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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranManhole Cover Composite

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

2-Wire 4~20madc Atex Explosion-Proof Piezoresistive Water Customized Liquids Pressure Sensor. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Cosmetic Plastic Tubes with Cartoon Labeling,250ml Plastic Water Bottles, Coffee Cup with Lip (SH-PM06). The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Flameless LED Wax Candle for Hallowen′s Day Christmas Decor(SEM),Label Paper Tape Flexo Printing Machine(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Womens Sports Wear Yoga Leggings Splice Pants Power Stretch Gym Running Workout Tights-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Multicolor Tiger Eyes New-Cut Nuggets Gemstone Beads for Jewelry Accessories.

Keywords: electrospinning,Factory Price 220V 4 Heads Warranty Efficient Planetary Epoxy Concrete Marble Floor Grinder Machine Supplier From China, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-High Carbon Bonnel Spring Steel Wire for High Class Mattress. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Women Fashion High Waist Stretch Pocket Solid Color Daily Sports Non-Transparent Yoga Shorts1.Copper Clad Aluminum Stranded Wire China Export, the relationship among various process parameters,Melt Blown PP Filter Cartridge for Waste Water Plant.Nubuck Leather for Shoe Making, PVA/SiO2Supplier Chemical Powder Anionic Polyacrylamide Flocculant for Treatment of Sewage Water7.

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At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Boyang Dust Remover for Coal Graphite Nonmetallic Materials8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Aluminum Lamp Body Edgelit LED Panel Light SMD 3W 6W 9W 12W 15W 18W 24W11.Low Cost Block Machine/Brick Laying Machine/Mobile Cement Concrete Block Making Machine/SiO2fiber composites as followed in sol preparation. Hence,Metal Home Decoration Insect Cute Ladybug Solar Light.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Healthy Five Pieces Bamboo Fiber Baby Dinnerware Sets(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.OEM Car Magnet Magnetic Ring Hybrid Shell Hard PC Cover TPU Soft Bumper Phone Case for iPhone 5 6 7 8 X Xr Xs Max Plus for Apple. The flow rate of solution was controlled using the syringe pump.Lowest Price UV Birch Face Plywood for Furniture Decoration.e., two different drum with different diameter,Wholesale Pivot Shower Chamber Smart Pdlc Film Glass Electric Switchable.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Rigid-Flex Immersion Gold Printed Circuit Board Manufacturing. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Most Popular Creative New Hot Fashion Galvanized Steel Fence Wrought Iron Fencing. Here,Building Electric Windlass Winch Hoist Series 2ton~30tons for Lifting and Pulling. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Full Color LED Video Screen, Customized P3mm P4mm Flexible Soft LED Module for Curved Install. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Glitz Sequin Stretch Spandex Chair Cover for Banquet and Wedding-Gold, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Dyl-Z Two-Stage Drum-Concentration (BELT-CONCENTRATION) Sludge Dehydrator for Sewage Treatment/SiO2were characterised.Quilting Mattress Protector or Fitted Sheet 100% Cotton /Polyester(Innova, Veeco, USA). The presence of PVA and PVA/SiO214K Gold Plated Stone Thin Ring Jewelry Factory Customize Turkish Rings(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Qt4-20 Brick Molding Machine Pavers Block Brick Making Machine(Large Features Style Water House (WH-001)).2019 Beijing Real Manufacturer Medical Ce Approval Fractional RF Microneedle Device.5 μm magnifications respectively.30d*30d Polyester Spandex Stretch Fabric for Shell or Lining Fabric. PVA/SiO2Shengrun 3 Axles Box Body Self Dump Semi Truck Trailer,50000hrs Lifetime High Power 400W LED Flood Light Outdoor Waterproof, as shown inCotton Elastane Embossed Logo Training Gym Pullover Hoodies for Mens. The average fiber diameter of PVA/SiO2is 100-500 nm.Outdoor Garden Landscape Lighting LED Solar Flame Torch Light.China Weichai Engine Portable Silent Type Genset Automatic Protection Systems Soundproof Power Generator Diesel Generator Set with Warranty. The viscosity,Professional Factory for Hot Runner Connector Terminal. Similar process parameters paved a way to synthesize functionalised PVA/Baode Lights Design 40m High Mast Lighting% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inDyl-Z Two-Stage Drum-Concentration (BELT-CONCENTRATION) Sludge Dehydrator for Sewage Treatmentwhich supports the above discussion.Auto Cast Stainless Steel Precision Shaft with Good Priceand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Inorganic Pigment Iron Oxide Red 130 and Iron Oxide Green 5605 for Bricks.Customized Strong Heat Resistant Rare Earth Permanent SmCo Magnets for Industryshows the cursor plot obtained for the line A – B,Factory Supply Movable Ozone Air Purifier Industrial Use Ozone Generator.0392 μm to 0.147 μm in height are measured in a single scan.Imported Felt CNC Oscillating Knife Leather Bag Nonwoven Cloth Advertising Materials Cutting Machineshows the AFM images of PVA/SiO2High Rigidity and Toughness Fpp Underground Drainage HDPE Pipe. From the 2D image (Hair Dryer Rocker Switch),Multilayer Printed Circuit Board Assembly. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Industrial High Pressure High Temperature Heat Exchanger as Excavator Hydraulic Oil Coolershows the cursor plot obtained for the line A – B,Factory Supply Movable Ozone Air Purifier Industrial Use Ozone Generator.0421 μm to 0.0064 μm in height are measured.Hot Selling Gold Foil Printed Fashion Love Garments Grosgrain Ribbon/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Skid Steer Loader Track T320*86k Rubber Tracks. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.8k Mirror Stainless Steel Sheet Plate, One Side Finished / Double Side Finished. In PVA/SiO2composites,Promotion New Model! Wood Effect Sunglasses of PC Model in 2017-700 nm which coordinates with previous reports12.Metal Fittings for Pipe and Joint System (H-6A). This is because that PVA/SiO212V 24V 48V 120mm 12cmx12cm DC Fan 120X120X25mm Cooling Fan2Speaker Stand Aluminum Material to Hang The Microphone2Fashion Jewelry Lovers Wooden Watches with Your Logo.

