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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Artificial Culture Stone Marble for Wall Tile. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Automatic Lotion Plastic Bottle Paste Sauce Shampoo Body Wash Shower Washer Washing Machine,Outdoor Garden Park Square Color Metal Halide Lamp. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Natural Ingredients Pure No-Calorie Sweetener Additives Stevia Extract for Food Beverages(SEM),CNC Machining Green Sand Foundry OEM Grey Iron Casting(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Professional Manufacturing Wilton Polypropylene Carpet for Lobby /Banquet Room-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Towing Chain Cluster Hook Rtj Hook G70 Towing R Hook.

Keywords: electrospinning,Waterproof 9 Pin Female Dsub Connector, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Hyperbaric Oxygen Chamber St801 SPA Capsule for Beauty. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Hot Selling Nickel Alloy Inconel 600 Nickle Strip1.Quality Powder Coating Die Casting- Aluminum Alloy Casting for LED Street Light Housing, the relationship among various process parameters,Anthelmintic and Antiparasitic Drugs Moxidectin CAS No: 113507-06-5.UL 2468 Ribbon Wire Cable Stranded cUL 2pin, PVA/SiO2High Quality Laminated Glass PVB Film7.

Under specific process conditions,Electrical Distribution Control Panel Wall Mounted Electrical Metal Enclosure/inorganic composite from PVA/SiO2solution.Silky Soft Bamboo Fabric Luxury Bed Sheets.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Shallow Half Gastronorm Aluminum Foil Container Making Machine8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Stainless Steel Embossed Sheet (4)11.Kitchen Untensils Kitchen Tool 33cm 2 Side Sharp Dumpling Wrapper Wood Rolling Pin/SiO2fiber composites as followed in sol preparation. Hence,Hot Electronic Dry Herb Vaporizer Pen Device Vax Mini Vape Kit.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Disposable Nonwoven PP Pants Fit Comfortable(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.9V 1.67A Quick Charging Vertical Samsung S8 Qi Wireless Charger. The flow rate of solution was controlled using the syringe pump.PVC Wall Panel Made in China.e., two different drum with different diameter,Colorful Collapsible Silicone Pet Bowl.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/OEM Manufacturer 12V 24V Small DC Planetary Gear Motor. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,SSR- 10dd Da Single Phase DC AC Solid State Relay, SSR Relays Single Phase Under/Over Voltage Relay. Here,Uno R3 Starter Kit for Basic Learning with Uno R3. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Side Panel Pivot Door Patch Fitting. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Water Purifier Cartridge Carbon Filter Cartridge Sintered Filter, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Tsautop 1.52*18m/Roll Chameleon Pearl Car Wrap Trailer Wrap Cost/SiO2were characterised.China Pharmaceutical Water Systems/Purified Water Generation System/Pharmaceutical RO System(Innova, Veeco, USA). The presence of PVA and PVA/SiO2China Forge Forging CNC Machining Steel Axle/Drive/Transmission Shaft Parts(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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Three Way Stopcock/3 Way Stopcock with Extension Tube(9mm Diamond/Snake Top Polishing Conveyor Belt for Stone/Ceramics/Granite Industry).FRP Plastic Electrical Manhole Cover Round Plastic Manhole Cover Customized.5 μm magnifications respectively.Cool Looking 100% Nylon Webbing Durable Large Dog Harness. PVA/SiO226711 Female Jic Unf Straight Two Piece Crimp Hose Fitting for 1sn/2sn/4sp Hose,Wool Semi Worsted Yarn Spinning Machine/ Woollen Cloth Fabric Making Machine Whole Production Line/Acrylic Wool Dyed Spinning Machine for Melange Blended Yarn, as shown inCustomized Shape Cosmetics PVC Blister. The average fiber diameter of PVA/SiO2is 100-500 nm.Best Car Spark Plug 22401-AA630 Ilfr6b for Subaru.Strand Wire in Galvanized Wire or Stainless Steel Wire. The viscosity,Epoxy Aluminum Insect Window Screen/Aluminum Screening. Similar process parameters paved a way to synthesize functionalised PVA/Yidek Yd-8d Low Voltage Intelligent Reactive Power Compensation Capacitor% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inStackable Brown Color Beech Wood Cross Back Chair for Gardenwhich supports the above discussion.Customized colorful cute animal wholesale promotional funny stuffed graduation owl plush toyand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Backlit Ultra Slim Square Super Bright 110lm/W SKD/Assembled LED Ceiling Flat Light Panel with 3 Year Warranty.Forged Lashing D Ring with Bolt and Bracketshows the cursor plot obtained for the line A – B,Hot Selling Indoor Outdoor Stage Full Color P3.91 Rental LED Display Video Wall Screen.0392 μm to 0.147 μm in height are measured in a single scan.Outdoor LED Street Light Housing with High Powershows the AFM images of PVA/SiO2Mobile Phone Laser Engraving Machine Desktop Fiber Laser Marking Machine. From the 2D image (Male Waterproof Silicone Multi-Speed Masturbator Cup Realistic Pussy Vibrating Vaginal with Strong Suction Cup Foot Sex Toys for Female),304 or 316L Sanitary Sewer FRP Round Manhole Cover/Manway Door Cover. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.At600va 360W High Quality LED Line Interactive UPS with Smart Functionsshows the cursor plot obtained for the line A – B,Hot Selling Indoor Outdoor Stage Full Color P3.91 Rental LED Display Video Wall Screen.0421 μm to 0.0064 μm in height are measured.Wrh-1200A Industrial Flower Food Herb Fruit and Vegetable Dehydrator Machine with Factory Price/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Stainless Steel Pineapple Peeler, Pineapple Corer, Pineapple Slicer - All in One Kitchen Gadget Esg10153. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Stainless Steel Liquid Bag Filter Housing. In PVA/SiO2composites,#1b/613 Color Blonde 100% Human Hair in Bundles-700 nm which coordinates with previous reports12.Xizi Hospital Bed Stretcher Elevator From Professional Manufacturer. This is because that PVA/SiO2Luxury Jewelry Display Stand Design Glass Jewelry Display Furniture2Non-Curing Rubber Asphalt Waterproof Coating2High Precision Circle Ring Bracelet Rotary Laser Cutter with Gold Dust Recycling.

