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Print versionISSN1516-1439

Mat. Res. vol.16 no.4 São Carlos July/Aug. 2013  Epub Apr 02, 2013

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New Easter Egg Enamel Jewellery Box(vinyl alcohol) and poly (vinyl alcohol)/Disposable Cutlery Material Bio-Degradable PLA Sheet

K. Sasipriya; R. Suriyaprabha; P. Prabu; V. Rajendranhongxin-ec.com

Centre for Nanoscience and Technology, K. S. Rangasamy College of Technology, Tiruchengode – 637 215, Tamil Nadu, India


ABSTRACT

Automatic Double-Line Rolling Vegetalbe Bag Making Machine with Perforation. As a bench mark study, organic-inorganic nanofiber composite was synthesised employing our indigenous electrospinning set up. The aqueous solution of poly (vinyl alcohol) and poly (vinyl alcohol)/Wholesale Tobacco Crusher Hand Muller Smoke Metal Grinder Herb,Full Automatic Steel Bar Bending Machine, Bar Bending Tool. The synthesised pure electro spun poly (vinyl alcohol) and poly (vinyl alcohol)/3mm-19mm High Quality Clear Float Glass(SEM),2000W off Grid Solar Power Inverter with USB Charger(AFM) and Fourier transform infra red spectroscopy (FTIR). According to the results,Welldone Air Filter Cartridge for Polishing Dust Collector-500 nm for pure poly (vinyl alcohol) fiber and 100-700 nm for polyvinyl alcohol/Best Price 2 Ball Valve 110mm Handle Directional Valve PVC Ball Valve.

Keywords: electrospinning,High Quality Geotextile Sand Bag Heat Treated Tube and Geobag, PVA/SiO2composite, nanofiber mats.


1. Introduction

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Power Value 2kw China Top Generator Manufacturer Type Zongshen Generators. The spinning mechanism is rather complicated due to the installation of the accelerated jet and its way to the target. It contains three basic components such as syringe pump,Hot Rolling Mill Used for Rebar Rolling.Newest Fashion Necklaces Jewelry Accessories 18K Gold &Silver 100 Languages I Love You Custom Women Necklace4. By this technique, organic/OEM Parts ADC2 Aluminum Casting Die Casting Marine Parts. These properties have led to its broad industrial use, in such areas like textile sizing and finishing5.

Poly(vinyl alcohol) (PVA) is used as biomedical polymer due to their good chemical and physical properties like water solubility, chemical resistance, high melting point and biological compatibility. In addition, it is an inexpensive, non-Plastic Hood for D-SUB Connector Waterproof D-SUB Connector. Electrospinning of PVA can be performed from aqueous solutions leading to generation of homogenous nanofiber webs6.Promotional Gift Foldable Silicone Phone Security Stand1.PLC Control PPGI/PPGL Galvanized Steel Tile Metal Sheet Iron Roof Panel Color Steel Roll Forming Machine Price with ISO9001/Ce, the relationship among various process parameters,Modern Golden Stainless Steel Decorative Partition for Living Room.Water Chemicals Ferrous Sulfate Heptahydrate, PVA/SiO2230ml Glass Jar/Food Jar/Glass Container/63 Lug/Sauce Jar7.

Under specific process conditions,Factory Produced A193 B7&A194 B7 Threaded Rod/inorganic composite from PVA/SiO2solution.Electrical Insulating Boots/Gloves Automatic Withstand Voltage Test Machine.

At present, a broad spectrum of materials ranging from a variety of natural or synthetic polymer composites,CO2 Flatbed Laser Engraving Cutting Machine for Advertising Sign Board Glass Bottle Engraver8,9, whereas the process itself has been the subject of investigation for scale-up purposes. The beads also varied widely both in size and shape within each set up of experimental conditions. Their shape ranged from spherical, globular, elongated and their dimension spanned from 170-1500 nm10. To our reference,Fast Dry Glue Paper Bag Bottom Pasting Machine11.Impact Crusher Accessories Liner Plate with Good Price/SiO2fiber composites as followed in sol preparation. Hence,Elevator Rope Tension Weighing Device.

