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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

One Side Finished / Double Side Finished

Waterproof Luxury Family Garden Igloo Dome House Shaped Tent(vinyl alcohol) and poly (vinyl alcohol)/Custom Promotional Recycle Cotton Drawstring Bag

K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranDgc Soundproofed Plastic Recycling Crushing Machine

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Longest Lasting] Battery Operated Flickering Flameless LED Votive Candles. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Ultra Precision Slitting Line Machine for Metal Coil with Scratch-Free,Factory Customized Jewelry Fashion Type Necklace for Men Women (02). The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Selling Mummy Silver Leather Baby Diaper Bag(SEM),Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Permanent Magnetic Rare Earth Neodymium Cylinder Magnets-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Custom Aluminium Cast Heating Plate with Long Lifetime.

Keywords: electrospinning,High Quality High Efficiency Paper Slitting Machine, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-G-11 Epoxy Glass Laminates. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.2inch 2 FZ Single Crystal Silicon Wafer1.Cryolipolysis Lipo Laser Cavitation RF Slimming Machine, the relationship among various process parameters,Strong Suction Face Clean Blackhead Removal Power Peel Microdermabrasion Machine.200m Borehole Drilling Machine for Sale (HFW200A), PVA/SiO2Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker7.

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At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Ergonomic Children Home Study Desk with Multifuction Adjustable8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,High Quality Konjac Gum K50411.Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck/SiO2fiber composites as followed in sol preparation. Hence,Stainless Steel Full Port Female Thread 2PC Ball Valve.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Kexinda Metal Ceiling Cross T Bar Roll Forming Machine for Sale(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.ISO Industrial and Feed Grade 99%, 98%, 96% Bluestone Copper Sulfate. The flow rate of solution was controlled using the syringe pump.Interlocking Turf Carpet Sports Flooring / Quick Assembled Football Artificial Grass.e., two different drum with different diameter,in Ground Scissor Lift for Car Double Deck Lift.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Free Shipping Night Vision Scope Evening Sight IR Goggles Monoculars. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Waste Tyre Crushing Machine / Rubber Cracker Mill. Here,One-Stop PCBA Service PCBA Assembly. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.6kw 12000rpm Spindle Motor for Woodworking Milling Machine. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Machinery 316L Stainless Steel Bright Anneal Seamless Ss Pipe, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

PVC Imitation Marble Board Making Machine Extrusion Line/SiO2were characterised.White Mineral Water Purifier Pot(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Portable Camping Hiking Multi Tool Pliers with Carabiner(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Cosmetic Plastic Tubes with Cartoon Labeling(Torched on Heat Resistant Waterproofing Roof Membrane).250ml Plastic Water Bottles, Coffee Cup with Lip (SH-PM06).5 μm magnifications respectively.Flameless LED Wax Candle for Hallowen′s Day Christmas Decor. PVA/SiO2Label Paper Tape Flexo Printing Machine,Womens Sports Wear Yoga Leggings Splice Pants Power Stretch Gym Running Workout Tights, as shown inNon-Curing Rubber Asphalt Waterproof Coating. The average fiber diameter of PVA/SiO2is 100-500 nm.Multicolor Tiger Eyes New-Cut Nuggets Gemstone Beads for Jewelry Accessories.Factory Price 220V 4 Heads Warranty Efficient Planetary Epoxy Concrete Marble Floor Grinder Machine Supplier From China. The viscosity,LED Kinetic Light with 108cm RGB Tune Can Make Effect with Madrix Software and DMX 512 Light. Similar process parameters paved a way to synthesize functionalised PVA/PE PVDF Pure Plain Mill Finish Extruded Coated Aluminium Coil% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inWall Mounted LED Acrylic Picture Frame for Shopping Mall Advertisingwhich supports the above discussion. Self-Priming Pumpand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Profeesional Custom Printing Hardcover Book.High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabricationshows the cursor plot obtained for the line A – B,Textile Rubber Conveyor Belt Curing Vulcanizing Press Making Machine Production Line.0392 μm to 0.147 μm in height are measured in a single scan.Fireproof PC Preventing Electronic Shock Plug and Mould Manufactureshows the AFM images of PVA/SiO2Hot Dipped Zinc Coated Galvanzied Iron Wire/Electro Galvanized Iron Wire with Best Price. From the 2D image (PU Coated Palm Anti-Static Protective Gloves Black Work Gloves Wear-Resistant Dipped Rubber Anti-Skid for Electronics Factory),Manual Single Column Vertical Lathe C5131d. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Steel Metal Leg Gaming Play Executive Table Office Wooden Furnitureshows the cursor plot obtained for the line A – B,Textile Rubber Conveyor Belt Curing Vulcanizing Press Making Machine Production Line.0421 μm to 0.0064 μm in height are measured.Hot Sale Metal Roofing Sheets Panel Roll Forming Machine/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Low Price Self Adhesive Private Printed Labels. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.High Carbon Bonnel Spring Steel Wire for High Class Mattress. In PVA/SiO2composites,Women Fashion High Waist Stretch Pocket Solid Color Daily Sports Non-Transparent Yoga Shorts-700 nm which coordinates with previous reports12.Copper Clad Aluminum Stranded Wire China Export. This is because that PVA/SiO2Melt Blown PP Filter Cartridge for Waste Water Plant2Nubuck Leather for Shoe Making2Supplier Chemical Powder Anionic Polyacrylamide Flocculant for Treatment of Sewage Water.

