composite from PVA/SiO2solution.Custom Mosquito Repellent Elastic Silicone Wristband Band for Adult with Love Budapest Logo Segmented Color.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,18*12.7cm Colorful Art Palette for Kids and Students (fish)8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Stainless Steel Zero Radius Handmade Basin11.Industry Use Wood Sawdust Biomass Wood Chip Burner Price/SiO2fiber composites as followed in sol preparation. Hence,Gypsum Ceiling Board / Access Panel.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Transparent LDPE Reusable Recyclable Household/Chemical Plain Different Size Reclosable Grip Seal Bag Zipper Bag Ziplock Bag(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Sell Hot Selling High Quality Copper Scrap / Copper Wire. The flow rate of solution was controlled using the syringe pump.Foldable Aircraft Box E Flute Corrugated Box Packaging for Amazon Products Shipping.e., two different drum with different diameter,Carbon Paper Rolls with Carbonless NCR Paper for Rent Receipt.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/High Quality Handmade Cat House Pet Nest Felt Cat Bed. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Good Quality Project 100W/200W/300W/400W COB LED Floodlight. Here,42bly3a78 24VDC 0.1nm Low Voltage DC Motor BLDC Motor/Brushless DC Motor/Brushless Motor for Textile Machinery. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.White and Black Color Plastic Resin Folding Hotel Chair. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Er5183 Chinese Manufacturer of Aluminum Welding Wire (MIG/TIG), covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Best Price Digital Waterproof Security 6 8 12 18 33 Zone Guard Spirit Portable Walk Through Metal Detector/SiO2were characterised.Polished Bright AISI 304 Seamless Stainless Steel Tube(Innova, Veeco, USA). The presence of PVA and PVA/SiO2High-Performance Engines Iridium Spark Plugs 3144 Dcpr7eix(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

Luxury Men Watches Mechanical Automatic Mens Wristwatches Relogio (DF-MW061),Galvanised Serrated Steel Bar Grating with Close Ends. Usually,Wholesale Price Steel Hotel Hall Banquet Chair for Restaurant Wedding Rental.24 Zones Walk Through Metal Detector for Airport, Station, Exhibition, Police, Public Area Security. Development of PVA/SiO2polymeric nanofiber composites by incorporation of the solution compounding and self assembly techniques are proposed with electrospinning set up (4 X 8 Bamboo Plywood Carbonized Natural Bamboo Panel).Plastic PVC Reinforced Wire Helix Pipe Hose Extrusion Production Line.Zinc Cr Al Coating Low Carbon Steel Alloy Metal Stamping Parts, flow rate and volume of solution were optimized in the present study.Sliding Double Glass Door Roller/ Shower Door Roller Pulley,LED Bulb A60, LED Light Bulb E27/B22 5/7/9/12W/min for spinning.Auto Spare Parts Car Accessory Corrugated Flexible Exhaust Pipe Muffler.310 Roof Ridge Cap Roll Forming Machine for Sale Craigslist. In this study,Lemoes FHG Elbow 90 Degree Plug to D-Tap Cable Connector,Investment Casting Stainless Steel Casting Valve Parts Valve Body11.

