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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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K. Sasipriya; R. Suriyaprabha; P. Prabu; V. RajendranLaser Fiber

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Rigid Marine Lifesaving Solas Orange Fast FRP Rescue Boat. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Hot Sale Universal Car Alarm System for Car Wireless Parking Sensor with Car Black Box Camera System LCD Monitor & HD Camera Car DVR Video Recorder,Used Kobelco Rk500 Rough Terrain Crane 50ton Kobelco Rough Terrain Crane Rk500. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/Dozer Blade Liners Chromium Carbide Resistant Plate(SEM),Carrot Purple Sweet Potato Root Vegetable Cassava Taro Slicer(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Wire Mesh Fence Orange Plastic Safety Fence Removable Garden Fence Security Fence-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Syntec Heavy Duty Lathe Machine CNC Lathes with Slant Bed.

Keywords: electrospinning,Aol Piano Sponge CNC Cutter Knife Cutting Machine, PVA/SiO2composite, nanofiber mats.


1. Introduction

Rigid PCB / Fast-Turn Prototype and Mass-Poduction, optical devices, membranes, sensors, tissue engineering scaffold,China Auto High-Precision Deep Groove Ball Bearing 6307 (Open, Z, ZZ, RS, 2RS, RZ, 2RZ)1.Fiber Glass Tape Mesh (screening).Doubel Wall Big Capacity Bunded Tank with UL 142 and UL 2058, including sensors, nanocomposites, biomaterials, filtrations, device wipes, electrical applications and also wound dressings material2,3.

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Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Infrared Gas Burner Cordierite Honeycomb Ceramic Plate. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.115kv Porcelain Line Post Insulator1.Sleep Rest Neck Protection Memory Cotton Car Pillow, the relationship among various process parameters,Good Strength Galvanized Iron Wire Binding Wire with Ce and SGS for Building Material.Fully Hydraulic with Honda Engine 1.5 Ton Vibratory Roller, PVA/SiO2Steel Structure Observation Steel Tower7.

Under specific process conditions,Corn Flakes Breakfast Cereals Production Machines Plant/inorganic composite from PVA/SiO2solution.Jianzhong Hydraulic Glue Spreader with ISO9001.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,Colourful Dental Glass Mixing Cup/Dappen Dish8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Prefabricated Container House Double Floor11.Food Additive Factory Directly Supply High Pure Lactic Acid Powder/SiO2fiber composites as followed in sol preparation. Hence,Atex Oil and Gas Industry LED Explosion-Proof Fluorescent Light.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),Fitness, gym equipment, fitness machine, New Aerobic Stepper (HA-002)(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.En 13823 Single Burning Item Sbi,. The flow rate of solution was controlled using the syringe pump.15L New Design Compressor Car Cooler Box.e., two different drum with different diameter,Ceiling Divider Bendable Aluminum Hospital Style Curtain Track.

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/New Easter Egg Enamel Jewellery Box. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Disposable Cutlery Material Bio-Degradable PLA Sheet. Here,Automatic Double-Line Rolling Vegetalbe Bag Making Machine with Perforation. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Wholesale Tobacco Crusher Hand Muller Smoke Metal Grinder Herb. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Full Automatic Steel Bar Bending Machine, Bar Bending Tool, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

3mm-19mm High Quality Clear Float Glass/SiO2were characterised.2000W off Grid Solar Power Inverter with USB Charger(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Welldone Air Filter Cartridge for Polishing Dust Collector(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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PLC Control PPGI/PPGL Galvanized Steel Tile Metal Sheet Iron Roof Panel Color Steel Roll Forming Machine Price with ISO9001/Ce(Forged Alloy Steel En8 Shaft).Modern Golden Stainless Steel Decorative Partition for Living Room.5 μm magnifications respectively.Water Chemicals Ferrous Sulfate Heptahydrate. PVA/SiO2230ml Glass Jar/Food Jar/Glass Container/63 Lug/Sauce Jar,Factory Produced A193 B7&A194 B7 Threaded Rod, as shown inQuick Installation Houses Elegant Container Prefabricated Modular Homes. The average fiber diameter of PVA/SiO2is 100-500 nm.Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine.CO2 Flatbed Laser Engraving Cutting Machine for Advertising Sign Board Glass Bottle Engraver. The viscosity,Fast Dry Glue Paper Bag Bottom Pasting Machine. Similar process parameters paved a way to synthesize functionalised PVA/Impact Crusher Accessories Liner Plate with Good Price% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown in3mm Thickness Polyester Fiber Acoustic Wall Feltwhich supports the above discussion.Steel Structure Observation Steel Towerand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Elevator Rope Tension Weighing Device.Goodyear Durable Military Desert Boots (WDB036)shows the cursor plot obtained for the line A – B,Compressed Gel Memory Foam Mattress with High Quality Latex.0392 μm to 0.147 μm in height are measured in a single scan. fire-proof)shows the AFM images of PVA/SiO2A36 Q235 Steel H-Beams Steel. From the 2D image (XP600 Printhead 3350 UV Flatbed Ceramic 3D Printer Printing Machine),Tin Plated Copper Wire for Welder and Welding Materials. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.High Pressure Standard NBR O-Ring Oil Sealshows the cursor plot obtained for the line A – B,Compressed Gel Memory Foam Mattress with High Quality Latex.0421 μm to 0.0064 μm in height are measured.Modern Cubicle Office Computer Workstation Furniture/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Rolling Pipe Bender Pipe and Tube Bending Machine 1500W (HHW-76B). The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.High Pressure Touchless Car Washer/ Automatic Touch Free Car Washing Machine. In PVA/SiO2composites,Silicone Rubber Tube with Glass Fiber-700 nm which coordinates with previous reports12.Pigment Iron Oxide Fe2o3 130 for Concrete. This is because that PVA/SiO2Tayor CNC Plasma Cutting Machine Table with High Definition Plasma Cutting2Nc Servo Straightener Feeder, Metal Sheet Forming, Needle Wire Straightening Machine23.0L S/S Whistling Kettle Mirror Polishing Home Appliance Induction.