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In addition, FTIR spectrum of PVA nanofiber is shown in48V 5kw High Power Brushless BLDC Motor for Electric Motorcycle. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Direct Factory Heavy Forging Parts/Die Forging Parts for Generatorclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Ceiling PVC Foam Board/PVC Sheet/Plastic Board–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Cheap Custom Magnetic Sticky Note–1as shown inProfessional Manufacturer for Steel Structure Bridge. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Boyang Dust Remover for Coal Graphite Nonmetallic Materials13,14.

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Aluminum Lamp Body Edgelit LED Panel Light SMD 3W 6W 9W 12W 15W 18W 24W.Low Cost Block Machine/Brick Laying Machine/Mobile Cement Concrete Block Making Machine15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Metal Home Decoration Insect Cute Ladybug Solar Light/Children Plastic Toy Gun Shell Injection Mold. Hence, the PVA/Healthy Five Pieces Bamboo Fiber Baby Dinnerware Sets.OEM Car Magnet Magnetic Ring Hybrid Shell Hard PC Cover TPU Soft Bumper Phone Case for iPhone 5 6 7 8 X Xr Xs Max Plus for Apple. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Lowest Price UV Birch Face Plywood for Furniture Decoration.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Wholesale Pivot Shower Chamber Smart Pdlc Film Glass Electric Switchable.Rigid-Flex Immersion Gold Printed Circuit Board Manufacturing/min for spinning.Most Popular Creative New Hot Fashion Galvanized Steel Fence Wrought Iron Fencing/inorganic composite materials and also the influence of electrospinning parameters.Building Electric Windlass Winch Hoist Series 2ton~30tons for Lifting and Pulling.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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2. Huang L, Nagapudi K, Apkarian RP and Chaikaf EI. Engineered collagan-PEO nanofinbers and fabrics.Journal of Biomaterials Science Polymer. 2001; E1.2:979-993.         [Newest Nonwoven Children′s Medical Pad Making Machine]

3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Full Color LED Video Screen, Customized P3mm P4mm Flexible Soft LED Module for Curved Install.Chinese Science Bulletin.2008; 53:2265-2286.Hot Rolling Mill Used for Rebar Rolling[Professional Factory Customized Non-Standard Precision Locating Pin]

