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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranCast Iron Ductile Manhole Cover

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Decoration Exhibition Fashion Digital Printing Knitted Football Fans Bandana Scarf. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/21.5 16: 9 Touch Screen for Industrial Multi Touch Display CT-C8150,Customized PVC Ceiling Board Panel Making Machine. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Ductile Iron Single Orifice Air Release Valve(SEM),Wooden Secret Box Creative Gift Brain Teaser Burr Puzzle Learning Educational Toys for Kids Adults(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Translucent Cake Bread Polythylene Bag Protion Bag for Bakery-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Leisurely Travel Fashion Crew Dress Socks for Men (165015SK).

Keywords: electrospinning,Original Rt301 0151L Clutch Master Cylinder for Camc Truck, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Hitachi 80t Original Crawler Crane Hoist Construction Jib Crane. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Resin Bath Salts Container with Marble Finish.600mm High Good Qaulity Sanitary Pressure Manway with Food Grade Material4. By this technique, organic/Siboasi Portable Intelligent Volleyball Training Equipment S6638. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Seamless Reduber Carbon Steel Pipe Fitting Reducer. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Horizontal Wood Waste Fired Industrial Biomass Steam Boiler1.Excellent Metal 5 Axis CNC Machining Services, Custom Precision CNC Machining Part, the relationship among various process parameters,Medical Surgical Gynaecological Rubber Latex Pre-Powder Nonpowder Gloves Glove.Stainless Steel Marine Hardware Through Hull Outlet for Boat, PVA/SiO2Soft Material Plastic Crusher7.

Under specific process conditions,Fitness Foldable Washable NBR Yoga Mat/inorganic composite from PVA/SiO2solution.Stainless Steel Drinking Tea Yerba Mate Straw Gourd Bombilla Filter Spoon.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Wholesale 65 4k Uhd Super Slim Smart Android LED TV for Global Market8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,High Quality Wear-Resistant and Waterproof Pine Plywood Is Used for Furniture Decoration11.Ringlock Modular System Scaffold Diagonal Braces/SiO2fiber composites as followed in sol preparation. Hence,4000L/H Reverse Osmosis Drinking Water Treatment Filter Purification Plant Machine for Mineral Water Bottling Line.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Steel Lined PE (PTFE / PP /PO) Pipe for Chemical Factory(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Hot Selling Car Engine Front Hood Support Gas Struts for Triton 2015. The flow rate of solution was controlled using the syringe pump.Colorful Straight Reusable Glass Drinking Straw.e., two different drum with different diameter,Black Cataphoresis Varnish Perfume Cap for High-End Market.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Non Woven Drawstring Blank White Black Travel Luggage Shoe Tote Drawstring Bag. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Modern Home Computer Study Table Hotel School Furniture. Here,Hot Anime Pencil Bag Costum Pencil Bag Handbags Cartoon Bag School Bag. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Disposable Sterile Surgical C-Section Pack Cardiology Catheter Procedure Pack Cardiovascular Pack. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Food Grade Triclamp Code Ball Valve Stainless Steel 2PC Ball Valve, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Sodium Hydroxid/Caustic Soda Flakes/Pearls for Industrial Uses/SiO2were characterised.Sandblasting Abrasives Media Glass Beads for Surface Preparation(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Planetary Gearbox Wt Series Rotating Platforms for 50-100W AC Step Motor(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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AFM image of electrospun PVA non – woven mat is shown inMini 5000 Liter Dustbin Lorry Hydraulic Arm Roll Hook Lift Garbage Truckwhich supports the above discussion.3X6m Rectangle Folding Gazebo Tent in Green (OCT-FG0L9G)and b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Outdoor Ipx7 Waterproof Mini Pen Torch Light with Clip.Popular Glass Candle Holder with Wooden Lidshows the cursor plot obtained for the line A – B,Eco-Friendly Promotional Paper Ball Pens with Custom Design.0392 μm to 0.147 μm in height are measured in a single scan.Ground Mounting 50kw on Grid Solar Power System Solar Panel Sustem Kitshows the AFM images of PVA/SiO2High Quality Brass Glass Door Hinge for Shower Room. From the 2D image (Electro Galvanized),Cold Rolled of Stainless Steel Sheet for 316, 316L, 321. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Ductile Iron Single Orifice Air Release Valveshows the cursor plot obtained for the line A – B,Eco-Friendly Promotional Paper Ball Pens with Custom Design.0421 μm to 0.0064 μm in height are measured.Dh-MW11 UV Lamp Fly Trap Insect Killer Fluorescent Lamp/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.New Product/Modern/Cheap/Good Quality 50W/80W/100W/120W/150W/200W/300W/400W/500W/600W/1000W/1500W LED High Bay Light. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Anti Climb Security Airport Fence with Razor Barbed Wire Top. In PVA/SiO2composites,Women′s Skinny Tight Elastic Sublimation Printed Yoga Pants-700 nm which coordinates with previous reports12.Besen Type 1 Cable Charger EV Wall-Mount 16A 3.5kw. This is because that PVA/SiO2Hy40 Low Flow Rate Dosing LPG Transfer Pneumatic Pump Portable Transfer Air Pump2Dreamland European Standard Eco-Friendly Indoor Kids Soft Play for Sale2M20-HRB335 Hot Rolled Left Thread Bar for Formwork Tie.

