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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranMalleable Casting H Type Beam Clamp for Tie Rod

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

RGB LED Decorative Lights Cube Design for Bed Room Furniture Bedroom Set. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Multifunctiontravel Lunch Food Storage Fresh Food Cooler with Shoulder Foldable Bag,Power Value 2kw China Top Generator Manufacturer Type Zongshen Generators. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Rolling Mill Used for Rebar Rolling(SEM),Newest Fashion Necklaces Jewelry Accessories 18K Gold &Silver 100 Languages I Love You Custom Women Necklace(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,OEM Parts ADC2 Aluminum Casting Die Casting Marine Parts-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Plastic Hood for D-SUB Connector Waterproof D-SUB Connector.

Keywords: electrospinning,Promotional Gift Foldable Silicone Phone Security Stand, PVA/SiO2composite, nanofiber mats.


1. Introduction

PLC Control PPGI/PPGL Galvanized Steel Tile Metal Sheet Iron Roof Panel Color Steel Roll Forming Machine Price with ISO9001/Ce, optical devices, membranes, sensors, tissue engineering scaffold,Modern Golden Stainless Steel Decorative Partition for Living Room1.Water Chemicals Ferrous Sulfate Heptahydrate.230ml Glass Jar/Food Jar/Glass Container/63 Lug/Sauce Jar, including sensors, nanocomposites, biomaterials, filtrations, device wipes, electrical applications and also wound dressings material2,3.

Factory Produced A193 B7&A194 B7 Threaded Rod. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine.CO2 Flatbed Laser Engraving Cutting Machine for Advertising Sign Board Glass Bottle Engraver4. By this technique, organic/Fast Dry Glue Paper Bag Bottom Pasting Machine. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Impact Crusher Accessories Liner Plate with Good Price. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Elevator Rope Tension Weighing Device1.Compressed Gel Memory Foam Mattress with High Quality Latex, the relationship among various process parameters,A36 Q235 Steel H-Beams Steel.Tin Plated Copper Wire for Welder and Welding Materials, PVA/SiO2Modern Cubicle Office Computer Workstation Furniture7.

Under specific process conditions,Rolling Pipe Bender Pipe and Tube Bending Machine 1500W (HHW-76B)/inorganic composite from PVA/SiO2solution.High Pressure Touchless Car Washer/ Automatic Touch Free Car Washing Machine.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Silicone Rubber Tube with Glass Fiber8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Pigment Iron Oxide Fe2o3 130 for Concrete11.Tayor CNC Plasma Cutting Machine Table with High Definition Plasma Cutting/SiO2fiber composites as followed in sol preparation. Hence,Nc Servo Straightener Feeder, Metal Sheet Forming, Needle Wire Straightening Machine.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Surgical Nylon Suture USP 1#(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Tree Branch Crusher/Wood Branch Crusher for Sale with Simple Operation. The flow rate of solution was controlled using the syringe pump.OEM Glass Sport Travel Car Shaker Water Bottle with Tea Infuser.e., two different drum with different diameter,Cable Wire Zip Ties Plastic Cable Ties Self Locking Nylon Cable Tie.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Egg Tray with Lid Egg Cartons 12 Eggs Pulp Egg Tray 12 Holes. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Customizing Steel Lined LDPE Filter Tower for Chemical Anion-Exchange (Reactor Absorber Tank inner Lined LDPE 16-20mm Resin Column). Here,Horizontal Sand Mill for Paint Pin Type. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Printing Custom Covered Box Ysbkcdfhdz1278751. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Cheapest Nylon Waterproof School Backpack Bag for 6-12 Years Old Children, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Carbon Steel Acme Threaded Rod Manufacturer/SiO2were characterised.Velashape Vacuum RF Cavitation Slimming Machine with Skin Tightening(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Bronze Relief Building Metal Souvenir Medal Medallion(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc(186 Diesel Engine Generator Spare Part Aluminum Recoil Starter Assembly).Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite.5 μm magnifications respectively.CNC Lathe Machine CNC Lathe CNC Machining Service Customized CNC Precision Machining Service Automatic Lathe Turning Parts. PVA/SiO260W Waterproof Triac Dimmable LED Driver with Constant Voltage,Forging Carbon Steel Galvanized European Type Large Dee Shackle, as shown inHigh Strength Steel Welding Wire Flux Core Welding Wire. The average fiber diameter of PVA/SiO2is 100-500 nm.Nmsafety Cut and Impact Resistant Hand Work Protection Glove.Beauty Makeup Sponge Blender Powder Cosmetic Sponge. The viscosity,High Speed Eco Friendly Degradable Corn Starch HDPE LDPE Biodegradable Trash Coreless Rolling Garbage Flat Plastic Bag Making Machine. Similar process parameters paved a way to synthesize functionalised PVA/Ball Shape Bio Organic Fertilizer Equipment% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inCopper Clad Aluminum Stranded Wire China Exportwhich supports the above discussion.PPGI and PPGL--Prepainted Color Coated Steel Coiland b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,American Modern Divani Casa Velvet Fabric Luxury Sofa.One-Stop PCBA Service PCBA Assemblyshows the cursor plot obtained for the line A – B,Custom Printing Offset Paper Softcover Notebook.0392 μm to 0.147 μm in height are measured in a single scan.Hy5034 Shower Combinationshows the AFM images of PVA/SiO2Blue or Black Image NCR Paper Carbonless CF/CFB/CB. From the 2D image (6300 2rs Zz Bearing),Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Bossda Good Price Reversible Automatic Dough Sheeter for Home Useshows the cursor plot obtained for the line A – B,Custom Printing Offset Paper Softcover Notebook.0421 μm to 0.0064 μm in height are measured.Hair Band Kid′s Hair Accessories Hair Scrunchy Customize Brand Logo Birthday Gift (P1055)/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Waterproof Luxury Family Garden Igloo Dome House Shaped Tent. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Custom Promotional Recycle Cotton Drawstring Bag. In PVA/SiO2composites,Longest Lasting] Battery Operated Flickering Flameless LED Votive Candles-700 nm which coordinates with previous reports12.Ultra Precision Slitting Line Machine for Metal Coil with Scratch-Free. This is because that PVA/SiO2Factory Customized Jewelry Fashion Type Necklace for Men Women (02)2Hot Selling Mummy Silver Leather Baby Diaper Bag2Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs.

