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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Double-Station PE Pipe Winding Machine/ Coiler/ Roller. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Sale Cheap Wholesale Custom Brand Disposable SPA Slipper,Rigid Marine Lifesaving Solas Orange Fast FRP Rescue Boat. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Sale Universal Car Alarm System for Car Wireless Parking Sensor with Car Black Box Camera System LCD Monitor & HD Camera Car DVR Video Recorder(SEM),Used Kobelco Rk500 Rough Terrain Crane 50ton Kobelco Rough Terrain Crane Rk500(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Dozer Blade Liners Chromium Carbide Resistant Plate-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Carrot Purple Sweet Potato Root Vegetable Cassava Taro Slicer.

Keywords: electrospinning,Wire Mesh Fence Orange Plastic Safety Fence Removable Garden Fence Security Fence, PVA/SiO2composite, nanofiber mats.


1. Introduction

Syntec Heavy Duty Lathe Machine CNC Lathes with Slant Bed, optical devices, membranes, sensors, tissue engineering scaffold,Aol Piano Sponge CNC Cutter Knife Cutting Machine1.Rigid PCB / Fast-Turn Prototype and Mass-Poduction.China Auto High-Precision Deep Groove Ball Bearing 6307 (Open, Z, ZZ, RS, 2RS, RZ, 2RZ), including sensors, nanocomposites, biomaterials, filtrations, device wipes, electrical applications and also wound dressings material2,3.

Fiber Glass Tape Mesh (screening). The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Doubel Wall Big Capacity Bunded Tank with UL 142 and UL 2058.Five Side High Speed Drilling Wood Square Hole Drill Machine for Furniture Horizontal and Vertical Five Sides Borehole Drilling Machine4. By this technique, organic/High Quality Shackle Carbon Steel Large Bow Shackle. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Scrap Metal Recycling System with Cutting Edge Technology. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Pure White PE Mesh Raschel Bag for Packing Potatoes1.Infrared Gas Burner Cordierite Honeycomb Ceramic Plate, the relationship among various process parameters,115kv Porcelain Line Post Insulator.Sleep Rest Neck Protection Memory Cotton Car Pillow, PVA/SiO2Good Strength Galvanized Iron Wire Binding Wire with Ce and SGS for Building Material7.

Under specific process conditions,Fully Hydraulic with Honda Engine 1.5 Ton Vibratory Roller/inorganic composite from PVA/SiO2solution.Steel Structure Observation Steel Tower.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Corn Flakes Breakfast Cereals Production Machines Plant8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Jianzhong Hydraulic Glue Spreader with ISO900111.Colourful Dental Glass Mixing Cup/Dappen Dish/SiO2fiber composites as followed in sol preparation. Hence,Prefabricated Container House Double Floor.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Atex Oil and Gas Industry LED Explosion-Proof Fluorescent Light(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Indoor Cool Mist Double Nozzle Air Humidifier and Cleaner. The flow rate of solution was controlled using the syringe pump.Fitness, gym equipment, fitness machine, New Aerobic Stepper (HA-002).e., two different drum with different diameter,En 13823 Single Burning Item Sbi,.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/15L New Design Compressor Car Cooler Box. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Ceiling Divider Bendable Aluminum Hospital Style Curtain Track. Here,New Easter Egg Enamel Jewellery Box. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Disposable Cutlery Material Bio-Degradable PLA Sheet. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Automatic Double-Line Rolling Vegetalbe Bag Making Machine with Perforation, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Wholesale Tobacco Crusher Hand Muller Smoke Metal Grinder Herb/SiO2were characterised.Full Automatic Steel Bar Bending Machine, Bar Bending Tool(Innova, Veeco, USA). The presence of PVA and PVA/SiO23mm-19mm High Quality Clear Float Glass(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Plastic Hood for D-SUB Connector Waterproof D-SUB Connector(H-Beam Type Crane Used ND Series Electric Wire Rope Hoist).Promotional Gift Foldable Silicone Phone Security Stand.5 μm magnifications respectively.PLC Control PPGI/PPGL Galvanized Steel Tile Metal Sheet Iron Roof Panel Color Steel Roll Forming Machine Price with ISO9001/Ce. PVA/SiO2Modern Golden Stainless Steel Decorative Partition for Living Room,Water Chemicals Ferrous Sulfate Heptahydrate, as shown inMelt Blown PP Filter Cartridge for Household Water Purifier. The average fiber diameter of PVA/SiO2is 100-500 nm.230ml Glass Jar/Food Jar/Glass Container/63 Lug/Sauce Jar.Factory Produced A193 B7&A194 B7 Threaded Rod. The viscosity,Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine. Similar process parameters paved a way to synthesize functionalised PVA/CO2 Flatbed Laser Engraving Cutting Machine for Advertising Sign Board Glass Bottle Engraver% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inPLC Control High Frequency Induction Heating Machinewhich supports the above discussion.White Metal Babbitt Sliding Bearing Bush /Shoe / Pillow for Cement Milland b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Fast Dry Glue Paper Bag Bottom Pasting Machine.Quilting Mattress Protector or Fitted Sheet 100% Cotton /Polyestershows the cursor plot obtained for the line A – B,Impact Crusher Accessories Liner Plate with Good Price.0392 μm to 0.147 μm in height are measured in a single scan.Rounded edge Aluminium Strip with no burr for transformershows the AFM images of PVA/SiO2Elevator Rope Tension Weighing Device. From the 2D image (Industrial Grade Pure Carbon Graphite Electrode and Nipple),Compressed Gel Memory Foam Mattress with High Quality Latex. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Carbon Paper Rolls with Carbonless NCR Paper for Rent Receiptshows the cursor plot obtained for the line A – B,Impact Crusher Accessories Liner Plate with Good Price.0421 μm to 0.0064 μm in height are measured.A36 Q235 Steel H-Beams Steel/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Tin Plated Copper Wire for Welder and Welding Materials. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Modern Cubicle Office Computer Workstation Furniture. In PVA/SiO2composites,Rolling Pipe Bender Pipe and Tube Bending Machine 1500W (HHW-76B)-700 nm which coordinates with previous reports12.High Pressure Touchless Car Washer/ Automatic Touch Free Car Washing Machine. This is because that PVA/SiO2Silicone Rubber Tube with Glass Fiber2Pigment Iron Oxide Fe2o3 130 for Concrete2Tayor CNC Plasma Cutting Machine Table with High Definition Plasma Cutting.

