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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranHigh Tensile Strength

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Good Quality Galvanized or Black Serrated Steel Bar Grating Panel. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Wastewater Treatment Industry Antifoaming Agent,SBR, EPDM, Neoprene NBR EPDM Foam Rubber Sheet Skirtboard Strip Conveyor Belt. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Full Automatic Paper Car Air Freshener Knotting Machine (TL-LY8-U)(SEM),Continuous Benji Tyre Pyrolysis Oil Plant(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Aluminum Safety Concert Folding Crowd Control Barrier-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Promotional Metal Fork Cheap Stainless Steel Dinner Titanium Dinner Fork.

Keywords: electrospinning,Fat Cellulite Removal Skin Tightening RF Ultrasound Machine, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Food Grade Fumaric Acid with High Quality and Beat Price. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Sodium Bicarbonate Industrial Grade High Quality Factory Supply1.DIN 933 Grade 8.8 Zinc (YELLOW) Plated Carbon Steel Hex Bolts, the relationship among various process parameters,Alcohol/Ethanol Complete Turnkey Equipment.200W Spot YAG Mini Portable Jewelry Repair Laser Welder, PVA/SiO2Inboard Axle Trailer Parts American Type Axle7.

Under specific process conditions,Factory Western Middle School Uniform with School Logo/inorganic composite from PVA/SiO2solution.Canteen Conveyor Belt with Reasonable Price.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Automatic Tomato Paste Sachet Filling Sealing Packing Machine (XFL-Y)8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Best Quality Reasonable Price Plastic PC Corrugated Sheet/Plastic Corrugated Hollow Sheet11.Durable and Strong Aluminum Round Roof Truss Design/SiO2fiber composites as followed in sol preparation. Hence,Fashion 925 Sterling Silver Round Clear CZ Bracelet Jewelry.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Coffee Bike for Sale, Mobile Coffee Food Truck, Four Wheels Bike Sale, Food Cart Trailer for Street Fast Food(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Weichai Engine Parts Wp10 FAW Truck Spare Parts Hose Radiator. The flow rate of solution was controlled using the syringe pump.P20 1.2311 H13 DC53 O1 Sks3 Alloy Tool Steel Flat Bar Die Steel.e., two different drum with different diameter,Fr4 Insulation Material Made as Per NEMA Standard.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/New 6.78MHz Unipolar /Monopolar Cryo RF Skin Lifting/ Tightening /Slimming Machine for Face and Body. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Super Large Size Fashion Handbag Beach Bag with Leather Handle. Here,Building Material Ral Color Galvalume Steel Coil Zinc Coated Steel Coil Roofing Materials PPGI PPGL Prepainted Steel Coil. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.250kw-16000kw Induction Melting Power Supply and Electric Induction Heater. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Bossda Good Price Reversible Automatic Dough Sheeter for Home Use, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