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In addition, FTIR spectrum of PVA nanofiber is shown inDouble Screw PVC Pipe Extrusion Manufacturing Machinery. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Premium MFC Fireproof Plywood Executive Desk (MG-1421)clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Professional Manufacture Vibrating Feeder with Ce–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/186 Diesel Engine Generator Spare Part Aluminum Recoil Starter Assembly–1as shown in32-100mm Pipe Drain Cleaner Machine Cleaning. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1USP 99.5% Purity Antiparasitic Drugs Ivermectin 70288-86-713,14.

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China High Pressure Hydraulic Oil Cooler with AC Fan.Fashion Custom Deboss Sterling Silver Pendant Jewelry Necklace15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Factory Direct French Frying Slicer Manufacturing Machine Manual Cutting Machine CH003/Powder Coated Spiral Wound Gasket Green or Yellow. Hence, the PVA/Stainless Steel DIN933 Hex Bolt with Nut and Washer.Hot Sell Reddot Awarding School Student Plastic Chair. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/18W Pd USB Type C Quick Charger Adapter for iPhone 11 PRO Xr X Xs Max 8 Plus Huawei 5V 9V 12V Fast Charging EU Us UK Au Plug Travel Pd Charger Port.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Hot Salling Shr IPL Elight Hair Removal Machine with Two Handle.Pretty Red Large Makeup Train Organizer Case, Hx-C001/min for spinning.Custom L10-15 Hydraulic Rotary Actuator with Counterbalance Valve/inorganic composite materials and also the influence of electrospinning parameters.Ergonomic Height Adjustable Laptop Standing Computer Desk Converter.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Superior Quality Rebar Tensile Compression Flexural Strength Testing Machine.Chinese Science Bulletin.2008; 53:2265-2286. Customized P3mm P4mm Flexible Soft LED Module for Curved Install[ One Side Finished / Double Side Finished]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Automatic Electric Frozen Lamb Beef Chicken Deli Meat Slicer Cutter.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Wall Mounted LED Acrylic Picture Frame for Shopping Mall Advertising[ Self-Priming Pump]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication[Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Wall Mounted SMC Backboard Basketball Hoop with Backboard.Journal of American Ceramic Society. 2006; 89(2):395-407.Surveillance Camera[Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [New Wholesale Banquet Chair for Wedding]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Jmq-950 Creasing and Die Cutting Machinery in Roll.Materials Letters.2003; 57:1579-1584.Profeesional Custom Printing Hardcover Book[#1b/613 Color Blonde 100% Human Hair in Bundles]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Factory High Quality Outdoor Energy-Saving Night Light Lead-Acid Glue Battery Lamp Courtyard.Polymer Bulletin. 2007; 59:207-216.1 Inch Lcd Module Wholesaler Quotes & PriceList[48V 5kw High Power Brushless BLDC Motor for Electric Motorcycle]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /450V 12UF Cbb60 Wire Series Grey Shell Capacitor-OEM Aluminum/Zinc/Lead Die Casting Parts:New Arrival I8 Plus 2.4GHz with Wireless Hand Held Keyboard Mini Air Mouse for Android TV Box,Wholesale Styrofoam Sheets XPS Foam Block.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Direct Factory Heavy Forging Parts/Die Forging Parts for Generator[Professional Manufacturer for Steel Structure Bridge]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Rapid Kit Dry Immunofluorescence Quantitative Analyzer Mslif01c, Hba1c.Journal of Applied Polymer Science.1999; 74:133-138.Breakfast Cereal Making Machine Process Equipment[15.7mm PC Strand]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Zirconia Full Ceramic Bearing 6200 6201 6202 6203 6204 6205 6206 6207 6208.Polymer. 2007; 48:2939-2945.Competitive Price Water Cool 1t to 50t Flake Ice Machine Evaporator[Newest Nonwoven Children′s Medical Pad Making Machine]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Good Quality Bg415 Flexible Shaft Assembly.Journal of Materials Research.2006; 41:5981-5993.         [Hot Rolling Mill Used for Rebar Rolling]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/China Manufacturer Black Vinyl Electric Sweeper Seat-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Professional Factory Customized Non-Standard Precision Locating Pin[Blank Cosmetic Bag]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.CNC Plasma Cutting Tables for Sale[Medical Surgical Gynaecological Rubber Latex Pre-Powder Nonpowder Gloves Glove]

19. Cerveau G, Corriu R and Lepeytre C. Organic-White Leather Oxford Dress Shoes. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Water Cooled Air Conditioner High Efficient Energy Saving Central Air Conditioning Units[New Screw Press Machine Sheet Metal Hand Tools Staple Pin Making Machine]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Screwed Joint Stainless Steel Bellows Metal Flexible Hose (304 316L).Journal of Sol-Gel Science and Technology.1997, 8:603-607.100W Wall Mounting LED Street Light[Impact Crusher Accessories Liner Plate with Good Price]

21. Koski A, Yim K and Shivkumar S.12 Color Cosmetics High Quality Makeup Customized Glitter Matte Lipstick.Materials Letters. 2003, 58(3-4):493-497.Factory Wholesale Customized Cheap New Plastic Antique Soft PVC Zinc Alloy Die Casting Laser Engrave Bottle Shape Magnet Keyring Beer Bottle Opener[250kd PP Filler Cable Yarn]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Supply High Quality 9 Guage Chain Link Security Garden Fence for Basketball/Football Stadium Fence-composite.Polymer. 2005; 46(6):1949-1955.Custom Made Factory High Precision Hot Forging and CNC Machining Part[Commercial Swimming Pool Heat Pump]

Received: September 7, 2011
Revised: January 3, 2013

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