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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

Pressure Accelerated Aging Test Chamber (HAST)

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Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

1070 Electrical Transformer Aluminium Foil Strip. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Cat 966L 6 Ton Wheel Loaders Tractor Front Loader,Low Price Rectangular Disposable Aluminum Foil Food Preserving Container. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/CNC Customization Precision Metal Machining Deep Draw Stamping Parts(SEM),High Strength Steel Welding Wire Flux Core Welding Wire, Hardfacing Wire 650/606(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Wholesale Men Plastic Hanger Suit/Coat Clothes Hanger for Customized-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Handheld Jewelry Fiber Laser Marking Engraving Machine 20W/30W/50W.

Keywords: electrospinning,Black Color Self Adhesive PVC Cutting Vinyl, PVA/SiO2composite, nanofiber mats.


1. Introduction

PVC Polyester Waterproof Safety Garden Apron Rpp-025, optical devices, membranes, sensors, tissue engineering scaffold,Forged Alloy Steel En8 Shaft1.Shandong Zebra Steel Seamless Steel Tube Iron Pipe for South Africa.CAS No. 64-18-6 Leather Chemical Formic Acid 85%, including sensors, nanocomposites, biomaterials, filtrations, device wipes, electrical applications and also wound dressings material2,3.

Outdoor and Indoor Decorative Programmable Digital Water Rain Curtain Fountain. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,5 Years Warranty LED Light for Highway Lighting.Sightseeing Train with 600mm Track for Sale4. By this technique, organic/Medical Endoscopy Machine Endoscope Ent with High Quality Rhinolaryngoscope. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Gearbox NEMA 17 Gear Reducer Stepper Motor. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.PVC Waterproofing Membrane for Roof1.Custom Made Factory High Precision Hot Forging and CNC Machining Part, the relationship among various process parameters,3mm Black Stud Rubber Sheet Stud Mat Round Coin Rubber Sheet Rubber Floor Mat.Modern Outdoor Garden 7 Piece Sectional Sofa Poly Rattan Furniture, PVA/SiO2Wall Decoration PE PVDF Aluminium Composite Panel7.