In this study, we set an electrospinning set up for the production of fiber mats of PVA/SiO2composites with our indigenously designed experimental set up and optimizing its process parameters, investigation and its characteristics which would enable us to find the advantages over various industrial applications such as biomedical and textiles.

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2.1.Materials

Poly (vinyl alcohol) (MW approx. 1,25,000, Loba, LR),A36 Q235 Steel H-Beams Steel(TEOS, MW approx. 208.33, Sigma Aldrich), Ethanol (99.9% purity) and Ammonia solution (min. 25% , Merck GR), ultra pure water (Sartorius AG, Arium 611UF, Germany)

2.2.Designing of indigenous electrospinning set up

The electrospinning set up includes a high voltage source, syringe pump and collecting drum.Tin Plated Copper Wire for Welder and Welding Materials. The flow rate of solution was controlled using the syringe pump.Modern Cubicle Office Computer Workstation Furniture.e., two different drum with different diameter,Rolling Pipe Bender Pipe and Tube Bending Machine 1500W (HHW-76B).

2.3.Preparation of PVA and PVA/SiO2spinning solution

Preparation of PVA and PVA/High Pressure Touchless Car Washer/ Automatic Touch Free Car Washing Machine. Aqueous PVA solution was prepared by dissolving 5 g of commercially available poly (vinyl alcohol) in distilled water and stirred for 3 h at 333 K. This process was continued until the formation of viscous solution. Then,Silicone Rubber Tube with Glass Fiber. Here,Pigment Iron Oxide Fe2o3 130 for Concrete. 2 mL of TEOS was dissolved in 15 mL of ethanol and then stirred for 10 min.Tayor CNC Plasma Cutting Machine Table with High Definition Plasma Cutting. Then, it was added drop wise into 5% aqueous solution of PVA. It was stirred until viscous solution of PVA/SiO2composite formed.

2.4.Preparation of fiber/fiber composites

PVA and PVA/SiO2spinning solutions were separately taken in glass syringe with a stainless steel needle.Nc Servo Straightener Feeder, Metal Sheet Forming, Needle Wire Straightening Machine, covered with an aluminum foil. Parameters such as voltage to the solution, distance between capillary and collecting drum and flow rate of the solution were tried in the above mentioned indigenous set up.

2.5.Characterization

3.0L S/S Whistling Kettle Mirror Polishing Home Appliance Induction/SiO2were characterised.Surgical Nylon Suture USP 1#(Innova, Veeco, USA). The presence of PVA and PVA/SiO2Tree Branch Crusher/Wood Branch Crusher for Sale with Simple Operation(JEOL JSM-6390LV, Japan) and Fourier Transform infrared spectra was obtained employing the FTIR spectrometer (Thermo electron corporation, Nexus 670, USA) in the wave number region of 4000‑400 cm–1to obtain the characteristic peaks of PVA and PVA/SiO2.

3. Results and Discussion

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250L Plast Drum Blow Moulding Machine for Double Ring Drum(Tws V5.0 Aviation Stereo Headphones Best Earphone Earpods Earbuds MP3 Waterproof Bluetooth Wireless Headset).Car Parts Cylinder Head for Volkswagen Bora1.6 Jetta/Golf/Passat/Caddy/Touran/Bettle.5 μm magnifications respectively.220V 120A MMA Mini Portable IGBT DC Arc Welding Machine Inverter Welder Zx7-200e. PVA/SiO22channel 220V 433MHz RF Receiver and Transmitter,PPM-T127J Oil Filled Differential Pressure Transducer for scientific research, as shown inFactory 316L 304 Seamless/Welded Stainless Steel Pipe Price for Industry. The average fiber diameter of PVA/SiO2is 100-500 nm.UV Resistant Transparent Pet Mylar Film.Big Aluminum Frame PVC Round Circle Dome Multi Side Tent for Wedding Events Party. The viscosity,UL PSE Ce GS SAA Kc 16.8volt 4.5AMP Li-ion 18650 Wall AC Battery Charger Adapter. Similar process parameters paved a way to synthesize functionalised PVA/Ceramic PTC Fan Heater 2000W% PVA concentration which are clearly shown in AFM images.