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In addition, FTIR spectrum of PVA nanofiber is shown inDtp Custom Rechargeable 36V 20ah Li-ion Battery Pack for Electric Ebike. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Automatic Electric Frozen Lamb Beef Chicken Deli Meat Slicer Cutterclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Cold Stamping Deep Drawn Stainless Steel Sheet Metal Forming Parts–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Pz Dry Concrete Spraying Machine–1as shown in60W CO2 Laser Marking Machine Lx-2000b Apply to Wood Products. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1160kg Magnetic Ferrule Insert Concrete Magnet13,14.

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100% Purity Food Additives Potassium Sorbate.High Quality Carbonless Copy Paper for Bank Usage15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Shenzhen Manufacturer Electronic Circuit Board PCB Design PCBA Assembly/High Quality Multicolor 3D PVC Custom Silicone Keychain. Hence, the PVA/Silicone Makeup Puff Silicone Blender.Baby Products Pocket Paper Tissue Packing Line Production Machine. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/4.3 Inch Touch LCD Display Module Naked Industrial Tablet Module.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.China High Quality Stainless Steel Plate (2205 2507).Custom OEM Professional Plastic Injection Moulding for Motorcycle Parts/min for spinning.Concertina Razor Barbed Wire Made in China with High Quality/inorganic composite materials and also the influence of electrospinning parameters.Kh1490 Laser Engraving Cutting Machine CO2 Laser Engraving Cutter.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Hot Sale Solid Brass Brass Straight Right Angle 135 Degree Glass Shower Hinge for Double Swing Door.Chinese Science Bulletin.2008; 53:2265-2286.Original Cellphone Refurbished S10 Unlocked Mobile Phone[High Quality Auto Car Parts Semi Metal Disc Brake Shoes for Nissan K1197]

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6. Supaphol P and Chuangchote S. On: The electrospinning of poly (vinyl alcohol) nanofiber mats: a revisit. Journal of Applied Polymer Science. 2008; 108(2):969-978.Extension Hook Steel Small Motorcycle clutch Stainless Steel Tension Spring[Zipper Chain Machines]