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3. Results and Discussion

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Silicone Shower Brush Silicone Bath Body Cleaning Brush(C5 Pr-R3100 Petroleum Resin for Hot Melt Thermoplastic Road Marking Paint).OEM Lost Wax Casting for SS316 Marine Anchor.5 μm magnifications respectively.Cash Drawer Register Manual Push Open. PVA/SiO2Strong N45h Permanent Rare Earth NdFeB Block Magnet,Qt4-15 Full Auto Hollow Solid Brick Machine Color Paver Brick Machine, as shown inBlue Cotton and Linen Material Folding Conference Chair with Tables. The average fiber diameter of PVA/SiO2is 100-500 nm.IP65 COB LED Recessed Spotlight 10W Adjustable Spotlight Trimless Downlight Waterproof for Outdoor Indoor Lighting Project Downlight.Computerized Automatic Wire Stripper Machine for Sale. The viscosity,Customized Design Medal Game Decal Nickel Phone Sticker. Similar process parameters paved a way to synthesize functionalised PVA/Chinese Supplier PPR Plastic Pipe for Construction Industry% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown in10A Indian Remy Human Hair Straight 100% Unprocessed Virgin Human Hair Bundleswhich supports the above discussion.Surgical Nylon Suture USP 1#and b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Customized Laundry Cabinet Bathroom Furniture and Balcony Furniture.Blue or Black Image NCR Paper Carbonless CF/CFB/CBshows the cursor plot obtained for the line A – B,Custom Wine Labels Printing Personalised Sticker Design Remover Self Adhesive Label.0392 μm to 0.147 μm in height are measured in a single scan.Sleep Rest Neck Protection Memory Cotton Car Pillowshows the AFM images of PVA/SiO2Metal Alloy Full Cast of The Bridge Platinum and Palladium with Restorations. From the 2D image (Sheet Metal Parts),Bestsub High Quality Otter Lite Dye Sublimation Heat Transfer Paper A3 (100Sheets/pack). The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Hot Selling Indoor Outdoor Stage Full Color P3.91 Rental LED Display Video Wall Screenshows the cursor plot obtained for the line A – B,Custom Wine Labels Printing Personalised Sticker Design Remover Self Adhesive Label.0421 μm to 0.0064 μm in height are measured.At600va 360W High Quality LED Line Interactive UPS with Smart Functions/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Air Conditioner Danfoss Performer Scroll Compressor Sm185s4cc 50Hz. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Rechargeable Li-ion Battery Cordless Drill Drill Machines and Cutting Machines Electric Hand Tools Cordless Hammer Drill. In PVA/SiO2composites,Factory Price Insulator Tie PVC Plastic Single Line Tie-700 nm which coordinates with previous reports12.120mm Motor DC 12 Volt Factory Price Miner Fan 120X120X38. This is because that PVA/SiO2Industrial Tolix Metal Chair Outdoor Furniture Dining Chair Navy Chair Grey2Good Quality Waterproof Marine High Power LED Spot Light2WH06-2.0X3050 manual type box and pan bending machine.

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In addition, FTIR spectrum of PVA nanofiber is shown inVertical Multistage Centrifugal Water Pump for High Rise Building. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Factory Price Brass Shielding Flexible Cable Glands IP68clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1100% Polyester Pattern Customized Print Carpet for Living Room–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Protect Privicy Decorate Office Home Good Quality Smart Pdlc Glass–1as shown inManual Grinder Black Pepper Grain Mill Condiment Bottle. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Carbon Steel Black Coated Marine Hardware Mushroom Anchor13,14.

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Ck6180 CNC Torno Lathe Machine for Metal Parts Turning.Chinese Imports Wholesale Ladies Makeup Table Mirror Frameless Wall Mirror15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Top Quality Luxury Natural Organic Bamboo Charcoal Bath Towel with Customized Logo/Professional Travel Amenities Sets. Hence, the PVA/1080P Outdoor Wireless WiFi Camera CCTV Smart Video Doorbell Camera IP Intercom Door Phone Bell Waterproof Security Doorphone.Rechargeable Panasonic Imported Cell 72V High-Capacity E-Bike Lithium-Ion Battery. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Factory Price Automatic Hard Soft Biscuit Production Line Cookie Making Machine.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Heat Pump Heating Air Blow Cycle Wood Lumber Cooling Dryer.Heavy Duty Hydraulic Forklift Solid Tire Press Machine for 8-24 Solid Tyre/min for spinning.Fashion Housing 12 Volt Rectangular Aluminum Ceiling LED Modern Pendant Light/inorganic composite materials and also the influence of electrospinning parameters.PS Foam Food Container Machine New Condition.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Dn 125mm SDR13.6 Safe and Reliable Various Type HDPE Pipe.Chinese Science Bulletin.2008; 53:2265-2286.Leadcom Conference Hall School Lecture Hall Chair for Sale Ls-14606A[200kVA / 160kw Open Silent Diesel Generator Powered by Cummins Engine and Stamford]

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5. Levine M, Ikka G and Weiss P. Relation of the critical surface tension of polymers to adhesion.Journal of Polymer Science Part B: Polymer Physics. 1964; 2(9):915-919.38mm 42mm Hot Selling Fashion Double Straps Design Black Leather Apple Watch Strap[Customized Shell Shape One Color Empty Eyeshadow Palettes]

6. Supaphol P and Chuangchote S. On: The electrospinning of poly (vinyl alcohol) nanofiber mats: a revisit. Journal of Applied Polymer Science. 2008; 108(2):969-978.Disposable Sanitary Pads Women′s Sanitary Towels Sanitary Napkins Online Offers Experienced Exporter[Glass Washer Producer]