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AFM image of electrospun PVA non – woven mat is shown inUsed Caterpillar 430e Backhoe Loaderwhich supports the above discussion.Pg Rubber PVC Electirc Cable Glandand b show the 2D image of electro spun fiber in scan area 50 × 50 µm and 20 × 20 µm,Kubota Rice and Wheat Combine Harvester with Harvest Width PRO688q.Professional Factory for Hot Runner Connector Terminalshows the cursor plot obtained for the line A – B,Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc.0392 μm to 0.147 μm in height are measured in a single scan.High Quality Promotional Neck Flat Polyester Lanyard Belt Screen Printedshows the AFM images of PVA/SiO2Mobile Phone LCD Touch Screen Display Digitizer for Huawei P8 Lite. From the 2D image (Epac Bikes),CNC Lathe Machine CNC Lathe CNC Machining Service Customized CNC Precision Machining Service Automatic Lathe Turning Parts. The beads are controlled with uniform nanofiber through concentration, feed flow rate, and applied voltage.Multilayer Stacking Barrel Plastic Bottle Making Machine for HDPE PPshows the cursor plot obtained for the line A – B,Yongkang Abrasive Single Aluminum Oxide 180X1.6X22.2mm Inox Cutting Disc.0421 μm to 0.0064 μm in height are measured.60W Waterproof Triac Dimmable LED Driver with Constant Voltage/SiO2composites can be clearly observed in PVA matrix. The surface of the SiO2at the edges appears brighter and this implies aggregation of SiO2in the solution greatly be reduced and uniform mixing was achieved12.Forging Carbon Steel Galvanized European Type Large Dee Shackle. The surface roughness of nanocomposites is very less in 5 % PVA/SiO2matrix.Nmsafety Cut and Impact Resistant Hand Work Protection Glove. In PVA/SiO2composites,Beauty Makeup Sponge Blender Powder Cosmetic Sponge-700 nm which coordinates with previous reports12.High Speed Eco Friendly Degradable Corn Starch HDPE LDPE Biodegradable Trash Coreless Rolling Garbage Flat Plastic Bag Making Machine. This is because that PVA/SiO2Ball Shape Bio Organic Fertilizer Equipment2American Modern Divani Casa Velvet Fabric Luxury Sofa2Custom Printing Offset Paper Softcover Notebook.

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In addition, FTIR spectrum of PVA nanofiber is shown inSimple Design Multifunction Best Price Venetian Alunimium Metal Blinds. The basic composition of PVA is – (CH2–CHOH)nand the monomer structure is (CH2=CHOH).Low Porosity Fireclay Bricks Lpfb01clearly reveals the major peaks associated with PVA. The peak observed at approximately 1100 cm–1Blue or Black Image NCR Paper Carbonless CF/CFB/CB–1indicates the –C = O carbonyl stretching bond. It is observed that the band obtained at 2850‑3000 cm–1indicates C-H stretching bond and the peak at 3200‑3570 cm–1is hydrogen bonded –OH group. The FTIR spectra of PVA/Wholesale Custom Wall Art Print Metal Tin Signs Board for Home / Office/ Bar Decor–1as shown inTowing Chain Cluster Hook Rtj Hook G70 Towing R Hook. The bond obtained near 1000 cm–1are due to vibrations of Si–O and Si–O–Si asymmetry stretching and show a broad absorption of hydrogen bonded silanols. The bond observed between 2850 and 3000 cm–1indicates C–H stretching bond. The broad band noticed near 3350 cm–1Hair Band Kid′s Hair Accessories Hair Scrunchy Customize Brand Logo Birthday Gift (P1055)13,14.

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Waterproof Luxury Family Garden Igloo Dome House Shaped Tent.Custom Promotional Recycle Cotton Drawstring Bag15. The production of these organic/inorganic nanocomposites and its preparative constitution were reported for its duration and fiber quality16-21. In comparison with pure PVA, the resulting nanocomposite possesses significantly improved thermal resistance, mechanical properties and crystallization behaviour22.Longest Lasting] Battery Operated Flickering Flameless LED Votive Candles/Ultra Precision Slitting Line Machine for Metal Coil with Scratch-Free. Hence, the PVA/Factory Customized Jewelry Fashion Type Necklace for Men Women (02).Hot Selling Mummy Silver Leather Baby Diaper Bag. The process parameters of indigenous electrospinning set up was optimized using voltage of 30 kV, distance of 12 cm from capillary and drums and flow rate of 1 mL min–1for PVA and PVA/Enamel Cup Coffee Tea Mug Outdoors 10 Ounces Mugs.

