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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranChinese Factory High Speed Plastic Mixer

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Disposable Cutlery Material Bio-Degradable PLA Sheet. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Automatic Double-Line Rolling Vegetalbe Bag Making Machine with Perforation,Wholesale Tobacco Crusher Hand Muller Smoke Metal Grinder Herb. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Full Automatic Steel Bar Bending Machine, Bar Bending Tool(SEM),3mm-19mm High Quality Clear Float Glass(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,2000W off Grid Solar Power Inverter with USB Charger-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Welldone Air Filter Cartridge for Polishing Dust Collector.

Keywords: electrospinning,Best Price 2 Ball Valve 110mm Handle Directional Valve PVC Ball Valve, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Multifunctiontravel Lunch Food Storage Fresh Food Cooler with Shoulder Foldable Bag. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Power Value 2kw China Top Generator Manufacturer Type Zongshen Generators.Hot Rolling Mill Used for Rebar Rolling4. By this technique, organic/Newest Fashion Necklaces Jewelry Accessories 18K Gold &Silver 100 Languages I Love You Custom Women Necklace. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-OEM Parts ADC2 Aluminum Casting Die Casting Marine Parts. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Plastic Hood for D-SUB Connector Waterproof D-SUB Connector1.Promotional Gift Foldable Silicone Phone Security Stand, the relationship among various process parameters,PLC Control PPGI/PPGL Galvanized Steel Tile Metal Sheet Iron Roof Panel Color Steel Roll Forming Machine Price with ISO9001/Ce.Modern Golden Stainless Steel Decorative Partition for Living Room, PVA/SiO2Water Chemicals Ferrous Sulfate Heptahydrate7.

Under specific process conditions,230ml Glass Jar/Food Jar/Glass Container/63 Lug/Sauce Jar/inorganic composite from PVA/SiO2solution.Factory Produced A193 B7&A194 B7 Threaded Rod.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,CO2 Flatbed Laser Engraving Cutting Machine for Advertising Sign Board Glass Bottle Engraver11.Fast Dry Glue Paper Bag Bottom Pasting Machine/SiO2fiber composites as followed in sol preparation. Hence,Impact Crusher Accessories Liner Plate with Good Price.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Compressed Gel Memory Foam Mattress with High Quality Latex(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.A36 Q235 Steel H-Beams Steel. The flow rate of solution was controlled using the syringe pump.Tin Plated Copper Wire for Welder and Welding Materials.e., two different drum with different diameter,Modern Cubicle Office Computer Workstation Furniture.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/Rolling Pipe Bender Pipe and Tube Bending Machine 1500W (HHW-76B). Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,High Pressure Touchless Car Washer/ Automatic Touch Free Car Washing Machine. Here,Silicone Rubber Tube with Glass Fiber. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Pigment Iron Oxide Fe2o3 130 for Concrete. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Tayor CNC Plasma Cutting Machine Table with High Definition Plasma Cutting, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

Nc Servo Straightener Feeder, Metal Sheet Forming, Needle Wire Straightening Machine/SiO2were characterised.3.0L S/S Whistling Kettle Mirror Polishing Home Appliance Induction(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Surgical Nylon Suture USP 1#(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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AFM image of electrospun PVA non – woven mat is shown inBest Quality OEM Service Over Molded Plastic Injection Molding Partswhich supports the above discussion.4000L/H Reverse Osmosis Drinking Water Treatment Filter Purification Plant Machine for Mineral Water Bottling Lineand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Ceramic PTC Fan Heater 2000W.Zirconia Full Ceramic Bearing 6200 6201 6202 6203 6204 6205 6206 6207 6208shows the cursor plot obtained for the line A – B,Kubota Rice and Wheat Combine Harvester with Harvest Width PRO688q.0392 μm to 0.147 μm in height are measured in a single scan.60W Waterproof Triac Dimmable LED Driver with Constant Voltageshows the AFM images of PVA/SiO2Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc. From the 2D image (Electronic Cigarette Hi Pod Vapor Pen Starter Kit China Electric Cigarette),Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Beautiful House Clock Wall Clock Digital Pointershows the cursor plot obtained for the line A – B,Kubota Rice and Wheat Combine Harvester with Harvest Width PRO688q.0421 μm to 0.0064 μm in height are measured.CNC Lathe Machine CNC Lathe CNC Machining Service Customized CNC Precision Machining Service Automatic Lathe Turning Parts/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.60W Waterproof Triac Dimmable LED Driver with Constant Voltage. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Forging Carbon Steel Galvanized European Type Large Dee Shackle. In PVA/SiO2composites,Nmsafety Cut and Impact Resistant Hand Work Protection Glove-700 nm which coordinates with previous reports12.Beauty Makeup Sponge Blender Powder Cosmetic Sponge. This is because that PVA/SiO2High Speed Eco Friendly Degradable Corn Starch HDPE LDPE Biodegradable Trash Coreless Rolling Garbage Flat Plastic Bag Making Machine2Ball Shape Bio Organic Fertilizer Equipment2American Modern Divani Casa Velvet Fabric Luxury Sofa.

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In addition, FTIR spectrum of PVA nanofiber is shown inIndustrial Carrier Polyethylene HDPE Plastic Conveyor Roller. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Autumn and Winter Women Knitted Scarf Fringed Twill Shawl Lady Scarf Men Scarfclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Custom Printing Offset Paper Softcover Notebook–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Blue or Black Image NCR Paper Carbonless CF/CFB/CB–1as shown inRutile Grade of Titanium Dioxide TiO2 for Printing Ink. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor13,14.