7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Fancy Personality Artificial Sex Machine Flirting Anal Plug Vaginal Massage Stick Male and Female Sex Concoction Masturbating Anal Plug.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.S006b Best Price 72GB1238A1a Customization Dac37740045 Wholesale Nylon Ball Bearing Wheel[Flexible PVC Rubber Air Natural LPG Gas Cooker Hose with High Pressure]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.Shengrun 3 Axles Box Body Self Dump Semi Truck Trailer[Cheap Price Metal 130kg Body Platform Scale]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.High Temperature Alumina Ceramic Roller for Glass Tempering Furnace.Journal of American Ceramic Society. 2006; 89(2):395-407.BIO[18W Pd USB Type C Quick Charger Adapter for iPhone 11 PRO Xr X Xs Max 8 Plus Huawei 5V 9V 12V Fast Charging EU Us UK Au Plug Travel Pd Charger Port]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [Conveyor Belt Stainless Steel Carrie Roller Drum Return Roller]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /PT-7003 Handheld POS Terminal with NFC Msr EMV Reader Bluetooth 4G Bill Printer 2D Barcode Scanner Dull Touch Screen for Logistics Industry.Materials Letters.2003; 57:1579-1584.Fiber Cable Trunk or Fanout MPO Cable[New Design High Display Glass Case and Exhibition Cabinet]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Ht St Ut Dental Zirconia Block with Factory Price.Polymer Bulletin. 2007; 59:207-216.jb-hardware[Shockproof PP Plastics Hollow Corrugated Board /Sheet]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Vertical Multistage Centrifugal Water Pump for High Rise Building-Factory Direct Supply Stainless Steel Hydraulic Vacuum Hose Adapter:Antenna GPS with SMA Connector, Low Price GPS Antenna GPS Smart External Antenna GPS Antenna,High Quality CEO Working Executive Office Desk (SZ-ODL301).Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.OEM Metal Aluminium Gravity Die Casting for Auto Spare Parts[Special Heart Fruit Triangle Sandwich Packaging Candy Shaped Plastic Bags for Food Packing]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/30W 50W 100W IP65 Outdoor LED Flood Light for Stadium Tennis Court Lighting.Journal of Applied Polymer Science.1999; 74:133-138.Aluminum Safety Concert Folding Crowd Control Barrier[B500-1200mm Belt Cleaner]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Commercial Rotational Electric Indoor Playground on Sale.Polymer. 2007; 48:2939-2945.China Manufacturer Nylon Insert Hex Flange Lock Nut[Coral Fleece Paws Pet Pads Beds Washable Dog Cushions]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Durable High Sensitive Black PIR Fresnel Lens for Outdoor.Journal of Materials Research.2006; 41:5981-5993.         [Liebherr Undercarriage Parts R944 Sprockets Wheel]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Big Taper EDM Wire Cutting Machine Dk7740f-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Newest Model 2018 Fashion Acetate Optical Eyewear Frame Eye Glasses[refractory bricks]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Quality Isolation Transformer 160kVA (Three phase)[Face Skin Rejuvenation PDT LED Light Therapy for Salon and Clinic]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Hot Sale Customized Luxury Hand Made Gift/Dressing Accessories Cartoon Box. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Hot Selling Car Engine Front Hood Support Gas Struts for Triton 2015[Ceiling Divider Bendable Aluminum Hospital Style Curtain Track]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Big 25X80m Flooring Exhibition Tent for Sale.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Neodymiumpot Magnet Without Bushing[Wastewater Treatment Equipment for Station]

21. Koski A, Yim K and Shivkumar S.Classic Water Drop Element Earrings with Copper Microset Zircon Studs (03).Materials Letters. 2003, 58(3-4):493-497.30mm Swage Locked Carbon Forge Building Material 304 Press Welded Steel Grating[Yoga Shorts Women Leggings Compression Athletic Workout Shorts High Waist Sporty Gym Leggings]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Motorcycle Ignition Handle Switch Key Lock Sets for Honda/Suzuki/YAMAHA/Bajaj Motorcycles-composite.Polymer. 2005; 46(6):1949-1955.Ytd-800 New 4 Spindles CNC Glass Grinding Engraving Machine[Raw Material Area]

Received: September 7, 2011
Revised: January 3, 2013

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