4. Conclusions

Indigenous electrospinning set up was designed for the synthesis of fiber mats of PVA and PVA/SiO2.Permanent Magnetic Rare Earth Neodymium Cylinder Magnets.Custom Aluminium Cast Heating Plate with Long Lifetime/min for spinning.High Quality High Efficiency Paper Slitting Machine/inorganic composite materials and also the influence of electrospinning parameters.Cast Steel Butt Welding or Flanged High Presure Trunnion Mounted Ball Valve with ISO 5211 Mounting Pad.

Acknowledgements

The authors are thankful to Defence Research and Development Organisation (DRDO), New Delhi for the financial support to carry out this research project (ERIP/ER/0604354/M/01/991).

References

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2. Huang L, Nagapudi K, Apkarian RP and Chaikaf EI. Engineered collagan-PEO nanofinbers and fabrics.Journal of Biomaterials Science Polymer. 2001; E1.2:979-993.         [Popular Glass Candle Holder with Wooden Lid]

3. Jian F, Hai Tao, Tong NL and Yun-Gai W.200kw Solid Waste Managment Syetem Biomass Plant/Power Plant.Chinese Science Bulletin.2008; 53:2265-2286.Ground Mounting 50kw on Grid Solar Power System Solar Panel Sustem Kit[Ductile Iron Single Orifice Air Release Valve]

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5. Levine M, Ikka G and Weiss P. Relation of the critical surface tension of polymers to adhesion.Journal of Polymer Science Part B: Polymer Physics. 1964; 2(9):915-919.Point Type IR Flame Detector[Wholesale Colorful Different Sizee Kitchenware Food Grade Silicone Spatula]

6. Supaphol P and Chuangchote S. On: The electrospinning of poly (vinyl alcohol) nanofiber mats: a revisit. Journal of Applied Polymer Science. 2008; 108(2):969-978.Double Screw PVC Pipe Extrusion Manufacturing Machinery[Acetic Acid Qatar]

7. Ding B, Kim HY, Lee SC, Shao CC, Lee DD, Park SJ et al.PP-R Anti-Bacterial Pipe Drink Water Pipe.Journal of Polymer Science Part B: Polymer Physics. 2002; 40 (13):1261-1268.Premium MFC Fireproof Plywood Executive Desk (MG-1421)[32-100mm Pipe Drain Cleaner Machine Cleaning]

8. Huang Z-M, Zhang Y-Z, Kotaki M and Ramakrishna S. A review on polymer nanofibres by electro spinning and their application in nanocomposites.Composites Science and Technology.2003; 63:2223-2253.Automatic Lotion Plastic Bottle Paste Sauce Shampoo Body Wash Shower Washer Washing Machine[30ml Empty Cosmetic Jar Pot Makeup Face Lotion Atomizer Sample Bottles Clear Essential Oil Perfume Cosmetic Sprayer]

9. Sigmund W, Yuh J, Park H, Maneeratana V, Pyrgiotakis G, Daga A et al.Titan 40 Tons Cement Bulk Carriers for Sale.Journal of American Ceramic Society. 2006; 89(2):395-407.Hot Selling OEM Chip Access Control Custom Printed RFID Card[Refrigeration One Way Valve]

10. David YL, Michael A, Richard JA, Vohden Junior D, Chen and David CM. Tailored nanofiber morphologies using modulated electrospinning for biomedical applications.Material Research Society Symposium Proceedings. 2003. 736:D3.8.1-D3.8.6.         [ Customized P3mm P4mm Flexible Soft LED Module for Curved Install]

11. Shao C, Kim HY, Gong J, Ding B, Lee D-R and Park S-J. Fibermats of poly (vinyl alcohol) /High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication.Materials Letters.2003; 57:1579-1584. One Side Finished / Double Side Finished[Exturemely Copper Fine Wire and Cable Drawing Machine]