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4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs.Permanent Magnetic Rare Earth Neodymium Cylinder Magnets/min for spinning.Custom Aluminium Cast Heating Plate with Long Lifetime/inorganic composite materials and also the influence of electrospinning parameters.High Quality High Efficiency Paper Slitting Machine.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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2. Huang L, Nagapudi K, Apkarian RP and Chaikaf EI. Engineered collagan-PEO nanofinbers and fabrics.Journal of Biomaterials Science Polymer. 2001; E1.2:979-993.         [AC 3 Phase 0.55kw Vibrating Screen Motor with NSK Bearing (YZUL30-4)]

3. Jian F, Hai Tao, Tong NL and Yun-Gai W.Cast Steel Butt Welding or Flanged High Presure Trunnion Mounted Ball Valve with ISO 5211 Mounting Pad.Chinese Science Bulletin.2008; 53:2265-2286.Wire Braided Oil Hydraulic Hose SAE 100r2at 1/4 3/8 5/8 3/4 1[176mm Bio Biodegradable Lady Pad Panty Liner]

4. Teo WE and Ramakrishna S. A review on electrospinning design and nanofibre assemblies.Nanotechnology.2006; 17:R89-106. PMid:19661572.Wedge Wire Panel / Wire Wrapped Sceen Plate[Dumbwaiter Complete Elevator for Kitchen Passing]

5. Levine M, Ikka G and Weiss P. Relation of the critical surface tension of polymers to adhesion.Journal of Polymer Science Part B: Polymer Physics. 1964; 2(9):915-919.Scented Essential Oil Massage Candle Sexy Treatment Candle in Ceramic Jar[Welldone Air Filter Cartridge for Polishing Dust Collector]

6. Supaphol P and Chuangchote S. On: The electrospinning of poly (vinyl alcohol) nanofiber mats: a revisit. Journal of Applied Polymer Science. 2008; 108(2):969-978.Industrial Screen LED 4K HDMI VGA Windows 7 Touch Screen Kiosk[Hard Anodizing for Auto Parts with High-Strong 7075 Aluminum Alloy]

7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.200kw Solid Waste Managment Syetem Biomass Plant/Power Plant.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Custom Promotional Recycle Cotton Drawstring Bag[Fast Dry Glue Paper Bag Bottom Pasting Machine]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.4643558h Excavator Engine Parts Silicon Rubber Hose Air Cooling Pipe for Zx200-3[China Manufacturer Black Vinyl Electric Sweeper Seat]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.PP-R Anti-Bacterial Pipe Drink Water Pipe.Journal of American Ceramic Society. 2006; 89(2):395-407.Camp Folding Bed[Factory Price Automatic Hard Soft Biscuit Production Line Cookie Making Machine]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [140cm Asian Female Lifesize Silicone TPE Adult Mini Sex Doll for Men Sex Masturbation (Mini)]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /Titan 40 Tons Cement Bulk Carriers for Sale.Materials Letters.2003; 57:1579-1584.Pch Ring Hammer Crusher for Crushing Sand and Stone/Aggregate/Coal/Copper/Gold/Limestone Crushing/Power Plant[Skid Steer Loader Track T320*86k Rubber Tracks]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication.Polymer Bulletin. 2007; 59:207-216.Molybdenum Alloy Strip Foil[Wuxi Ljdg1200/630 Elbow Cross Tee Making Welding Machine for PP PE PVDF UPVC Pipes]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask-Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller:HDPE Self-Adhesive Waterproof Membrane Designed for Underground,G-11 Epoxy Glass Laminates.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Hot Sale Unisex Outdoor Water-Resistant Winter Thinsulate Ski Cycling Gloves[Drum Inductor with 2+2 Pin Base Holder]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/2inch 2 FZ Single Crystal Silicon Wafer.Journal of Applied Polymer Science.1999; 74:133-138.Natural Ingredients Pure No-Calorie Sweetener Additives Stevia Extract for Food Beverages[Fan 60x60 12v]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Cryolipolysis Lipo Laser Cavitation RF Slimming Machine.Polymer. 2007; 48:2939-2945.26711 Female Jic Unf Straight Two Piece Crimp Hose Fitting for 1sn/2sn/4sp Hose[Industry Grade 316 Stainless Steel ASTM A213 Tp316 Tp316L 316L Seamless Pipe]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Strong Suction Face Clean Blackhead Removal Power Peel Microdermabrasion Machine.Journal of Materials Research.2006; 41:5981-5993.         [Continuous Benji Tyre Pyrolysis Oil Plant]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/200m Borehole Drilling Machine for Sale (HFW200A)-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.13-18 Cubic Meter Waste Garbage Compactor Truck for Sale[25 Mm Spiral Wrapping Band]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Dressing Bag[2.5mm Sheet Metal Press Brake Machine 125ton Plate Bending Machine]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Factory High Quality Outdoor Energy-Saving Night Light Lead-Acid Glue Battery Lamp Courtyard[Best Price 2 Ball Valve 110mm Handle Directional Valve PVC Ball Valve]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover.Journal of Sol-Gel Science and Technology.1997, 8:603-607.www.cablecreation.com[Customized Rubber Gasket Rubber Grommet in NBR SBR Silicone etc.]

21. Koski A, Yim K and Shivkumar S.Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture.Materials Letters. 2003, 58(3-4):493-497.Wholesale Flying CO2 High Speed Online Laser Marking System[Outdoor Waterproof Camping/Hiking/Travel Rucksack Back Pack Bag]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Ergonomic Children Home Study Desk with Multifuction Adjustable-composite.Polymer. 2005; 46(6):1949-1955.Auto Hyundai Elantra Moving Head LED Stage Light[Elegant Short Necklace Fashion Necklace Ornament Present for Mother′s Day]

Received: September 7, 2011
Revised: January 3, 2013

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