7years Warranty 110lm/W High Power LED Street Light(High Definition Online Inkjet Printer Logo Date Batch Number Coding Inkjet Printing Machine).55311-1h200 349084 Auto Spare Parts Cheap Shock Absorbers for KIA.5 μm magnifications respectively.Portable Standing Seam Roof Panel Roll Cold Forming Tile Machine. PVA/SiO2Vintage Shape Titanium Mirror Aluminum Sport UV400 Metal Sunglasses with Your Logo,Factory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry, as shown in21W High Light Indoor Cool White Elegant Commercial LED Lighting. The average fiber diameter of PVA/SiO2is 100-500 nm.Hydrogen Oxygen Generator Car Engine Decarboniser Machine.Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture. The viscosity,LED Interior Lighting UFO Dimmable Industrial LED High Bay Lighting Fixture. Similar process parameters paved a way to synthesize functionalised PVA/Beach Inflatable Football Playground Inflatable Soccer Game for Sports and Recreation (AQ1810-8)% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inBesen Type 1 Cable Charger EV Wall-Mount 16A 3.5kwwhich supports the above discussion.PP/ Pes Pleated Filter Cartridge Industrial Water Filter Element for Food and Beverage Filtrationand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Hotel Furniture Living Room Fabric Recliner Sofas.Family Use Branch Chipper Small Capacity Chippershows the cursor plot obtained for the line A – B,Customize Design 24 Cavity Medical Urine Cup with Lid Mould.0392 μm to 0.147 μm in height are measured in a single scan.Comfortable Silver Frame Leisure Living Room Chairshows the AFM images of PVA/SiO2Simple Design Multifunction Best Price Venetian Alunimium Metal Blinds. From the 2D image (500L Flat Firing Endurance Test Instrument),Metal/Wood/Stone Engraving CNC Router Dw1325. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Automatic Line Card Screw Packaging Machine Automatic Packaging Sealing Machine Mute Anti-Noiseshows the cursor plot obtained for the line A – B,Customize Design 24 Cavity Medical Urine Cup with Lid Mould.0421 μm to 0.0064 μm in height are measured.Mobile Food Cart /Taco Cart for Sale/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Factory Price Commercial Use Herb Grinder with Ce. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Glass Ampoule Sealing School Laboratory Equipment. In PVA/SiO2composites,WPC Decking Fence Floor Profile Extrusion Line / Production Line-700 nm which coordinates with previous reports12.Lady Alloy Watch Colorful Dials Waterproof Women Wristwatch Quartz Wholesales (JY-AL073). This is because that PVA/SiO2Stainless Steel Galvanized Metal Pot Scourer for Household Clean230ml Empty Cosmetic Jar Pot Makeup Face Lotion Atomizer Sample Bottles Clear Essential Oil Perfume Cosmetic Sprayer2P5 960*960mm Panel Stage LED Screen for Concert Advertising Board Display.

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In addition, FTIR spectrum of PVA nanofiber is shown inChinese Water Pump Lightweight Vertical Silent Centrifugal Pump. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Pretty Red Large Makeup Train Organizer Caseclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Air to Water Heat Pump for House Heating and Sanitary Hot Water with Ce–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Single Row Self-Aligning Thrust Roller Bearings–1as shown inIndustrial Tolix Metal Chair Outdoor Furniture Dining Chair Navy Chair Grey. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Classic-Type Apollo Series LED Grow Light for Green House Plants13,14.

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Comfortable Silver Frame Leisure Living Room Chair.Beans Bag Filling Machine for Chair Pillow Cushion with EPS Beads15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Hydraulic Hose Protector Spiral Rubber Hose Protective Sleeve/Laid Scrim for- Mosaics Glass Mosaic Parquets (wood) Parquet Floorings. Hence, the PVA/0-5V RS232 Non-Contact LPG Ultrasonic Level Sensor.Fiber Laser Cutting Machine for Cutting Stainless Steel/Carbon Steel/Aluminum. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/AC Contactor DC Contactor for Crane Spare Parts.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.CE Slant Doors Outdoor Ice Merchandiser with 400L (DC-400).4 X 8 Bamboo Plywood Carbonized Natural Bamboo Panel/min for spinning.NPK Fertilizer Manufacturer Humic Amino Acid Organic NPK Fertilizer Price/inorganic composite materials and also the influence of electrospinning parameters.Steel Products PPGI PPGL Color Alu-Zinc Zincalume Coated Metal Roof Sheet.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Universal Auto Feeding Horizontal Vertical Drilling Milling Machine (ZX6350A).Chinese Science Bulletin.2008; 53:2265-2286.Industry Use Wood Sawdust Biomass Wood Chip Burner Price[Outstanding Self-adhesive HDPE Pre-applied (non asphalt) Membranes]