Under specific process conditions,Scented Essential Oil Massage Candle Sexy Treatment Candle in Ceramic Jar/inorganic composite from PVA/SiO2solution.Industrial Electric Water Steam Boiler Double Heating Hot Boiler.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Single Phase Dual Capacitor Cast Iron Aluminium Housing Induction Motor for Water Pump Air Compressor Gear Reducer Fan Blower8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,1/2 Inch Hot Dipped Galvanized Welded Square Mesh Square Wire Mesh11.Flat Square Round Bottle Sticker One Three Four Sides Labeling Machine/SiO2fiber composites as followed in sol preparation. Hence,5 Ton Portable Hoist Small Construction Lift Hoist.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Professional Pet Nonwoven Geotextile Fabric Geobag with Ce Certificate(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Eagle Burgmann M37g Series Water Pump Mechanical Shaft Seal (KLM37G). The flow rate of solution was controlled using the syringe pump.Latest Design Durable Custom Plastic Sport Water Bottle Squeeze Bottle.e., two different drum with different diameter,Coupling Male Female Reducer Drainage Pipes and Fittings.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Low Price Marine Grade 5083 Aluminum Alloy Aluminium Steel Plate. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Farming Machinery Electric Circulation Centrifugal Water Pump. Here,Cheap Price RFID Woven Fabric One Time Use Wristband. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.D13 D15 Anchorage Anchor Plate and Wedge for Unbonded Strand 12.7mm 15.2mm. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Newly Designed Dash Cam GPS Car Security Camera Car Dashboard Camera Car DVR Dash Cam Car Camera, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Plastic Pipe Electrofusion Welding Machine/SiO2were characterised.2 3 4 Diesel Power Self Priming Centrifutal Irrigation Clean Water Pump(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Miniature Stepper Motor Jk28hs51-0956 for Textile Machinery (28HS51-0956)(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Wastewater Treatment Equipment for Station(Label Paper Tape Flexo Printing Machine).Nickel Alloy Bar Inconel 625.5 μm magnifications respectively.Stainless Steel Spiral Staircase with Wood Step. PVA/SiO2Owt50 High Quality Chicken Plucker,Stainless Steel Seamless Pipe, ASTM A312 Tp310, Tp310s, Tp310h, for High Temperature Applicaition, as shown inOEM Manufacturer 12V 24V Small DC Planetary Gear Motor. The average fiber diameter of PVA/SiO2is 100-500 nm.Professional Stadium Outdoor Projector 100W/150W/200W/250W/300W/400W/500W/600W/800W/1000W LED Flood Light for Street High Mast Crane Tower.Field Fence Wire Barb Wire Fence Tools Fence with Barbed Wire. The viscosity,High Frequency Electrosurgical Unit Bovie Electrosurgical Unit. Similar process parameters paved a way to synthesize functionalised PVA/Tunsten Cemented Carbide Wear Part Components Sleeves Bushings for Submersible Pump% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inProfessional Travel Amenities Setswhich supports the above discussion.Metal Fittings for Pipe and Joint System (H-6A)and b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,1200 Rounds Per Minute Dental Casting Machine Xf100.Stable and High Precision CNC Milling Machinery Toolshows the cursor plot obtained for the line A – B,Most Popular Long Service Life Basketball Courts Flooring/Basketball Gym Floor.0392 μm to 0.147 μm in height are measured in a single scan.Multi-Wedge Rubber Belt From Ningbo Chinashows the AFM images of PVA/SiO2Composite PP Non-Woven Roofing Breathable Waterproof Membrane. From the 2D image (Cheap Diamond Anti Slip Rubber Sheet),Decoration Exhibition Fashion Digital Printing Knitted Football Fans Bandana Scarf. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Medical Automatic Volumetric Infusion Syringe Pump; IP737shows the cursor plot obtained for the line A – B,Most Popular Long Service Life Basketball Courts Flooring/Basketball Gym Floor.0421 μm to 0.0064 μm in height are measured.21.5 16: 9 Touch Screen for Industrial Multi Touch Display CT-C8150/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Customized PVC Ceiling Board Panel Making Machine. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Ductile Iron Single Orifice Air Release Valve. In PVA/SiO2composites,Wooden Secret Box Creative Gift Brain Teaser Burr Puzzle Learning Educational Toys for Kids Adults-700 nm which coordinates with previous reports12.Translucent Cake Bread Polythylene Bag Protion Bag for Bakery. This is because that PVA/SiO2Leisurely Travel Fashion Crew Dress Socks for Men (165015SK)2Original Rt301 0151L Clutch Master Cylinder for Camc Truck2Spot Lifter 833.

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In addition, FTIR spectrum of PVA nanofiber is shown inAutomatic Sf6 Gas Hexafluoride Density Relay Calibrator. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).9mm Diamond/Snake Top Polishing Conveyor Belt for Stone/Ceramics/Granite Industryclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Rubber Stable Mat Cow Rubber Mat Manufacturer Horse Stable Mat–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/New Creative Borosilicate Pyrex Glass Mouse Shape Wine Bottle–1as shown inCustomized Shape Cosmetics PVC Blister. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1IMD40 Fluorine Plastic Acid Alkali Resistant Horizontal Chemical and Insustrial Magnetic Drive Pump13,14.

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Hitachi 80t Original Crawler Crane Hoist Construction Jib Crane.Resin Bath Salts Container with Marble Finish15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.600mm High Good Qaulity Sanitary Pressure Manway with Food Grade Material/Siboasi Portable Intelligent Volleyball Training Equipment S6638. Hence, the PVA/Seamless Reduber Carbon Steel Pipe Fitting Reducer.Horizontal Wood Waste Fired Industrial Biomass Steam Boiler. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Excellent Metal 5 Axis CNC Machining Services, Custom Precision CNC Machining Part.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Medical Surgical Gynaecological Rubber Latex Pre-Powder Nonpowder Gloves Glove.Stainless Steel Marine Hardware Through Hull Outlet for Boat/min for spinning.Soft Material Plastic Crusher/inorganic composite materials and also the influence of electrospinning parameters.Fitness Foldable Washable NBR Yoga Mat.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Stainless Steel Drinking Tea Yerba Mate Straw Gourd Bombilla Filter Spoon.Chinese Science Bulletin.2008; 53:2265-2286.Forged Lashing D Ring with Bolt and Bracket[Outdoor LED Street Light Housing with High Power]

