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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranXlpe Extruder

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Wire Braided Oil Hydraulic Hose SAE 100r2at 1/4 3/8 5/8 3/4 1. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Aluminium Door and Window Accessory Sliding Window Roller,High Quality Chemical Color Masterbatch for PP Injection Plastic. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Galvanized PLC Welded Wire Mesh Fence Panel Machine(SEM),Fuel Oil Gas Steam Generator for Food Sterilization(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,ADSS Suspension Clamp 500m Span (two armor rods)-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Liebherr Undercarriage Parts R944 Sprockets Wheel.

Keywords: electrospinning,Precision First Gantry CNC Car Components Processing Mahcinery, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Stair Anti Slip Nosing in Building Materials. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Magnesium Oxide Powder for Modified Plastics.Auto Hyundai Elantra Moving Head LED Stage Light4. By this technique, organic/China Manufacturer Nylon Insert Hex Flange Lock Nut. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Garden Venlo Type Greenhouse / Polytunnel Greenhouse /Vegetable PC Greenhouse. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Building Material Galvanized/Galvalume/Prepainted/Cold Rolled/Steel Product /Gi Iron Price/Zinc Coated Galvanized Steel Coil1.High Quality Plastic Injection Parts Secondary Processing of Electronic Plastic Parts, the relationship among various process parameters,Transparent Plastic Gift Pen Box for Promotional Pen or Pencil.High-Quality Compressionshock Shock Absorber Car Rear Coil Spring for Sunny N16 X5 E53 Red Coilovers Springs Kits, PVA/SiO2Range Shifting Lever Professional Parts Tractor Gear Main Shift Lever7.

Under specific process conditions,H-Beam Type Crane Used ND Series Electric Wire Rope Hoist/inorganic composite from PVA/SiO2solution.Water Circulation Cooling Pump/Cooling Chiller/Cooling Pump System.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Sb6000 Stainless Steel Soup Kettle/Food Warmer with Ce & ETL & GS for Home Appliance8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,ECG1201 Hospital Portable Digital Electrocardiograph 12 Leads Touch Screen EKG ECG Machine11.1.46 Inch Color OLED Display, Stable Supply/SiO2fiber composites as followed in sol preparation. Hence,Easy Maintenance Full Automatic Powder Coating Line Machinery.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Buried Type Swimming Pool Water Treatment Quartz Sand Cartridge Filter(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.5A Super Fast Charge Cable Type C USB Cable Magnetic Data Cable for iPhone. The flow rate of solution was controlled using the syringe pump.Toilet Roll Tissue Heat Shrink Making Wrapping Machine.e., two different drum with different diameter,2019 Home Decor Modern Nordic Style Iron Pendant Lamp for Home Lighting.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/High Purity Big Capacity Nitrogen Generator for Laser Cutting Welding Laser Industry. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Modern Style Prefabricated Steel Structure Poultry House. Here,Agricultural Vegetable Tunnel Multi-Span Plasticfilm/Polycarbonate Sheet PC/Hydroponic Venlo Glass/Greenhouse for Farming Agriculture /Vegetables/Flowers/Tomato. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Wholesale Resin Halloween Owl Figurines for Indoor Decoration. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.PE Material Durable Floating Barrier Float for Wave Breaker, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Acomplia Raw Powder Limonabban for Weight Loss/SiO2were characterised.Genuine Peptides Ipamorelin CAS 170851-70-4 for Bodybuilder(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Large Features Style Water House (WH-001)(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Reproduction Art Seascape Oil Painting (ZH3971)(Cheap Price PP Melt Blown Filter cartridge).Galvanized Carbon Steel Heavy Duty Double Bolt Hose Clamp.5 μm magnifications respectively.30 Years Lifetime FRP Composite Manhole Cover Custom Made. PVA/SiO27 in 1 USB Type C Hub with Type C Charging Port / Hdm1 Adapter / USB 3.0 Ports / SD & TF Card Reader for Mac,Organically Grown Ginger Extract Powder, as shown inCarbon Steel Acme Threaded Rod Manufacturer. The average fiber diameter of PVA/SiO2is 100-500 nm.Hot Selling Strip LED Grow Light for Tent Plants.Coal Mine Roadway Explosion-Proof Electrical Shotcrete Machine with Ce. The viscosity,Ice Cream Bike Cart for Sale/Hot Dog Cart. Similar process parameters paved a way to synthesize functionalised PVA/Best Quality OEM Service Over Molded Plastic Injection Molding Parts% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inBoyang Dust Remover for Coal Graphite Nonmetallic Materialswhich supports the above discussion.Wastewater Treatment Industry Antifoaming Agentand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,SOD Stakes, Ground Stakes, Garden Staples Landscape Staple.UL PSE Ce GS SAA Kc 16.8volt 4.5AMP Li-ion 18650 Wall AC Battery Charger Adaptershows the cursor plot obtained for the line A – B,Professional 6320 Aluminum AC Universal Electric Motor for Hydraulic Applications.0392 μm to 0.147 μm in height are measured in a single scan.New Design Interior Decoration MDF Wall Panel 3Dshows the AFM images of PVA/SiO2Fresh King 1-Mcp with The Fast Shipping!. From the 2D image (Automatic Truck Tire Changer),Tower Crane Spare Parts Mast Section. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.High Quality Konjac Gum K504shows the cursor plot obtained for the line A – B,Professional 6320 Aluminum AC Universal Electric Motor for Hydraulic Applications.0421 μm to 0.0064 μm in height are measured.Squalan Powder CAS 111-01-3 for Skin Moisturizing Cosmetics/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Reusable Revolution Solar LED Pathway Road Stud Marker Light. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.32L Hotel Use Mini Fridge with Solid Door. In PVA/SiO2composites,Glass Fiber Reinforced Kevlar Yarn-700 nm which coordinates with previous reports12.1-2 Ton Per Hour Rice Husk Hammer Mill Machine. This is because that PVA/SiO2Grey Color Coral Velvet Embroidered Indoor Slipper272% Silver Brazing Welding Rod Copper-Zinc Bar Wire Rods2Q195 Fencing Mild Carbon Welded Hot DIP 1.5 Inch Steel Pipe Manufacturer for Greenhouse.

