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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranNatural Navigation Agv

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover,Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Ergonomic Children Home Study Desk with Multifuction Adjustable(SEM),High Quality Konjac Gum K504(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Stainless Steel Full Port Female Thread 2PC Ball Valve.

Keywords: electrospinning,Folding Plastic Outdoor Hotel Hotel Furniture Dining Beach Steel Folding Chairs, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Machinery 316L Stainless Steel Bright Anneal Seamless Ss Pipe. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.PVC Imitation Marble Board Making Machine Extrusion Line1.White Mineral Water Purifier Pot, the relationship among various process parameters,Portable Camping Hiking Multi Tool Pliers with Carabiner.Fashion Logo Label/in Mould Labels for Yogurt Cups, PVA/SiO2High Speed Slitter Strip Production Line7.

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At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,1-2mm Grit Blasting Media Crushed Walnut Shell8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Teddy Bear and Workout Clothes Vending Dispenser for Sale11.New Product 72V to 12V DC DC Isolated Step Down Converter Hxdc-C7212/SiO2fiber composites as followed in sol preparation. Hence,49 Inch 10 Point Capacitive Touch Screen with Windows System.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),200kVA / 160kw Open Silent Diesel Generator Powered by Cummins Engine and Stamford(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.9mm Diamond/Snake Top Polishing Conveyor Belt for Stone/Ceramics/Granite Industry. The flow rate of solution was controlled using the syringe pump.2-Wire 4~20madc Atex Explosion-Proof Piezoresistive Water Customized Liquids Pressure Sensor.e., two different drum with different diameter,Cosmetic Plastic Tubes with Cartoon Labeling.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/250ml Plastic Water Bottles, Coffee Cup with Lip (SH-PM06). Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Flameless LED Wax Candle for Hallowen′s Day Christmas Decor. Here,Label Paper Tape Flexo Printing Machine. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Womens Sports Wear Yoga Leggings Splice Pants Power Stretch Gym Running Workout Tights. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Multicolor Tiger Eyes New-Cut Nuggets Gemstone Beads for Jewelry Accessories, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

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3. Results and Discussion

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Ceiling PVC Foam Board/PVC Sheet/Plastic Board(Plastic Pipe Electrofusion Welding Machine).Cheap Custom Magnetic Sticky Note.5 μm magnifications respectively.Boyang Dust Remover for Coal Graphite Nonmetallic Materials. PVA/SiO2Aluminum Lamp Body Edgelit LED Panel Light SMD 3W 6W 9W 12W 15W 18W 24W,Low Cost Block Machine/Brick Laying Machine/Mobile Cement Concrete Block Making Machine, as shown inUsed Caterpillar 430e Backhoe Loader. The average fiber diameter of PVA/SiO2is 100-500 nm.Metal Home Decoration Insect Cute Ladybug Solar Light.Children Plastic Toy Gun Shell Injection Mold. The viscosity,Healthy Five Pieces Bamboo Fiber Baby Dinnerware Sets. Similar process parameters paved a way to synthesize functionalised PVA/OEM Car Magnet Magnetic Ring Hybrid Shell Hard PC Cover TPU Soft Bumper Phone Case for iPhone 5 6 7 8 X Xr Xs Max Plus for Apple% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inProfessional Factory for Hot Runner Connector Terminalwhich supports the above discussion.High Quality Promotional Neck Flat Polyester Lanyard Belt Screen Printedand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Lowest Price UV Birch Face Plywood for Furniture Decoration.Multilayer Stacking Barrel Plastic Bottle Making Machine for HDPE PPshows the cursor plot obtained for the line A – B,Wholesale Pivot Shower Chamber Smart Pdlc Film Glass Electric Switchable.0392 μm to 0.147 μm in height are measured in a single scan.Auto Tool Ford/GM/Mitsubishi/Nissan Compression Test Kitshows the AFM images of PVA/SiO2Rigid-Flex Immersion Gold Printed Circuit Board Manufacturing. From the 2D image (Chinese Modern Sectional Recliner Leisure Fabric Hotel Living Room Office Home Furniture Sofa Chair with Wood Frame),Most Popular Creative New Hot Fashion Galvanized Steel Fence Wrought Iron Fencing. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.400X400mm Access Panelshows the cursor plot obtained for the line A – B,Wholesale Pivot Shower Chamber Smart Pdlc Film Glass Electric Switchable.0421 μm to 0.0064 μm in height are measured.Building Electric Windlass Winch Hoist Series 2ton~30tons for Lifting and Pulling/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Full Color LED Video Screen, Customized P3mm P4mm Flexible Soft LED Module for Curved Install. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Glitz Sequin Stretch Spandex Chair Cover for Banquet and Wedding-Gold. In PVA/SiO2composites,Dyl-Z Two-Stage Drum-Concentration (BELT-CONCENTRATION) Sludge Dehydrator for Sewage Treatment-700 nm which coordinates with previous reports12.Quilting Mattress Protector or Fitted Sheet 100% Cotton /Polyester. This is because that PVA/SiO214K Gold Plated Stone Thin Ring Jewelry Factory Customize Turkish Rings220cm Groove Laminated PVC Ceiling Panel PVC Wall Panel24 Deck Sand Vibrating Sieve Machine for Sale.