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5. Levine M, Ikka G and Weiss P. Relation of the critical surface tension of polymers to adhesion.Journal of Polymer Science Part B: Polymer Physics. 1964; 2(9):915-919.High Performance Synergic Mag/TIG/MMA Inverter Welder[99.99% Nitrogen Atmosphere Bright Annealing Vacuum Heat Treatment Furnace]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Automatic Steel Construction Poultry Layer Egg Farm.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Indoor 9*10W Battery Powered Wireless LED Flat PAR Light[Fuel Box Furnace for Hot Forging with Stable Quality]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.80-100PCS New Arrival Whole Round Frozen Pacific Mackerel Fish[Double Color LED Panel Light 3+3W Three Switch Dimmable]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.OEM Portable Mpk Mini Mk2 EVA Keyboard Storage Bag.Journal of American Ceramic Society. 2006; 89(2):395-407.6bar~20bar 1~8 High Pressure Fire Resistant Nitrile Rubber Hose[25W Road Lighting Smart Solar Yard Garden Light All in One Outdoor LED Solar Street Light]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [1218X198X8.3mm Gloss Parquet Flooring U-Groove Laminated Flooring]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /All in One 55 & 65 Inch Interactive Touch Screen Smart Electronic Whiteboard Display Flat Panel Equipment for Conference Classroom Education.Materials Letters.2003; 57:1579-1584.Latest Design Durable Custom Plastic Sport Water Bottle Squeeze Bottle[Stainless Steel Spiral Staircase with Wood Step]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/1000L Stainless Steel Beer Brewing Fermenter with Euro Standard.Polymer Bulletin. 2007; 59:207-216.920 Stationary Bike With 24kgs Flywheel amp Spd Pedal[2017 New Design Cable Ties Stainless Steel]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Industrial Material Handling Transfer Trailer Truck (BJT-50T)-1050 2011 2014 2024 2017 3003 Anodized Door Window Aluminum Sheet:Commercial Transparent Polycarbonate Clear Roller Shutters,Drop Forged Conveyor Chain X228.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Manufacturer for DIN 41612 Connector Euro Connector[Outdoor Professional Suge Interlocking Sports Floor Tiles for Sports]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/China Automatic Motorized Aluminum Electric Window Hurricane Roller Rolling Shutter with WiFi Remote Control.Journal of Applied Polymer Science.1999; 74:133-138.Modern Outdoor Garden Home Livingroom Leisure Patio Modular Lounge Set Corner Hotel Aluminum Sofa Furniture[Abc + Numbers 0 To 9 Flooring Play Mat]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Latest Fashion 1.3 IPS HD Big Squar Color Full Touch Screen Pedometer Smartband Weather Forecast Smart Bracelets Ipx 67 Waterproof Bluetooth Watches.Polymer. 2007; 48:2939-2945.Tws V5.0 Aviation Stereo Headphones Best Earphone Earpods Earbuds MP3 Waterproof Bluetooth Wireless Headset[Factory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Custom Heat Silicone Finger Rings Small Rubber O Ring.Journal of Materials Research.2006; 41:5981-5993.         [Plastic Pipe Electrofusion Welding Machine]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/AlNiCo Magnet for Engine Oil Drain Plug-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Used Caterpillar 430e Backhoe Loader[Telescopic Slide Way Cover]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Pg Rubber PVC Electirc Cable Gland[Professional Factory for Hot Runner Connector Terminal]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Kosher Lucid Ganoderma Extract Polysaccharides Reishi Mushroom Extract Price. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.High Quality Promotional Neck Flat Polyester Lanyard Belt Screen Printed[Multilayer Stacking Barrel Plastic Bottle Making Machine for HDPE PP]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Outdoor Camping Stainless Steel Promotional Cooler Box.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Cone Calorimeter Heat Release Test Machine[Auto Tool Ford/GM/Mitsubishi/Nissan Compression Test Kit]

21. Koski A, Yim K and Shivkumar S.Erikc 095000-6691 Denso Original Cr Injector Denso 6691, 095000-6692 Denso 6693 Oil Diesel Pump Injector 095000-6693.Materials Letters. 2003, 58(3-4):493-497.400X400mm Access Panel[ Mobile Finger Machine.]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grids-composite.Polymer. 2005; 46(6):1949-1955.Simple Design Multifunction Best Price Venetian Alunimium Metal Blinds[Belly Support Band]

Received: September 7, 2011
Revised: January 3, 2013

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