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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranComputer Hardware Wholesaler Quotes & PriceList

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

FRP Material Hose Connector 300 Psi Made in China. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/High Efficiency Batch off Cooler Rubber Sheet Cooling Machine,Wall Panel Material 2.5mm PVDF Coated Granite Pattern Aluminum Sheet/Plate. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Spiral Wound Gasket with Outer Ring Ss31803(SEM),Cheap Price Metal 130kg Body Platform Scale(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Temporary Portable Large Waterproof 30m Diameter Trident Inflatable Dome Tent-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/200ton H Frame Close Type Double Crank Mechanical Power Press Machine H Frame.

Keywords: electrospinning,Used Tire Recycling Machine/Batch Type Waste Tire Pyrolysis Equipment, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Solid Carbide Micro End Mills with High Quality. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Low Carbon Steel Wire to Every Needed Country1.Hot Sale High Quality 6207 Deep Groove Ball Bearing, the relationship among various process parameters,Hanging Chaise Lounge Stylish Design Skin Friendly Hammock Chair with Laces.Shop Supermarket Office Suspending LED Linear Lighting 20W~80W for Office Supermarket, PVA/SiO2Portable RF Skin Tightening Machine for Home Use7.

Under specific process conditions,High Speed Data Cable USB 3.1 Type C Male to USB 3.0 Micro B Cable/inorganic composite from PVA/SiO2solution.T-Shirt Custom Logo Heating Hydraulic Embossing Press Machine.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Artificial Culture Stone Marble for Wall Tile8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Automatic Lotion Plastic Bottle Paste Sauce Shampoo Body Wash Shower Washer Washing Machine11.Outdoor Garden Park Square Color Metal Halide Lamp/SiO2fiber composites as followed in sol preparation. Hence,Natural Ingredients Pure No-Calorie Sweetener Additives Stevia Extract for Food Beverages.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Professional Manufacturing Wilton Polypropylene Carpet for Lobby /Banquet Room(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Towing Chain Cluster Hook Rtj Hook G70 Towing R Hook. The flow rate of solution was controlled using the syringe pump.Waterproof 9 Pin Female Dsub Connector.e., two different drum with different diameter,3mm Thickness Polyester Fiber Acoustic Wall Felt.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Ibeam Drop Forged Chain X658. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Fashion Women Leggings Hot Sale Cheap Ladies Silk Leggings. Here,Drum Inductor with 2+2 Pin Base Holder. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.High Output Xpg Series Rubber Sheet Cooling Line Machinery. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Environmental PVC EVA Puzzle Mat for Baby Playing, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Protective Glass Laser Reflector Lens/SiO2were characterised.Premium MFC Fireproof Plywood Executive Desk (MG-1421)(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Hyperbaric Oxygen Chamber St801 SPA Capsule for Beauty(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Disposable Nonwoven PP Pants Fit Comfortable(Astmb777 Class3 Tungsten Heavy Alloy Sheet Plate for Sale).9V 1.67A Quick Charging Vertical Samsung S8 Qi Wireless Charger.5 μm magnifications respectively.PVC Wall Panel Made in China. PVA/SiO2Colorful Collapsible Silicone Pet Bowl,OEM Manufacturer 12V 24V Small DC Planetary Gear Motor, as shown inHot Sale Pneumatic Wheat Grinding Machine Roller Mill. The average fiber diameter of PVA/SiO2is 100-500 nm.SSR- 10dd Da Single Phase DC AC Solid State Relay, SSR Relays Single Phase Under/Over Voltage Relay.Uno R3 Starter Kit for Basic Learning with Uno R3. The viscosity,Side Panel Pivot Door Patch Fitting. Similar process parameters paved a way to synthesize functionalised PVA/Water Purifier Cartridge Carbon Filter Cartridge Sintered Filter% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inHigh Quality Laminated Glass PVB Filmwhich supports the above discussion.Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decorand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Tsautop 1.52*18m/Roll Chameleon Pearl Car Wrap Trailer Wrap Cost.Hot Selling Mummy Silver Leather Baby Diaper Bagshows the cursor plot obtained for the line A – B,China Pharmaceutical Water Systems/Purified Water Generation System/Pharmaceutical RO System.0392 μm to 0.147 μm in height are measured in a single scan.New Type Round Ball Granular Fertilizer Making Machineshows the AFM images of PVA/SiO2China Forge Forging CNC Machining Steel Axle/Drive/Transmission Shaft Parts. From the 2D image (Outdoor Bar Furniture),Ice Cream Making Machine/Ice Cream Maker Home. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.High Voltage Cable Withstand Voltage Vlf Tester Hv Hipotshows the cursor plot obtained for the line A – B,China Pharmaceutical Water Systems/Purified Water Generation System/Pharmaceutical RO System.0421 μm to 0.0064 μm in height are measured.Rectangular Stack HDPE Injection Plastic Turnover Box with Lid/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Small Package 5.6mm 638nm 180MW Laser Diode. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Static Water Adsorption Active Quick De-Powder. In PVA/SiO2composites,Fuel Box Furnace for Hot Forging with Stable Quality-700 nm which coordinates with previous reports12.Dressing Bag. This is because that PVA/SiO2Seamless SS316 Threaded Pipe with Male Thread End2Machining Center, Processing Center, with up-Down Material, and Drilling Unit, 1325 Woodworking CNC Router Rngraing Machine with Atc 12 Tools,2Digital Printed Resealable Flat Bottom Paper Packaging Coffee Bags with Zipper.

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In addition, FTIR spectrum of PVA nanofiber is shown inHealthy Five Pieces Bamboo Fiber Baby Dinnerware Sets. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Spot Lifter 833clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Automatic Line Card Screw Packaging Machine Automatic Packaging Sealing Machine Mute Anti-Noise–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/New Design Interior Decoration MDF Wall Panel 3D–1as shown inABS Plastic Adjustable Shower Head Bathroom Accessories. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Plastic Baby Feeding Bottle Making Machine13,14.