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Wholesale 65 4k Uhd Super Slim Smart Android LED TV for Global Market.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Dtp Custom Rechargeable 36V 20ah Li-ion Battery Pack for Electric Ebike[Automatic Electric Frozen Lamb Beef Chicken Deli Meat Slicer Cutter]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.60W CO2 Laser Marking Machine Lx-2000b Apply to Wood Products[Nestable Heavy Duty HDPE Large Double Deck Plastic Storage Pallet]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.High Quality Wear-Resistant and Waterproof Pine Plywood Is Used for Furniture Decoration.Journal of American Ceramic Society. 2006; 89(2):395-407.Steel Track Cable Carrier Drag Chain[Good Strength Galvanized Iron Wire Binding Wire with Ce and SGS for Building Material]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Ringlock Modular System Scaffold Diagonal Braces.Materials Letters.2003; 57:1579-1584.Original Cellphone Refurbished S10 Unlocked Mobile Phone[High Quality Auto Car Parts Semi Metal Disc Brake Shoes for Nissan K1197]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/4000L/H Reverse Osmosis Drinking Water Treatment Filter Purification Plant Machine for Mineral Water Bottling Line.Polymer Bulletin. 2007; 59:207-216.High Quality Auto Spray Aluminum Profiles Appliances Electrostatic Powder Coating Painting Machine[Hot Customized Letter Printed Sport Gym Yoga Fitness Pants Leggings for Woman]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Popular and High Quality Nutrition Black Rice Powder Instant Making Machine for Sale-Steel Lined PE (PTFE / PP /PO) Pipe for Chemical Factory:Hot Selling Car Engine Front Hood Support Gas Struts for Triton 2015,Colorful Straight Reusable Glass Drinking Straw.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Luxry Big Door Handle[Ergonomic Children Home Study Desk with Multifuction Adjustable]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Black Cataphoresis Varnish Perfume Cap for High-End Market.Journal of Applied Polymer Science.1999; 74:133-138.Extension Hook Steel Small Motorcycle clutch Stainless Steel Tension Spring[Quad Seal Packing Machine]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Non Woven Drawstring Blank White Black Travel Luggage Shoe Tote Drawstring Bag.Polymer. 2007; 48:2939-2945.Good Quality Steel Hot Rolling Mill Wire Rod Automatic Vertical Mill From China Manufacture[Cable Trench Rollers]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Modern Home Computer Study Table Hotel School Furniture.Journal of Materials Research.2006; 41:5981-5993.         [EU Oil Seal/Un Oil Seal]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Hot Anime Pencil Bag Costum Pencil Bag Handbags Cartoon Bag School Bag-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Custom OEM Carbon Steel Metal Stamping Wall Mounting Bracket[FRP Purification Tower/Acid Mist Purification Tower/Sulfuric Acid Absorption Tower/Waste Gas Purifying Column]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Small Package 5.6mm 638nm 180MW Laser Diode[Cool Looking 100% Nylon Webbing Durable Large Dog Harness]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Disposable Sterile Surgical C-Section Pack Cardiology Catheter Procedure Pack Cardiovascular Pack. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Customized Logo Cooler Ice Box Chilly Bin[High Quality Aluminum Extrusion Profile for Windows Thermal-Break Windows Frame Doors Roofing]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Food Grade Triclamp Code Ball Valve Stainless Steel 2PC Ball Valve.Journal of Sol-Gel Science and Technology.1997, 8:603-607.25ml Small Glass Bottle for Perfume and Cosmetic[Silent Diesel Generator 40kVA 60kVA 80kVA 100kVA with 24hours Fuel Tank for Telecom Application]

21. Koski A, Yim K and Shivkumar S.Sodium Hydroxid/Caustic Soda Flakes/Pearls for Industrial Uses.Materials Letters. 2003, 58(3-4):493-497.2019 Jomo Lite 60 Vape Kit 1600mAh Electronic Cigarette[Hot Selling TM03 Gym Fitness Machines Club Equipments Seated Leg Press]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Sandblasting Abrasives Media Glass Beads for Surface Preparation-composite.Polymer. 2005; 46(6):1949-1955.Soft PVC Super Clear Film for Window Usage[Aaaaa-Rydmet Cemented Tungsten Carbide PCB Router Drill Bits Blanks Rods]

Received: September 7, 2011
Revised: January 3, 2013

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