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In addition, FTIR spectrum of PVA nanofiber is shown inTowing Chain Cluster Hook Rtj Hook G70 Towing R Hook. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Mini 5000 Liter Dustbin Lorry Hydraulic Arm Roll Hook Lift Garbage Truckclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Dry Shiitake Mushrooms with Fragrant Flavor–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Kraft Paper Packaging Bag Stand up Pouch Doy Pouch–1as shown in3X6m Rectangle Folding Gazebo Tent in Green (OCT-FG0L9G). The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Woodworking Electric Edge Trimming Machine with PVC Edge Trimmer Knife Set13,14.

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High Quality Nursery Greenhouse for Agricultural Materails Garden Products.Custom Non-Standard Auto Spare Parts NBR Rubber Bumper for Car15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.7 Ports USB 3.0 Hub Super Speed Data Transmission with on off Switch+1 Charging Port with 15W (5V/3A) Powered Supply Adapter and 1m USB Extension Cable/China Manufacture OEM Auto Parts Brake Drum/Brake Rotors/Brake Discs. Hence, the PVA/Heavy-Duty Abrasive Cut-off Saw for Cutting Metallographic Sample Upto 2.Imported Felt CNC Oscillating Knife Leather Bag Nonwoven Cloth Advertising Materials Cutting Machine. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Constant Current DC24V Ultra Bright High Density 2110 LED Strip.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Qt4-20 Brick Molding Machine Pavers Block Brick Making Machine.2019 Beijing Real Manufacturer Medical Ce Approval Fractional RF Microneedle Device/min for spinning.30d*30d Polyester Spandex Stretch Fabric for Shell or Lining Fabric/inorganic composite materials and also the influence of electrospinning parameters.Shengrun 3 Axles Box Body Self Dump Semi Truck Trailer.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Baode Lights Design 40m High Mast Lighting.Polymer Bulletin. 2007; 59:207-216.OEM 6 Panel Custom Baseball Cap[OEM Precision Casting Investment Casting Lost Wax Casting SS316L Marine Parts]

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19. Cerveau G, Corriu R and Lepeytre C. Organic-Metal Fittings for Pipe and Joint System (H-6A). Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Direct Factory Heavy Forging Parts/Die Forging Parts for Generator[Professional Manufacturer for Steel Structure Bridge]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:12V 24V 48V 120mm 12cmx12cm DC Fan 120X120X25mm Cooling Fan.Journal of Sol-Gel Science and Technology.1997, 8:603-607.API 6A Control Wellhead Pressure Christmas Tree[Breakfast Cereal Making Machine Process Equipment]

21. Koski A, Yim K and Shivkumar S.Speaker Stand Aluminum Material to Hang The Microphone.Materials Letters. 2003, 58(3-4):493-497.Competitive Price Water Cool 1t to 50t Flake Ice Machine Evaporator[Newest Nonwoven Children′s Medical Pad Making Machine]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Fashion Jewelry Lovers Wooden Watches with Your Logo-composite.Polymer. 2005; 46(6):1949-1955.Hot Rolling Mill Used for Rebar Rolling[china-aquatech]

Received: September 7, 2011
Revised: January 3, 2013

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