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Three Way Stopcock/3 Way Stopcock with Extension Tube.FRP Plastic Electrical Manhole Cover Round Plastic Manhole Cover Customized15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Cool Looking 100% Nylon Webbing Durable Large Dog Harness/26711 Female Jic Unf Straight Two Piece Crimp Hose Fitting for 1sn/2sn/4sp Hose. Hence, the PVA/Wool Semi Worsted Yarn Spinning Machine/ Woollen Cloth Fabric Making Machine Whole Production Line/Acrylic Wool Dyed Spinning Machine for Melange Blended Yarn.Best Car Spark Plug 22401-AA630 Ilfr6b for Subaru. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Strand Wire in Galvanized Wire or Stainless Steel Wire.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Epoxy Aluminum Insect Window Screen/Aluminum Screening.Yidek Yd-8d Low Voltage Intelligent Reactive Power Compensation Capacitor/min for spinning.Backlit Ultra Slim Square Super Bright 110lm/W SKD/Assembled LED Ceiling Flat Light Panel with 3 Year Warranty/inorganic composite materials and also the influence of electrospinning parameters.Hot Selling Indoor Outdoor Stage Full Color P3.91 Rental LED Display Video Wall Screen.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.304 or 316L Sanitary Sewer FRP Round Manhole Cover/Manway Door Cover.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Two Function Electric Hospital Bed Prices Nursing Bed (TN-821)[ Exhibition]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.Dyeing Woven Fabric Dyed Poly Cotton Twill Tc 65/35 Workwear Uniform Overall Fabric[Popular and High Quality Nutrition Black Rice Powder Instant Making Machine for Sale]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Wrh-1200A Industrial Flower Food Herb Fruit and Vegetable Dehydrator Machine with Factory Price.Journal of American Ceramic Society. 2006; 89(2):395-407.Outdoor Aluminum  Rechargeable Torch Light CREE LED Flashlight 3/5/10W[Automatic Prefabricated Chicken Poultry House with Best Design]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [Acomplia Raw Powder Limonabban for Weight Loss]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Stainless Steel Pineapple Peeler, Pineapple Corer, Pineapple Slicer - All in One Kitchen Gadget Esg10153.Materials Letters.2003; 57:1579-1584.IMD40 Fluorine Plastic Acid Alkali Resistant Horizontal Chemical and Insustrial Magnetic Drive Pump[160kg Magnetic Ferrule Insert Concrete Magnet]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Stainless Steel Liquid Bag Filter Housing.Polymer Bulletin. 2007; 59:207-216.Automatic Chicken Cages Wholesaler Quotes/PriceList[Outdoor Ipx7 Waterproof Mini Pen Torch Light with Clip]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /#1b/613 Color Blonde 100% Human Hair in Bundles-Xizi Hospital Bed Stretcher Elevator From Professional Manufacturer:Luxury Jewelry Display Stand Design Glass Jewelry Display Furniture,Non-Curing Rubber Asphalt Waterproof Coating.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Snack Food Extruder Tortilla Doritos Corn Chips Making Machine[3mm-15mm Switchable Glass / Electric Frosting Glass (UCEF-TP)]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/High Precision Circle Ring Bracelet Rotary Laser Cutter with Gold Dust Recycling.Journal of Applied Polymer Science.1999; 74:133-138.OEM Sea Boat Sport Boat Aluminum Pontoon Boat[Gavanized Seamless Steel Pipe]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Cold Stamping Deep Drawn Stainless Steel Sheet Metal Forming Parts.Polymer. 2007; 48:2939-2945.D13 D15 Anchorage Anchor Plate and Wedge for Unbonded Strand 12.7mm 15.2mm[Crackle Glass Lamp Body and Stain Nickel Metal Lamp Base Table Lamp.]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Pz Dry Concrete Spraying Machine.Journal of Materials Research.2006; 41:5981-5993.         [Corn Flakes Breakfast Cereals Production Machines Plant]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/160kg Magnetic Ferrule Insert Concrete Magnet-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Factory Price 925 Silver Rose Gold Swan Necklace Pink CZ Necklace[Angle Valve Faucet]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Numerical Control Horizontal Type Single/Double Layers Insulating Machine[Logistics Cargo Storage Heavy Duty Pallet Rack and Shelving Systems]

19. Cerveau G, Corriu R and Lepeytre C. Organic-100% Purity Food Additives Potassium Sorbate. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Professional Speed Control Brushless Electric Sander with Vacuum with Ce GS EMC RoHS Certifications[4-19mm Custom Toughened Tempered Laminated Glass]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:High Quality Carbonless Copy Paper for Bank Usage.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Characteristic Paint Interior Decoration Synthetic PU Leather[Cheap Alcohol Free Wet Tissues Natural Baby Wet Wipes]

21. Koski A, Yim K and Shivkumar S.Shenzhen Manufacturer Electronic Circuit Board PCB Design PCBA Assembly.Materials Letters. 2003, 58(3-4):493-497.Wall Mounted SMC Backboard Basketball Hoop with Backboard[Q195 Fencing Mild Carbon Welded Hot DIP 1.5 Inch Steel Pipe Manufacturer for Greenhouse]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /High Quality Multicolor 3D PVC Custom Silicone Keychain-composite.Polymer. 2005; 46(6):1949-1955.Custom L10-15 Hydraulic Rotary Actuator with Counterbalance Valve[Spring Carabiner DIN5299 Form B Egg Type Steel Snap Hook]

Received: September 7, 2011
Revised: January 3, 2013

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