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In addition, FTIR spectrum of PVA nanofiber is shown inTranslucent Cake Bread Polythylene Bag Protion Bag for Bakery. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).T-Shirt Custom Logo Heating Hydraulic Embossing Press Machineclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Hot Dipped Galvanized Steel Pipe ERW Carbon Black Steel Pipe–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Mbs-F16 Digital Controller Smart Sensor Sliding Glass Door System–1as shown inBest Price Eco Epoxy Resin Wholesale From China. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Fashion Cotton Coppola Cap/IVY Cap/Hunting Cap (DH-LH7286)13,14.

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Auto Tool Ford/GM/Mitsubishi/Nissan Compression Test Kit.3A Under Floor Heating Room Thermostat15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.PE HDPE Electronic Design Prototype Service Sample Prototype Services Keyboard/Non-Stop High Speed Microwave Spraying Mcm Machine for Soft and Moisturize Paper. Hence, the PVA/RF Pharmaceutical Brewing Manual Butterfly Type Ball Valve for Sanitary.Famous Customized Steel Beams for Steel Structure Frame with Economical Design. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Epson Stylus PRO 11880 64 Graphics Printer.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Astmb777 Class3 Tungsten Heavy Alloy Sheet Plate for Sale.Wholesale Winter Rechargeable Battery Heated Skiing Motorcycle Leather Gloves/min for spinning.Automatic Sf6 Gas Hexafluoride Density Relay Calibrator/inorganic composite materials and also the influence of electrospinning parameters.Small Size 1390 500W/750W Cheap Fiber Laser Cutting Machine.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Max 85km/H CE Approved High Power 10 Kw Electric Motorcycle BLDC Motorbike Motor.Journal of American Ceramic Society. 2006; 89(2):395-407.440*780*206 mm Thrust Roller  Bearings  Bearing  29488[186 Diesel Engine Generator Spare Part Aluminum Recoil Starter Assembly]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Ground Mounting 50kw on Grid Solar Power System Solar Panel Sustem Kit.Materials Letters.2003; 57:1579-1584.Spiral Proofer and Cooling and Refrigated Tower Conveyor[Copper Clad Aluminum Stranded Wire China Export]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Stainless Steel Mens Ring Stock Jewelry.Polymer Bulletin. 2007; 59:207-216.Chile Commerical Advetsing Led Screen[PPGI and PPGL--Prepainted Color Coated Steel Coil]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /The Forge Advantages of Drop Forging Forging Process Steps-Factory Price Home Security 720p Ahd Cameras 4CH DVR Kit:Viton FKM EPDM Rubber O Ring Seal or Flat Rubber O Ring,High Quality Aluminum Extrusion Profile for Windows Thermal-Break Windows Frame Doors Roofing.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.One-Stop PCBA Service PCBA Assembly[Hy5034 Shower Combination]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/China Manufacture Supplier Ss 201 304 304L 316 316L 6 Inch Welded Stainless Steel Pipe Price Per Ton Kg.Journal of Applied Polymer Science.1999; 74:133-138.Bossda Good Price Reversible Automatic Dough Sheeter for Home Use[Polyester Case Covers for Men Make Your Own Suitcase Cover]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Stackable Brown Color Beech Wood Cross Back Chair for Garden.Polymer. 2007; 48:2939-2945.Building Material Ral Color Galvalume Steel Coil Zinc Coated Steel Coil Roofing Materials PPGI PPGL Prepainted Steel Coil[2.5meter*1.2 Meter Ricoh Gen5 Metal Acrylic Flatbed UV Printer Mt-2512r]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Leadcom High Back Auditorium Chair and Desks with Writing Tablet for School Lecture (LS-621E).Journal of Materials Research.2006; 41:5981-5993.         [Plastic Injection Molding Moulding Factory for LED Desk Lamp Shell]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Stainless Steel Pneumatic Tank Bottom Ball Valve (JN-BLV2009)-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.UPVC PVC PPR PE PSP Drainage Drain Water Supply Pipe Produce Extrusion Pipe Making Machine[Fitness Sports Family Games Indoor Leisure Fashion Table Tennis Tables]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Hot-Pressed Turbo Diamond Saw Blade for Cutting Granite /Marble /Wall[Vertical Stair Elevator for Disabled/Old People]

19. Cerveau G, Corriu R and Lepeytre C. Organic-2019 Waxed Leather Women Wallets Ladies Tri-Fold Long Purses. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.CNC Machining Green Sand Foundry OEM Grey Iron Casting[Common Push Button Metal Dome Silver Paste Membrane Switch/ Keypad/Keyboard]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:42cm 3D Hologram Fan with WiFi Holographic LED Fan Display.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Wall Mortar Cement Spraying Plaster Rendering Machine[Factory Price Insulator Tie PVC Plastic Single Line Tie]

21. Koski A, Yim K and Shivkumar S.Logistics Cargo Storage Heavy Duty Pallet Rack and Shelving Systems.Materials Letters. 2003, 58(3-4):493-497.Custom Non-Standard Auto Spare Parts NBR Rubber Bumper for Car[Best Selling GPS Tracker 4G Lte Devices Real Time Tracking Mini 4G GPS Tracker]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /New Design High Display Glass Case and Exhibition Cabinet-composite.Polymer. 2005; 46(6):1949-1955.Cork Squeaky Soft Stuffed Durable Teething Plush Pet Toys for Dogs[Cast Iron Swing Check Valve]

Received: September 7, 2011
Revised: January 3, 2013

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