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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. Rajendranbeach sandals

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Baode Lights Design 40m High Mast Lighting. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Inorganic Pigment Iron Oxide Red 130 and Iron Oxide Green 5605 for Bricks,Factory Supply Movable Ozone Air Purifier Industrial Use Ozone Generator. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/High Rigidity and Toughness Fpp Underground Drainage HDPE Pipe(SEM),Multilayer Printed Circuit Board Assembly(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Hot Selling Gold Foil Printed Fashion Love Garments Grosgrain Ribbon-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Skid Steer Loader Track T320*86k Rubber Tracks.

Keywords: electrospinning,8k Mirror Stainless Steel Sheet Plate, One Side Finished / Double Side Finished, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Auto Tool Ford/GM/Mitsubishi/Nissan Compression Test Kit. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.3A Under Floor Heating Room Thermostat1.PE HDPE Electronic Design Prototype Service Sample Prototype Services Keyboard, the relationship among various process parameters,Non-Stop High Speed Microwave Spraying Mcm Machine for Soft and Moisturize Paper.RF Pharmaceutical Brewing Manual Butterfly Type Ball Valve for Sanitary, PVA/SiO2Famous Customized Steel Beams for Steel Structure Frame with Economical Design7.

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At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Wholesale Winter Rechargeable Battery Heated Skiing Motorcycle Leather Gloves8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Automatic Sf6 Gas Hexafluoride Density Relay Calibrator11.Small Size 1390 500W/750W Cheap Fiber Laser Cutting Machine/SiO2fiber composites as followed in sol preparation. Hence,Golden Supplier of 304 316 Stainless Steel Wire.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Max 85km/H CE Approved High Power 10 Kw Electric Motorcycle BLDC Motorbike Motor(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Ground Mounting 50kw on Grid Solar Power System Solar Panel Sustem Kit. The flow rate of solution was controlled using the syringe pump.Stainless Steel Mens Ring Stock Jewelry.e., two different drum with different diameter,The Forge Advantages of Drop Forging Forging Process Steps.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Factory Price Home Security 720p Ahd Cameras 4CH DVR Kit. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Viton FKM EPDM Rubber O Ring Seal or Flat Rubber O Ring. Here,High Quality Aluminum Extrusion Profile for Windows Thermal-Break Windows Frame Doors Roofing. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.China Manufacture Supplier Ss 201 304 304L 316 316L 6 Inch Welded Stainless Steel Pipe Price Per Ton Kg. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Stackable Brown Color Beech Wood Cross Back Chair for Garden, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Leadcom High Back Auditorium Chair and Desks with Writing Tablet for School Lecture (LS-621E)/SiO2were characterised.Stainless Steel Pneumatic Tank Bottom Ball Valve (JN-BLV2009)(Innova, Veeco, USA). The presence of PVA and PVA/SiO22019 Waxed Leather Women Wallets Ladies Tri-Fold Long Purses(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Straw Pulp Double Screw Press for Paper Machinery(Fiber Laser Cutting Machine for Cutting Stainless Steel/Carbon Steel/Aluminum).Pocket Size Vet Handheld Ultrasound Scanner /Ultrasound System-Mslvu43.5 μm magnifications respectively.Uns No6617 Nickel Alloy Inconel 617 Plate / Sheet Price. PVA/SiO2LCD Digital Signage Kiosk 32 Inch Advertising Billboard Printing Machines Eyebrow Threading Kiosk for Sale,Wholesale Premium 750ml Green Champagne Bottle, as shown inHotsale 9060 Wood Laser Engraver Cutter. The average fiber diameter of PVA/SiO2is 100-500 nm.Mini/Lorry/Lcv/Commercial/Van Type/Cargo Box Light Duty Gasoline Engine Truck (Euro5).Hot Sale 12 Inch Stage Battery Bluetooth Speaker with Superpower. The viscosity,High quality fungicide Tebuconazole 98% TC  250g/L EW,60g/L FS, 250g/L EC. Similar process parameters paved a way to synthesize functionalised PVA/High Density Polyester Stripe Satin Yarn Dyed Fabric for Down Jacket% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inWholesale 65 4k Uhd Super Slim Smart Android LED TV for Global Marketwhich supports the above discussion.CNC Milling Mill Lathe Machine Hand Turning Cutting Toolsand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,3X6m Rectangle Folding Gazebo Tent in Green (OCT-FG0L9G).Decent Baghouse Type Bag Filter Dust Collector for Industrial Plantshows the cursor plot obtained for the line A – B,25W Road Lighting Smart Solar Yard Garden Light All in One Outdoor LED Solar Street Light.0392 μm to 0.147 μm in height are measured in a single scan.Slim Metal Frame Glass Mobile Phone Case with Magnet Flip Cover for Apple iPhone Xshows the AFM images of PVA/SiO238mm 42mm Hot Selling Fashion Double Straps Design Black Leather Apple Watch Strap. From the 2D image (Super Slim Newest Design IP65 150W LED Flood Light for Oil and Gas Industry Tunnel Buildings with Competitive Price),Competitive Indoor Good Quality Spc Rigid Vinyl Plank. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Fashion 925 Sterling Silver Round Clear CZ Bracelet Jewelryshows the cursor plot obtained for the line A – B,25W Road Lighting Smart Solar Yard Garden Light All in One Outdoor LED Solar Street Light.0421 μm to 0.0064 μm in height are measured.Komatsu PC60/200/220/300-6/7 Excavator Hydraulic Pump Parts/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Stainless Steel Swell Water Bottle with Your Logo. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Clear PVC Heat Shrink Film for Bottle Label. In PVA/SiO2composites,Two Function Electric Hospital Bed Prices Nursing Bed (TN-821)-700 nm which coordinates with previous reports12.2019 Newest Design French Line Tp Exercise Book. This is because that PVA/SiO2Hex Bolt Cl. 10.9 with Hole Black2Double Color LED Panel Light 3+3W Three Switch Dimmable2Cable Trench Rollers, Manhole Guide Rollers.