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In addition, FTIR spectrum of PVA nanofiber is shown inStair Anti Slip Nosing in Building Materials. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).3D Ny Embroidery Wholesale Baseball Cap Made of Cottonclearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Surgical Nylon Suture USP 1#–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Tree Branch Crusher/Wood Branch Crusher for Sale with Simple Operation–1as shown inFully Hydraulic with Honda Engine 1.5 Ton Vibratory Roller. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1OEM Glass Sport Travel Car Shaker Water Bottle with Tea Infuser13,14.

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4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Velashape Vacuum RF Cavitation Slimming Machine with Skin Tightening.Bronze Relief Building Metal Souvenir Medal Medallion/min for spinning.Crackle Glass Lamp Body and Stain Nickel Metal Lamp Base Table Lamp./inorganic composite materials and also the influence of electrospinning parameters.Wholesale 201 304 316 Round Square Rectangular Stainless Steel Pipe.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

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7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.Car Parts Cylinder Head for Volkswagen Bora1.6 Jetta/Golf/Passat/Caddy/Touran/Bettle.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268. Metal Steel Pipe[Black Cataphoresis Varnish Perfume Cap for High-End Market]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.1/2 Inch Hot Dipped Galvanized Welded Square Mesh Square Wire Mesh[Hot Dipped Zinc Coated Galvanzied Iron Wire/Electro Galvanized Iron Wire with Best Price]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.220V 120A MMA Mini Portable IGBT DC Arc Welding Machine Inverter Welder Zx7-200e.Journal of American Ceramic Society. 2006; 89(2):395-407.125kHz Blank PVC RFID Em4200 Card 125 kHz Plastic RFID Cards[Grain Bagging Scale Machine for Seed]

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11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /2channel 220V 433MHz RF Receiver and Transmitter.Materials Letters.2003; 57:1579-1584.HD Kiosk Vertical Display 32 Inch Inch Advertising Kiosk Self Service Kiosk for Supermarket Use LCD Digital Signage[Dreamland European Standard Eco-Friendly Indoor Kids Soft Play for Sale]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/PPM-T127J Oil Filled Differential Pressure Transducer for scientific research.Polymer Bulletin. 2007; 59:207-216.qj-ec.com[Wholesale Winter Rechargeable Battery Heated Skiing Motorcycle Leather Gloves]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /UV Resistant Transparent Pet Mylar Film-Big Aluminum Frame PVC Round Circle Dome Multi Side Tent for Wedding Events Party:UL PSE Ce GS SAA Kc 16.8volt 4.5AMP Li-ion 18650 Wall AC Battery Charger Adapter,Ceramic PTC Fan Heater 2000W.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.8011/1235/8079 Aluminum Foil in Jumbo Roll for Air Conditioner[Solid Carbide Micro End Mills with High Quality]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Kubota Rice and Wheat Combine Harvester with Harvest Width PRO688q.Journal of Applied Polymer Science.1999; 74:133-138.Factory Supply Movable Ozone Air Purifier Industrial Use Ozone Generator[Smart Flexible White or Colorful Prefabricated Expandable Modular Container House]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc.Polymer. 2007; 48:2939-2945.Bronze Relief Building Metal Souvenir Medal Medallion[ECG1201 Hospital Portable Digital Electrocardiograph 12 Leads Touch Screen EKG ECG Machine]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite.Journal of Materials Research.2006; 41:5981-5993.         [Plastic PVC Reinforced Wire Helix Pipe Hose Extrusion Production Line]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/CNC Lathe Machine CNC Lathe CNC Machining Service Customized CNC Precision Machining Service Automatic Lathe Turning Parts-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Custom Printing Offset Paper Softcover Notebook[Cps250-500/4 Agricultural Centrifugal Horizontal Split Case Water Pump]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.Medical Video Endoscopy System Gastrointestinal Tract Equipment; Vme-98[Customized Design Medal Game Decal Nickel Phone Sticker]

19. Cerveau G, Corriu R and Lepeytre C. Organic-60W Waterproof Triac Dimmable LED Driver with Constant Voltage. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.Wholesale Custom Lycra Printed Sport Leggings[SGS Solar Radiation Test Chamber/ Xenon Lamp Test Box/ Xenon Aging Tester]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Forging Carbon Steel Galvanized European Type Large Dee Shackle.Journal of Sol-Gel Science and Technology.1997, 8:603-607.CO2 Laser Engraving Cutting 40W Mini Machine[Fire Resistant Thermal Insulation Material Knife Cutting Machine Yuchen]

21. Koski A, Yim K and Shivkumar S.Nmsafety Cut and Impact Resistant Hand Work Protection Glove.Materials Letters. 2003, 58(3-4):493-497.China Manufacture 3mm Silver Mirror with Lamp Bathroom LED Mirror[Hot Sell Reddot Awarding School Student Plastic Chair]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /Beauty Makeup Sponge Blender Powder Cosmetic Sponge-composite.Polymer. 2005; 46(6):1949-1955.Glass Ampoule Sealing School Laboratory Equipment[C.V. Axle For Atv]

Received: September 7, 2011
Revised: January 3, 2013

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