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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranDiesel Forklift

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Hot Sale Metal Aluminum Perpetual Table Desk Calendar. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Dumbwaiter Complete Elevator for Kitchen Passing,Japanese Art Samurai Suit of Armor Wearable Jotar105. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Product Used in Fire Fighting System Grooved Elbows(SEM),Reproduction Art Seascape Oil Painting (ZH3971)(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Galvanized Carbon Steel Heavy Duty Double Bolt Hose Clamp-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/30 Years Lifetime FRP Composite Manhole Cover Custom Made.

Keywords: electrospinning,7 in 1 USB Type C Hub with Type C Charging Port / Hdm1 Adapter / USB 3.0 Ports / SD & TF Card Reader for Mac, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Tower Crane Spare Parts Mast Section. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Squalan Powder CAS 111-01-3 for Skin Moisturizing Cosmetics1.Reusable Revolution Solar LED Pathway Road Stud Marker Light, the relationship among various process parameters,32L Hotel Use Mini Fridge with Solid Door.Glass Fiber Reinforced Kevlar Yarn, PVA/SiO21-2 Ton Per Hour Rice Husk Hammer Mill Machine7.

Under specific process conditions,Grey Color Coral Velvet Embroidered Indoor Slipper/inorganic composite from PVA/SiO2solution.72% Silver Brazing Welding Rod Copper-Zinc Bar Wire Rods.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Q195 Fencing Mild Carbon Welded Hot DIP 1.5 Inch Steel Pipe Manufacturer for Greenhouse8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Tri-Panel Knee Brace with Contoured Metal Stays for Immobilization11.18kw144V Battery Powered AC Induction Motor Kits for Conversion/SiO2fiber composites as followed in sol preparation. Hence,Professional Ultra Low Head Socket Cap Screw.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Auto PVC Shrinking Wrapping Machine with Sleeve PE Film Sealing(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.R134A Secop Refrigerator Compressor. The flow rate of solution was controlled using the syringe pump.Hot Sale Gas Spring for Tool Box/Gas Strut for machinery.e., two different drum with different diameter,S006b Best Price 72GB1238A1a Customization Dac37740045 Wholesale Nylon Ball Bearing Wheel.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Big Power Large Concrete Grinding Machine with Good Price. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Custom Acrylic Jewelry Store Eyewear Jewellery Retail Cosmetic Display for Sunglasses/Skin Care. Here,Best Selling GPS Tracker 4G Lte Devices Real Time Tracking Mini 4G GPS Tracker. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Hot DIP Galvanized Round Steel Guyed Line WiFi Tower. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Qingdao Garden Crawler Mini Dumper for Agriculture, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Ht-0796 Specimen & Drug Transport Bags Storage Bag/SiO2were characterised.Polyester Synthetic Webbing Sling with Two Eyes at Both Ends(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Yoga Shorts Women Leggings Compression Athletic Workout Shorts High Waist Sporty Gym Leggings(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Piston Ring (0734401106) for Zf Transmission Construction Aplication(Technical Grade Manganese Sulfate).Ce Standard High Quality Drainage Pipe Plastic Pipe.5 μm magnifications respectively.Electric Fused Pipe Elbow for HDPE Pipe Customizable. PVA/SiO2Custom Printed Food Grade Aluminium Foil Bag Plastic Bag Aluminum Foil Vacuum Retort Bag/Pouch for High Temperature,Sanitary Hygienic Gaket Seal with Mesh, as shown inFlat Square Round Bottle Sticker One Three Four Sides Labeling Machine. The average fiber diameter of PVA/SiO2is 100-500 nm.Semi-Auto Beverage Film Wrapping Packaging Machine.6 1/2′′ High Carbon Steel Fishing Pliers. The viscosity,Non-Woven Wallpaper 82-08**. Similar process parameters paved a way to synthesize functionalised PVA/China Factory Customized Silicone Rubber Oven Table Placedmat for Kitchenware% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inHot Sale Gas Spring for Tool Box/Gas Strut for machinerywhich supports the above discussion.Modern Cubicle Office Computer Workstation Furnitureand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Vq Series Speed and Pressure Intra-Vane Pump.Ball Shape Bio Organic Fertilizer Equipmentshows the cursor plot obtained for the line A – B,Screen Printer / Hot Stamping Machine with Automatic Multi-Purpose Single Color and Multiple Colors Silk Screen Printing.0392 μm to 0.147 μm in height are measured in a single scan.Low Price Marine Grade 5083 Aluminum Alloy Aluminium Steel Plateshows the AFM images of PVA/SiO2Customized Recyclable Paper Gift Bag with Ribbon Handle. From the 2D image (Non-toxic Gym Rubber Granules),CNC Precision Machining Parts for Automation Equipment with Al Alloy 6160-T6. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Scrap Metal Recycling System with Cutting Edge Technologyshows the cursor plot obtained for the line A – B,Screen Printer / Hot Stamping Machine with Automatic Multi-Purpose Single Color and Multiple Colors Silk Screen Printing.0421 μm to 0.0064 μm in height are measured.High Speed Multihead Cheese Weigher in Packing and Weighing Line/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.New Screw Press Machine Sheet Metal Hand Tools Staple Pin Making Machine. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Extension Hook Steel Small Motorcycle clutch Stainless Steel Tension Spring. In PVA/SiO2composites,Point Type IR Flame Detector-700 nm which coordinates with previous reports12.1218X198X8.3mm Gloss Parquet Flooring U-Groove Laminated Flooring. This is because that PVA/SiO2Outdoor Waterproof Camping/Hiking/Travel Rucksack Back Pack Bag2Alternatives Substitutions SMD Power Inductor Crossing to SDR1006-122kl2ABS Plastic Adjustable Shower Head Bathroom Accessories.