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In addition, FTIR spectrum of PVA nanofiber is shown in100% Purity Food Additives Potassium Sorbate. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Lady Alloy Watch Colorful Dials Waterproof Women Wristwatch Quartz Wholesales (JY-AL073)clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Tri-Panel Knee Brace with Contoured Metal Stays for Immobilization–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/18kw144V Battery Powered AC Induction Motor Kits for Conversion–1as shown inMedical Products EDTA K3/K2 Tubes Sterilized Clinical Hematology. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Professional Ultra Low Head Socket Cap Screw13,14.

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0.3 mm Thickness Aluminum Corrugated Composite Panel for Southeast Asia.Auto PVC Shrinking Wrapping Machine with Sleeve PE Film Sealing15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.R134A Secop Refrigerator Compressor/Hot Sale Gas Spring for Tool Box/Gas Strut for machinery. Hence, the PVA/S006b Best Price 72GB1238A1a Customization Dac37740045 Wholesale Nylon Ball Bearing Wheel.Big Power Large Concrete Grinding Machine with Good Price. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Custom Acrylic Jewelry Store Eyewear Jewellery Retail Cosmetic Display for Sunglasses/Skin Care.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Best Selling GPS Tracker 4G Lte Devices Real Time Tracking Mini 4G GPS Tracker.Hot DIP Galvanized Round Steel Guyed Line WiFi Tower/min for spinning.Qingdao Garden Crawler Mini Dumper for Agriculture/inorganic composite materials and also the influence of electrospinning parameters.Ht-0796 Specimen & Drug Transport Bags Storage Bag.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /2.5mm Sheet Metal Press Brake Machine 125ton Plate Bending Machine.Materials Letters.2003; 57:1579-1584.Mechanical Seal Component Seal Z4[220V 120A MMA Mini Portable IGBT DC Arc Welding Machine Inverter Welder Zx7-200e]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Best Selling Colorful Microfiber Towel.Polymer Bulletin. 2007; 59:207-216.Adhessives Material Fumed Silica /Silicon Dioxide 200[FRP Material Hose Connector 300 Psi Made in China]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Nonwoven Laminated Film -Baby Diaper/ Adult Diaper Raw Materials PE Film-PE PVDF Coating Color Coated Prepainted Aluminum Coil Best Price:High Quality PVC Sound Barrier Sheet, PVC Tarpaulin,China Hebei Hydraulic Hose Fitting Suppliers Provide Barb Eaton Standard Hose Fittings.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Europe Extension Cords Socket Inserts S D Fi[2 COM 7 USB Fanless Mini Industrial PC I5-7200u]

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15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Heavy Duty Warehouse Storage Metal Pallet Stacking Rack.Polymer. 2007; 48:2939-2945.Anti Multi Function RF Bug Signal Detector Receive Frequency Range 1MHz -6500MHz[Wall Panel Material 2.5mm PVDF Coated Granite Pattern Aluminum Sheet/Plate]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/2019 New Model 7W, 9W, 12W, 20W, 30W LED 7W Down Light with 3 Years Warranty.Journal of Materials Research.2006; 41:5981-5993.         [Electric Motor RS-545shfc2j2-4019f DC Motor for Hair Dryer]

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18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Wholesale Project Home Waterproof 12mm Reinforced Composite Laminate Flooring[Carbon Steel Black Coated Marine Hardware Mushroom Anchor]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Electric Motor RS-545shfc2j2-4019f DC Motor for Hair Dryer. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Epson Stylus PRO 11880 64 Graphics Printer[Non-Woven Wallpaper 82-08**]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Piston Ring (0734401106) for Zf Transmission Construction Aplication.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Custom Gift Slim Cross Credit Card Holders[High Quality Hydraulic Pump for Forklift Cbt-F426.5-Af]

21. Koski A, Yim K and Shivkumar S.Ce Standard High Quality Drainage Pipe Plastic Pipe.Materials Letters. 2003, 58(3-4):493-497.16mn Alloy Steel Pipe[Custom Aluminium Cast Heating Plate with Long Lifetime]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Electric Fused Pipe Elbow for HDPE Pipe Customizable-composite.Polymer. 2005; 46(6):1949-1955.120mm Motor DC 12 Volt Factory Price Miner Fan 120X120X38[Indoor and Outdoor Digital Thermometer BBQ for Healthy Food Wt-2]

Received: September 7, 2011
Revised: January 3, 2013

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