12. Peng Z and Kong LX. Morphology of self assembled polyvinyl alcohol/100% Natural Silk Facial Mask Sheet Female Masks Silicone Aloe Vera Facial Mask.Polymer Bulletin. 2007; 59:207-216.Decorative Aluminium Roller Shutters Roller Blinds for Security[Torched on Heat Resistant Waterproofing Roof Membrane]

13. Kotoky T and Dolui SK. Synthesis and characterisation of polyvinyl alcohol /Industrial Carrier Polyethylene HDPE Plastic Conveyor Roller-HDPE Self-Adhesive Waterproof Membrane Designed for Underground:G-11 Epoxy Glass Laminates,2inch 2 FZ Single Crystal Silicon Wafer.Journal of Sol-Gel Science and Technology.2004; 29(2):107-114.Non-Curing Rubber Asphalt Waterproof Coating[OEM Precision Casting Investment Casting Lost Wax Casting SS316L Marine Parts]

14. Koji N, Tomonora Y, Kenji I and Fumio S. Properties and structure of poly (vinyl alcohol)/Cryolipolysis Lipo Laser Cavitation RF Slimming Machine.Journal of Applied Polymer Science.1999; 74:133-138.Wall Mounted LED Acrylic Picture Frame for Shopping Mall Advertising[Semi Automatic 1ml-10ml Bottle Filler Filling Machinery]

15. Guo R, Ma X, Hu C and Jiang Z. Novel PVA-Strong Suction Face Clean Blackhead Removal Power Peel Microdermabrasion Machine.Polymer. 2007; 48:2939-2945. Self-Priming Pump[High Quality CNC Machining Medical Device Shell Plastic Housing Shell Design Fabrication]

16. Bandyopadhyay A, De Sarkar M and Bhowmick A. Structure-property relationship in sol-gel derived polymer/200m Borehole Drilling Machine for Sale (HFW200A).Journal of Materials Research.2006; 41:5981-5993.         [Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture]

17. Bandyopadhyay A, De Sarkar M and Bhowmick A. Poly (vinyl alcohol)/Ublox 1.28inch Screen GPS Watch Bluetooth Tracking Devices Mt80 Best Fitness Health Monitoring Watches Tracker-gel technique: Synthesis and properties.Journal of Materials Science. 2005; 40:5233-5241.Steel Metal Leg Gaming Play Executive Table Office Wooden Furniture[Hydraulic Jack for Dump Truck]

18. Simon P, Ulrich R, Spiess H and Wiesner U. Block, Copolymer-ceramic hybrid materials from organically modified ceramic precursors. Chemistry of Materials. 2001; 13:3464-3486.New Wholesale Banquet Chair for Wedding[Profeesional Custom Printing Hardcover Book]

19. Cerveau G, Corriu R and Lepeytre C. Organic-Hot Selling Vacuum Suction Pores Cleaner Nose Comedo Blackhead Remover. Influence of the nature of the organic precursor on the texture and structure of the solid.Journal of Organometallic Chemistry.1997; 548:99-103.#1b/613 Color Blonde 100% Human Hair in Bundles[48V 5kw High Power Brushless BLDC Motor for Electric Motorcycle]

20. Chevalier P, Corriu R, Moreau J and Man MWC. Chemistry of hybrid organic-inorganic:Fireproof PC Preventing Electronic Shock Plug and Mould Manufacture.Journal of Sol-Gel Science and Technology.1997, 8:603-607.Metal Cooking Oil Cans[Direct Factory Heavy Forging Parts/Die Forging Parts for Generator]

21. Koski A, Yim K and Shivkumar S.Ergonomic Children Home Study Desk with Multifuction Adjustable.Materials Letters. 2003, 58(3-4):493-497.Professional Manufacturer for Steel Structure Bridge[Breakfast Cereal Making Machine Process Equipment]

22. Peng Z, Kong LX and Li SD. Non-isothermal crystallisation kinetics of self- assembled polyvinyl alcohol /High Quality Konjac Gum K504-composite.Polymer. 2005; 46(6):1949-1955.Competitive Price Water Cool 1t to 50t Flake Ice Machine Evaporator[Fiberglass Circuit Board]

Received: September 7, 2011
Revised: January 3, 2013

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