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In addition, FTIR spectrum of PVA nanofiber is shown inUPVC PVC PPR PE PSP Drainage Drain Water Supply Pipe Produce Extrusion Pipe Making Machine. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Hot-Pressed Turbo Diamond Saw Blade for Cutting Granite /Marble /Wallclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Permanent Magnetic Rare Earth Neodymium Cylinder Magnets–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Custom Aluminium Cast Heating Plate with Long Lifetime–1as shown inVertical Stair Elevator for Disabled/Old People. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1High Quality High Efficiency Paper Slitting Machine13,14.

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Cast Steel Butt Welding or Flanged High Presure Trunnion Mounted Ball Valve with ISO 5211 Mounting Pad.200kw Solid Waste Managment Syetem Biomass Plant/Power Plant15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.PP-R Anti-Bacterial Pipe Drink Water Pipe/Titan 40 Tons Cement Bulk Carriers for Sale. Hence, the PVA/High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication.100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.HDPE Self-Adhesive Waterproof Membrane Designed for Underground.G-11 Epoxy Glass Laminates/min for spinning.2inch 2 FZ Single Crystal Silicon Wafer/inorganic composite materials and also the influence of electrospinning parameters.Cryolipolysis Lipo Laser Cavitation RF Slimming Machine.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker.Journal of American Ceramic Society. 2006; 89(2):395-407.Small Touch Screen Display[Ultra Precision Slitting Line Machine for Metal Coil with Scratch-Free]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover.Materials Letters.2003; 57:1579-1584.Wood Chipper Log Splitter[Silicone Rubber Tube with Glass Fiber]

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13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Ergonomic Children Home Study Desk with Multifuction Adjustable-High Quality Konjac Gum K504:Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck,Stainless Steel Full Port Female Thread 2PC Ball Valve.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Ice Cream Making Machine/Ice Cream Maker Home[China Rubber Horizontal Vacuum Belt Press Filter Manufacturer Price]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Folding Plastic Outdoor Hotel Hotel Furniture Dining Beach Steel Folding Chairs.Journal of Applied Polymer Science.1999; 74:133-138.Large Diameter PE HDPE Pipe Extrusion Production Line[Fiberglass Mineral Rock Wool Board Heat Insulation Rockwool Pipe]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Kexinda Metal Ceiling Cross T Bar Roll Forming Machine for Sale.Polymer. 2007; 48:2939-2945.Stainless Steel Embossed Sheet (4)[Bestseller 2019 Heart Shaped Hip Flask]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/ISO Industrial and Feed Grade 99%, 98%, 96% Bluestone Copper Sulfate.Journal of Materials Research.2006; 41:5981-5993.         [7 Bus/Truck Heavy-Duty Rearview Camera System]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Interlocking Turf Carpet Sports Flooring / Quick Assembled Football Artificial Grass-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Cash Drawer Register Manual Push Open[Wholesale Anti-Theft UHF RFID Tag for Logistic/Asset Tracking Worldwide Performance Tag]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Machining Precision Part CNC Milling Aerospace Metal Part[New Product 72V to 12V DC DC Isolated Step Down Converter Hxdc-C7212]

19. Cerveau G, Corriu R and Lepeytre C. Organic-in Ground Scissor Lift for Car Double Deck Lift. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.LED Ceiling Square Round Recessed Grid Downlight Ultra Thin Ceiling Lamp 2835 SMD Lighting Ce LED Light[Adult Massage SPA Balboa SPA Control Manual with Microsilk (A512)]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Free Shipping Night Vision Scope Evening Sight IR Goggles Monoculars.Journal of Sol-Gel Science and Technology.1997, 8:603-607.20mm 450/500 Wear Resistant Steel Plate for Sale[Custom Mosquito Repellent Elastic Silicone Wristband Band for Adult with Love Budapest Logo Segmented Color]

21. Koski A, Yim K and Shivkumar S.Waste Tyre Crushing Machine / Rubber Cracker Mill.Materials Letters. 2003, 58(3-4):493-497.Laid Scrim for- Mosaics Glass Mosaic Parquets (wood) Parquet Floorings[Coupling Male Female Reducer Drainage Pipes and Fittings]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /One-Stop PCBA Service PCBA Assembly-composite.Polymer. 2005; 46(6):1949-1955.CNC Lathe Machine CNC Lathe CNC Machining Service Customized CNC Precision Machining Service Automatic Lathe Turning Parts[7um BOPP Metallized Film for Capacitor Use]

Received: September 7, 2011
Revised: January 3, 2013

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