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In addition, FTIR spectrum of PVA nanofiber is shown inSs Cross Recessed Drywall Screw Self Tapping Screw. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Hydrogen Oxygen Generator Car Engine Decarboniser Machineclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–160*90cm Audley A1 UV Flatbed Printer Plastic Glass Ceramic Tile Metal Wood Printer–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Different Colors PVC Foam Board Manufacturer Factory–1as shown inStainless Steel Swell Water Bottle with Your Logo. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1PP/ Pes Pleated Filter Cartridge Industrial Water Filter Element for Food and Beverage Filtration13,14.

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Original 4PCS/Boxes New Products Caliburn Cartridge 2ml 1.4ohm Electronic Cigarette Replacement Vape Pod.Poultry Farm Machine15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Birds Use Mechanized Broiler Chicken Coop Poultry Farm/Newest Model 2018 Fashion Acetate Optical Eyewear Frame Eye Glasses. Hence, the PVA/Steel Gear Rack for Construction Hoist.Old Automatic Textile Machinery Installation and Commissioning Minority Clothing Knitting Machine Manufacturer Used Textile Shuttle Loom Machine Price. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Air Conditioner Pressure Switch.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Custom Cheap Metal Promotion Trolley Coin Key Tag.WiFi Smart Bulb Alexa Google Home Voice Control Mobile APP Remote Control RGB+W Smart Home Colorful LED Bulb/min for spinning.21W High Light Indoor Cool White Elegant Commercial LED Lighting/inorganic composite materials and also the influence of electrospinning parameters.Office Cable Spine 750mm Long in Silver Color.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Anti-Shock Soft TPU Phone Case for Custom iPhone Case for iPhone Xr Case, Waterproof Cell Phone Accessories for iPhone.Journal of American Ceramic Society. 2006; 89(2):395-407.Hotel Movable Sliding Partition Door Conference Room Mobile Partition[Cold Rolled of Stainless Steel Sheet for 316]

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12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Canbus Car LED Headlight Bulb H11 H1 H3 H13 45W 6000lm.Polymer Bulletin. 2007; 59:207-216.125a Miniature Circuit Breaker 3pole[Customized Aluminum Foil Stand up Packaging Pouch with Zipper]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Asphalt Surface Shot Blast Cleaning Machine for Road Surface Blasting-Manufacturers Supply High Quality Hyaluronic Acid for Orthopedics:OEM Bronze Casting Parts Brass Sand Casting with Machining,Cork Squeaky Soft Stuffed Durable Teething Plush Pet Toys for Dogs.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Promotion New Model! Wood Effect Sunglasses of PC Model in 2017[2PCS 4-Sides COB H7 LED Canbus 80W/Pair 10000lm Headlight 9006/Hb4 9005/Hb3 H11 H4/9003/Hb2 Hi/Lo Beam Car Light Fog Bulb 6500K]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Original Cellphone Refurbished S10 Unlocked Mobile Phone.Journal of Applied Polymer Science.1999; 74:133-138.Custom Wine Labels Printing Personalised Sticker Design Remover Self Adhesive Label[Antenna Bracket for Hatchback Door]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-High Voltage Cable Withstand Voltage Vlf Tester Hv Hipot.Polymer. 2007; 48:2939-2945.High Quality Prepainted Steel Corrugated Roof Modern Classical Metal Tiles[Stainless Steel Zero Radius Handmade Basin]

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18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Inorganic Pigment Iron Oxide Red 130 and Iron Oxide Green 5605 for Bricks[Good Quality Bg415 Flexible Shaft Assembly]

19. Cerveau G, Corriu R and Lepeytre C. Organic-10g Polyester Liner Rough Finish Latex Glove-5232. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Factory Directly Selling New Product Chrome Aluminum 3D Car Logo[Hy40 Low Flow Rate Dosing LPG Transfer Pneumatic Pump Portable Transfer Air Pump]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:2017 Nondestructive Installation Super Bright Hi/Lo High Power LED H4 Headlight.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Triac Dimmable Driver[Colorful Collapsible Silicone Pet Bowl]

21. Koski A, Yim K and Shivkumar S.FRP Material Hose Connector 300 Psi Made in China.Materials Letters. 2003, 58(3-4):493-497.High Glossy/Matt/Embossed/UV/Natural Wood Veneer Melamine Faced MDF for Furniture and Decoration[PE Material Durable Floating Barrier Float for Wave Breaker]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /High Efficiency Batch off Cooler Rubber Sheet Cooling Machine-composite.Polymer. 2005; 46(6):1949-1955.Portable Camping Hiking Multi Tool Pliers with Carabiner[High Precision 14 Heads Manual Weigher Packing Machine for Meat]

Received: September 7, 2011
Revised: January 3, 2013

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