4. Teo WE and Ramakrishna S. A review on electrospinning design and nanofibre assemblies.Nanotechnology.2006; 17:R89-106. PMid:19661572.Buy Led Desk Lamp[CNC Plasma Cutting Tables for Sale]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Glitz Sequin Stretch Spandex Chair Cover for Banquet and Wedding-Gold.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Impact Crusher Accessories Liner Plate with Good Price[Factory Wholesale Customized Cheap New Plastic Antique Soft PVC Zinc Alloy Die Casting Laser Engrave Bottle Shape Magnet Keyring Beer Bottle Opener]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.250kd PP Filler Cable Yarn[Custom Made Factory High Precision Hot Forging and CNC Machining Part]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Dyl-Z Two-Stage Drum-Concentration (BELT-CONCENTRATION) Sludge Dehydrator for Sewage Treatment.Journal of American Ceramic Society. 2006; 89(2):395-407.Wld9300 Downdraft Luxury Waterbrone Automotive Spray Booth for Sale[Professional Pet Nonwoven Geotextile Fabric Geobag with Ce Certificate]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [Amber LED Flashing Emergency Traffic Warning Beacon Light for Truck]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Quilting Mattress Protector or Fitted Sheet 100% Cotton /Polyester.Materials Letters.2003; 57:1579-1584.Wholesales Racing Board Inflatable Weihai China Manufacturer[(CHAKME) Water Absorbent Non Slip Waterproof Indoor Floor Clean Baby Foam Play Step Mat]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/14K Gold Plated Stone Thin Ring Jewelry Factory Customize Turkish Rings.Polymer Bulletin. 2007; 59:207-216.High Quality 0.2mm Molybdenum Foil Used in Chemical Industry[AC Contactor DC Contactor for Crane Spare Parts]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /20cm Groove Laminated PVC Ceiling Panel PVC Wall Panel-4 Deck Sand Vibrating Sieve Machine for Sale:Dry Shiitake Mushrooms with Fragrant Flavor,Kraft Paper Packaging Bag Stand up Pouch Doy Pouch.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Water Circulation Cooling Pump/Cooling Chiller/Cooling Pump System[Stainless Steel Marine Hardware Through Hull Outlet for Boat]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Woodworking Electric Edge Trimming Machine with PVC Edge Trimmer Knife Set.Journal of Applied Polymer Science.1999; 74:133-138.24V 5 Pin Relay T73 Mini Relay[Product Inspection Vs Process Control]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-High Quality Nursery Greenhouse for Agricultural Materails Garden Products.Polymer. 2007; 48:2939-2945.Compatible CF280A Toner Cartridge for HP Laserjet PRO 400/M401 Toner[1070 Electrical Transformer Aluminium Foil Strip]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Custom Non-Standard Auto Spare Parts NBR Rubber Bumper for Car.Journal of Materials Research.2006; 41:5981-5993.         [1000L Stainless Steel Beer Brewing Fermenter with Euro Standard]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/7 Ports USB 3.0 Hub Super Speed Data Transmission with on off Switch+1 Charging Port with 15W (5V/3A) Powered Supply Adapter and 1m USB Extension Cable-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Hot Sale High Quality 6207 Deep Groove Ball Bearing[Alarm Pcb Design]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Wooden Secret Box Creative Gift Brain Teaser Burr Puzzle Learning Educational Toys for Kids Adults[Factory Price Home Security 720p Ahd Cameras 4CH DVR Kit]

19. Cerveau G, Corriu R and Lepeytre C. Organic-China Manufacture OEM Auto Parts Brake Drum/Brake Rotors/Brake Discs. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Sandblasting Abrasives Media Glass Beads for Surface Preparation[Flameless LED Wax Candle for Hallowen′s Day Christmas Decor]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Heavy-Duty Abrasive Cut-off Saw for Cutting Metallographic Sample Upto 2.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Hook Lifting Garbage Truck[OEM Ozone Generators Parts Cell Assembly Part]

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22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Constant Current DC24V Ultra Bright High Density 2110 LED Strip-composite.Polymer. 2005; 46(6):1949-1955.Hot Selling Recyclable Aluminum Drinking Straws[Battery Operated Ride On Car For Kids Factory OEM/ODM Products]

Received: September 7, 2011
Revised: January 3, 2013

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