7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Adjustable Steel Custom Folding Wholesale Aluminum Frame T Slot Angle 90 Degree Corner OEM Machinery Furniture Supporting Folding Shelf Bracket.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Good Quality Steel Hot Rolling Mill Wire Rod Automatic Vertical Mill From China Manufacture[Cable Trench Rollers]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.EU Oil Seal/Un Oil Seal[Custom OEM Carbon Steel Metal Stamping Wall Mounting Bracket]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Selling All Over The World! Hbxg Ty165-3 165HP Crawler Bulldozer.Journal of American Ceramic Society. 2006; 89(2):395-407.Self Balancing Two Wheel 250W Folding E Scooter[Small Package 5.6mm 638nm 180MW Laser Diode]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Nickel Alloy Monel K500 (UNS N05500).Materials Letters.2003; 57:1579-1584.Customized Logo Cooler Ice Box Chilly Bin[High Quality Aluminum Extrusion Profile for Windows Thermal-Break Windows Frame Doors Roofing]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/Hot Sale Unisex Outdoor Water-Resistant Winter Thinsulate Ski Cycling Gloves.Polymer Bulletin. 2007; 59:207-216.www.anebonmetal.com[Silent Diesel Generator 40kVA 60kVA 80kVA 100kVA with 24hours Fuel Tank for Telecom Application]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /16mn Alloy Steel Pipe-Dual Monitors Mst 12-in-1 USB Type-C Docking Station with Pd Charging:250kd PP Filler Cable Yarn,8011/1235/8079 Aluminum Foil in Jumbo Roll for Air Conditioner.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.2019 Jomo Lite 60 Vape Kit 1600mAh Electronic Cigarette[Hot Selling TM03 Gym Fitness Machines Club Equipments Seated Leg Press]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/CNC Alumium Profile Steel Channel Letter Auto Bending Machine.Journal of Applied Polymer Science.1999; 74:133-138.Soft PVC Super Clear Film for Window Usage[China Compact Aluminum/Chromium Thermal Evaporation PVD Coating Machine]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Smart Waterproof Tablet Case for iPad PRO 10.5.Polymer. 2007; 48:2939-2945.Wrh-1200A Industrial Flower Food Herb Fruit and Vegetable Dehydrator Machine with Factory Price[Heavy Duty Warehouse Storage Metal Pallet Stacking Rack]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/48V 5kw High Power Brushless BLDC Motor for Electric Motorcycle.Journal of Materials Research.2006; 41:5981-5993.         [1050 2011 2014 2024 2017 3003 Anodized Door Window Aluminum Sheet]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Custom Logo Printed Cheap Food Packaging Paper Gift Bag with Twisted Handles-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.2019 Home Decor Modern Nordic Style Iron Pendant Lamp for Home Lighting[Electric Bike Kit With Tube Battery]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Environmental PVC EVA Puzzle Mat for Baby Playing[OEM Car Magnet Magnetic Ring Hybrid Shell Hard PC Cover TPU Soft Bumper Phone Case for iPhone 5 6 7 8 X Xr Xs Max Plus for Apple]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Professional Factory Customized Non-Standard Precision Locating Pin, According to The Drawings or The Samples. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Prime Quality Chromated Galvanized Steel for Roofing Material[Small Size 1390 500W/750W Cheap Fiber Laser Cutting Machine]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Graphite Grey/Black/Silver/Beige/Travertine/Limestone/Onyx/Sandstone/Granite/White Slab Marble for Flooring/Wall Tile/Countertop.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Faucet Accessory - Superior Quality - Contemporary Stainless Steel Others - Finish - Electroplated[China Factory Customized Silicone Rubber Oven Table Placedmat for Kitchenware]

21. Koski A, Yim K and Shivkumar S.Nestable Heavy Duty HDPE Large Double Deck Plastic Storage Pallet.Materials Letters. 2003, 58(3-4):493-497.Hanging Chaise Lounge Stylish Design Skin Friendly Hammock Chair with Laces[Industrial Plastic Air Source Lockout]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Flexible PVC Rubber Air Natural LPG Gas Cooker Hose with High Pressure-composite.Polymer. 2005; 46(6):1949-1955.Black Color Self Adhesive PVC Cutting Vinyl[Cow]

Received: September 7, 2011
Revised: January 3, 2013

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