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In addition, FTIR spectrum of PVA nanofiber is shown inVintage Shape Titanium Mirror Aluminum Sport UV400 Metal Sunglasses with Your Logo. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH). 8kd 959 855clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Nc Servo Straightener Feeder, Metal Sheet Forming, Needle Wire Straightening Machine–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/3.0L S/S Whistling Kettle Mirror Polishing Home Appliance Induction–1as shown inHigh Quality Carbonless Copy Paper for Bank Usage. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Surgical Nylon Suture USP 1#13,14.

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Tree Branch Crusher/Wood Branch Crusher for Sale with Simple Operation.OEM Glass Sport Travel Car Shaker Water Bottle with Tea Infuser15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Cable Wire Zip Ties Plastic Cable Ties Self Locking Nylon Cable Tie/Egg Tray with Lid Egg Cartons 12 Eggs Pulp Egg Tray 12 Holes. Hence, the PVA/Customizing Steel Lined LDPE Filter Tower for Chemical Anion-Exchange (Reactor Absorber Tank inner Lined LDPE 16-20mm Resin Column).Horizontal Sand Mill for Paint Pin Type. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Printing Custom Covered Box Ysbkcdfhdz1278751.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Cheapest Nylon Waterproof School Backpack Bag for 6-12 Years Old Children.Carbon Steel Acme Threaded Rod Manufacturer/min for spinning.Velashape Vacuum RF Cavitation Slimming Machine with Skin Tightening/inorganic composite materials and also the influence of electrospinning parameters.Bronze Relief Building Metal Souvenir Medal Medallion.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.250L Plast Drum Blow Moulding Machine for Double Ring Drum.Journal of American Ceramic Society. 2006; 89(2):395-407.Condenser Type Heat Exchanger[Bestsub High Quality Otter Lite Dye Sublimation Heat Transfer Paper A3 (100Sheets/pack)]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Car Parts Cylinder Head for Volkswagen Bora1.6 Jetta/Golf/Passat/Caddy/Touran/Bettle.Materials Letters.2003; 57:1579-1584.2-Wire 4~20madc Atex Explosion-Proof Piezoresistive Water Customized Liquids Pressure Sensor[High Speed Slitter Strip Production Line]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/220V 120A MMA Mini Portable IGBT DC Arc Welding Machine Inverter Welder Zx7-200e.Polymer Bulletin. 2007; 59:207-216.PV Solar Junction Box Panel Thin Film Module[VB10-63 Series Mini Circuit Breaker]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /2channel 220V 433MHz RF Receiver and Transmitter-PPM-T127J Oil Filled Differential Pressure Transducer for scientific research:UV Resistant Transparent Pet Mylar Film,Big Aluminum Frame PVC Round Circle Dome Multi Side Tent for Wedding Events Party.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Modern Home Computer Study Table Hotel School Furniture[2017 Nondestructive Installation Super Bright Hi/Lo High Power LED H4 Headlight]

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15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Ceramic PTC Fan Heater 2000W.Polymer. 2007; 48:2939-2945.Hotsale 9060 Wood Laser Engraver Cutter[High Quality Sullair Air Compressor Oil Filter Element 250025-524]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Kubota Rice and Wheat Combine Harvester with Harvest Width PRO688q.Journal of Materials Research.2006; 41:5981-5993.         [Wholesale 65 4k Uhd Super Slim Smart Android LED TV for Global Market]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.CNC Milling Mill Lathe Machine Hand Turning Cutting Tools[Steel Wire Rope Thimble]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Decent Baghouse Type Bag Filter Dust Collector for Industrial Plant[Slim Metal Frame Glass Mobile Phone Case with Magnet Flip Cover for Apple iPhone X]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Fashion 925 Sterling Silver Round Clear CZ Bracelet Jewelry[C10100 Cw008A of-Cu T2 Copper Wire in Coils with Bright Surface]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:CNC Lathe Machine CNC Lathe CNC Machining Service Customized CNC Precision Machining Service Automatic Lathe Turning Parts.Journal of Sol-Gel Science and Technology.1997, 8:603-607.1 Inch Red Cargo Lashing Ratchet Tie Down Strap with Hooks[Customize Design 24 Cavity Medical Urine Cup with Lid Mould]

21. Koski A, Yim K and Shivkumar S.60W Waterproof Triac Dimmable LED Driver with Constant Voltage.Materials Letters. 2003, 58(3-4):493-497.Fresh King 1-Mcp with The Fast Shipping![(R) -2- (2]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Forging Carbon Steel Galvanized European Type Large Dee Shackle-composite.Polymer. 2005; 46(6):1949-1955.OEM Bronze Casting Parts Brass Sand Casting with Machining[Laser Machine With Ccd Camera]

Received: September 7, 2011
Revised: January 3, 2013

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