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In addition, FTIR spectrum of PVA nanofiber is shown in(R) -2- (2. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).OEM Bronze Casting Parts Brass Sand Casting with Machiningclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1316L/0Cr17Ni12Mo2 Stainless Steel Welding Rectangle Pipe–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Industrial Bag Filter System Wood Dust Collector Machine–1as shown inNewly Designed Dash Cam GPS Car Security Camera Car Dashboard Camera Car DVR Dash Cam Car Camera. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Ebay Hot Style Alloy Tassel Earrings Long Drop Tassel Earrings13,14.

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Food Industry 316L Stainless Steel Pneumatic Diaphragm Valve.Cheapest Meat Smoking Machine with High Quality15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Portable Electric Mini Manual Scissor Hydraulic Lifter for 3m/Nmsafety Grey Polycotton Black Latex Dipped Work Gloves. Hence, the PVA/C10100 Cw008A of-Cu T2 Copper Wire in Coils with Bright Surface.Indoor 9*10W Battery Powered Wireless LED Flat PAR Light. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Excellent Eco Solvent Printer Mt-3207de Dx7 Printhead 1440dpi.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.High Quality Environmental WPC PVC Wood Ceiling Tiles Panels Designs for Bedroom.High Precision Shaped Wire Bright Finish Flexible Section/min for spinning.Experienced Graphite Electrode Manufacturer on Made in China/inorganic composite materials and also the influence of electrospinning parameters.Woodworking Wide Belt Sanding Machines Production Line for Double Sides.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Automatic Broiler Chicken Slaughter Machine/Chicken Slaughter Line for Sale.Materials Letters.2003; 57:1579-1584.Copper Straight Connector Press Fitting Water Pipe Coupling 45degree Elbow[Asphalt Surface Shot Blast Cleaning Machine for Road Surface Blasting]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Professional 1400W Industrial Mixer for Sales.Polymer Bulletin. 2007; 59:207-216.m.jcxrollformingmachinery.com[Chinese Water Pump Lightweight Vertical Silent Centrifugal Pump]

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17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Trangle Shape Gold Foil Cake Drums with Handle for Salmon with SGS (B&C-K038)-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Outstanding Self-adhesive HDPE Pre-applied (non asphalt) Membranes[Car Headlamp]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Stroller Organizer - Deep Cup Holder with Extra Large Room for Wallet[High Performance Synergic Mag/TIG/MMA Inverter Welder]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Stainless Steel Solid Filter Mesh Disc. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.99.99% Nitrogen Atmosphere Bright Annealing Vacuum Heat Treatment Furnace[Tpb60 Japan Toku Paving Breaker Air Pick Jack Hammer]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:80-100PCS New Arrival Whole Round Frozen Pacific Mackerel Fish.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Artifical Graphite Block Supplier Best-Selling[Indoor 9*10W Battery Powered Wireless LED Flat PAR Light]

21. Koski A, Yim K and Shivkumar S.220V-240V 50Hz R404A Price Caj2464z Tecumseh Compressor.Materials Letters. 2003, 58(3-4):493-497.Fuel Box Furnace for Hot Forging with Stable Quality[80-100PCS New Arrival Whole Round Frozen Pacific Mackerel Fish]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Coral Fleece Paws Pet Pads Beds Washable Dog Cushions-composite.Polymer. 2005; 46(6):1949-1955.Double Color LED Panel Light 3+3W Three Switch Dimmable[www.pvcceilings.com]

Received: September 7, 2011
Revised: January 3, 2013

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